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Ilan Jen-La Plante and Taleb Mokari Harnessing Thermal Expansion Mismatch to Form Hollow Nanoparticles Small 9

Version of Record online: 2 NOV 2012 | DOI: 10.1002/smll.201202471

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Nano popcorn: a new formation mechanism for the synthesis of hollow metal oxide nanoparticles through a melt fracture mechanism. The hollow nanoparticles are formed via brittle fracture following the generation of tensile stresses arising due to liquid-phase thermal expansion of a low melting point core metal. The progress of this physical process can be monitored using in situ transmission electron microscopy for a model system of indium/indium oxide.

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