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Nan Lu and Huatian Wang Theoretical study of enantiomeric and geometric control in chiral guanidine-catalyzed asymmetric 1,4-addition of 5H-oxazol-4-ones International Journal of Quantum Chemistry 113

Version of Record online: 9 APR 2013 | DOI: 10.1002/qua.24447

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Chiral guanidine catalysts are widely used in various asymmetric reactions to obtain high enantioselectivity. However, the reaction of asymmetric 1,4-addition catalyzed by bicyclic chiral guanidine is not well understood. This article presents the origin of high enantiomeric and geometric control for this type of guanidine. The results are expected to contribute to the design and modification of guanidine catalysts.

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