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Shmuel Zilberg Chemical reaction with two different elementary transition states International Journal of Quantum Chemistry 114

Version of Record online: 3 MAR 2014 | DOI: 10.1002/qua.24638

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Elementary chemical reactions with two different transition states between reactants and products have been reported since 2004, e.g., cis-trans isomerization around polar double bonds syn-anti isomerization of azo-compounds, charge shift in aliphatic radical-cations, and H atom transfer vs. proton-coupled electron transfer. Valence bond theory provides a rationalization of this phenomenon.

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