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Ying Wang, Kristopher R. Ward, Eduardo Laborda, Chris Salter, Alison Crossley, Robert M. J. Jacobs and Richard G. Compton A Joint Experimental and Computational Search for Authentic Nano-electrocatalytic Effects: Electrooxidation of Nitrite and L-Ascorbate on Gold Nanoparticle-Modified Glassy Carbon Electrodes Small 9

Version of Record online: 2 NOV 2012 | DOI: 10.1002/smll.201201670

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The comparison of simulated and experimental voltammograms enables the detection of changes of the electron transfer kinetics at the nanoscale. This approach is applied to verify electrocatalytic nanoeffects of gold nanoparticles for the electrooxidation of L-ascorbate and to discount electrocatalysis for the electrooxidation of nitrite.

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