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Jiawei Zhang, Changping Hou, Huang Huang, Lei Zhang, Zhiyuan Jiang, Guangxu Chen, Yanyan Jia, Qin Kuang, Zhaoxiong Xie and Lansun Zheng Surfactant-Concentration-Dependent Shape Evolution of Au–Pd Alloy Nanocrystals from Rhombic Dodecahedron to Trisoctahedron and Hexoctahedron Small 9

Version of Record online: 6 NOV 2012 | DOI: 10.1002/smll.201202013

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Rhombic dodecahedral, trisoctahedral, and hexoctahedral structures of Au–Pd alloy NCs are synthesized by changing the concentration of surfactant via a facile surfactant-mediated method. The catalytic activities toward electro-oxidation of ethanol are in the order of HOH > RD > TOH, while the activities toward catalytic reduction of 4-nitrophenol follow the order of RD > TOH > HOH.

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