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Qi Song, Yuying Jia, Bin Luo, Haiyong He and Linjie Zhi Covalently Stabilized Pd Clusters in Microporous Polyphenylene: An Efficient Catalyst for Suzuki Reactions Under Aerobic Conditions Small 9

Version of Record online: 19 JUN 2013 | DOI: 10.1002/smll.201301194

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With an in-situ one-pot chemical approach, a highly efficient conjugated microporous polymer-based catalyst for the Suzuki reaction is synthesized. The unique Pd/microporous polyphenylene cluster exhibits not only a high surface area, high gradient pore size distribution, and monodisperse and highly stabilized Pd clusters, but also a very high catalytic activity for a broad scope of Suzuki reactions in aqueous media under aerobic conditions with good yield, and high turnover number and turnover frequency values.

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