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Michael X. Macrae, Diana Schlamadinger, Judy E. Kim, Michael Mayer and Jerry Yang Using Charge to Control the Functional Properties of Self-Assembled Nanopores in Membranes Small 7

Version of Record online: 31 MAY 2011 | DOI: 10.1002/smll.201100394

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Light sensitive, semisynthetic ion channels allow for the modulation of multi­ple channel properties. Covalent attachment of a photoswitchable spiropyran group to the entrance of a gramicidin A ion channel enables reversible control of both conductance and channel lifetime, which show opposite trends in behavior at high and low salt concentrations.

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