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Hamid Berriche Potential energy and dipole moment of the Na2+ ionic molecule International Journal of Quantum Chemistry 113

Article first published online: 25 JUN 2013 | DOI: 10.1002/qua.24475

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Ionic alkali pairs like Na2+ become immobilized and localized spatially in Coulomb crystals when translationally cooled to temperatures of a few mK. Accurate potential energy and dipole functions data are required to predict and guide the experimental studies. Potential energies, spectroscopic constants and dipole functions of ground and excited states of the Na2+ ionic molecule are calculated using a one-electron pseudopotential approach, where the Na2+ core is replaced by effective potential.

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