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Xianhong Rui, Ziyang Lu, Zongyou Yin, Dao Hao Sim, Ni Xiao, Tuti Mariana Lim, Huey Hoon Hng, Hua Zhang and Qingyu Yan Oriented Molecular Attachments Through Sol–Gel Chemistry for Synthesis of Ultrathin Hydrated Vanadium Pentoxide Nanosheets and Their Applications Small 9

Version of Record online: 14 NOV 2012 | DOI: 10.1002/smll.201201473

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Ultrathin single-crystalline V2O5·0.76H2O nanosheets with a thickness of 1.5–2.6 nm are prepared on the basis of molecular-level ‘oriented attachment’ through special sol–gel chemistry. The initial formation of 3–7 nm nanodiscs by confining the condensation reactions within the ab plane is critical to form nanosheets. As a proof-of-concept, these nanosheets exhibit good properties for hydrogen sensors and supercapacitors.

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