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Maha Chaieb, Héla Habli, Leila Mejrissi, Brahim Oujia and Florent Xavier Gadéa Ab initio spectroscopic study for the NaRb molecule in ground and excited states International Journal of Quantum Chemistry 114

Article first published online: 13 MAR 2014 | DOI: 10.1002/qua.24664

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Heteronuclear alkali dimers, like NaRb, have applications in Bose–Einstein condensates, laser cooling, and photoassociative spectroscopy. Comprehensive first-principles modeling of the potential energy for all electronic states dissociating below the ionic limits of Na- and Rb+ helps in the correct assignment of vibrational and rotational quantum numbers from experiments, and inspires new pathways in cold ions trapping research.

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