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Yukatsu Shichibu and Katsuaki Konishi HCl-Induced Nuclearity Convergence in Diphosphine-Protected Ultrasmall Gold Clusters: A Novel Synthetic Route to “Magic-Number” Au13 Clusters Small 6

Article first published online: 18 MAY 2010 | DOI: 10.1002/smll.200902398

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A magic-number Au13 cluster with icosahedral geometry can be exclusively generated from a polydisperse mixture of ultrasmall 1,2-bis(diphenylphosphino)ethane-coordinated gold clusters upon treatment with HCl, which acts as an efficient promoter.

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