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John M. Pettibone and Jeffrey W. Hudgens Predictive Gold Nanocluster Formation Controlled by Metal-Ligand Complexes Small 8

Version of Record online: 9 JAN 2012 | DOI: 10.1002/smll.201101777

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Selective reduction of gold-diphosphine complexes produces predictable nascent gold nanoclusters that can be separated into two classes. Class I complexes produce nascent neutral clusters and Class II produce cationic, ligated Au8 and Au10 nanoclusters. Predictable nascent products allow further tunable control of metal nuclearity through postreduction, size-selective processing, when desired.

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