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Mehdi D. Esrafili, Parvin Esmailpour, Fariba Mohammadian-Sabet and Mohammad Solimannejad Substituent effects on cooperativity between lithium bonds International Journal of Quantum Chemistry 114

Article first published online: 9 OCT 2013 | DOI: 10.1002/qua.24560

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Substituent effects on the cooperativity in a series of lithium-bonded trimmers are reported. Li-bonding enhances pair interactions on the trimer formation, and Li…N interactions are found to be stronger than corresponding Li…C linkages. Generally, the electron density at the Li···N and Li···C critical points can be regarded as a good descriptor of the degree of cooperative effects.

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