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Xiaoqing Huang, Changyou Guo, Jinquan Zuo, Nanfeng Zheng and Galen D. Stucky An Assembly Route to Inorganic Catalytic Nanoreactors Containing Sub-10-nm Gold Nanoparticles with Anti-Aggregation Properties Small 5

Version of Record online: 15 JAN 2009 | DOI: 10.1002/smll.200800808

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Yolk–shell catalytic nanoreactors with sub-10-nm Au nanoparticles and a mesoporous ZrO2 or TiO2 shell are prepared from monodisperse hydrophobic Au nanoparticles through an assembly approach (see image). The nanoreactors demonstrate both a remarkable catalytic activity and anti-aggregation properties upon thermal treatment and recycling.

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