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Xin Huang, Nicole Hauptmann, Dietmar Appelhans, Petr Formanek, Simon Frank, Stefan Kaskel, Achim Temme and Brigitte Voit Synthesis of Hetero-Polymer Functionalized Nanocarriers by Combining Surface-Initiated ATRP and RAFT Polymerization Small 8

Version of Record online: 22 AUG 2012 | DOI: 10.1002/smll.201201397

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Smart nanocarriers are created based on a bi-functional hetero-initiator for RAFT and ATRP technique, bi-functionalizing mesoporous silica nanoparticles with two polymer types. The pH-dependent behavior of PDEAEMA as the gatekeeper polymer is verified by electrokinetic measurements and a controlled release behavior is demonstrated using doxorubicin as the drug.

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