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Wei Li, Thomas Dittrich, Frank Jäckel and Jochen Feldmann Optical and Electronic Properties of Pyrite Nanocrystal Thin Films: the Role of Ligands Small 10

Version of Record online: 6 JAN 2014 | DOI: 10.1002/smll.201302333

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The influence of ligand anchor and bridging groups on the optical and electronic properties of pyrite nanocrystal thin films is investigated systematically. The thin film absorption onset shifts up to 100 meV to the red and the differential conductance varies over four orders of magnitude for the different ligands with ammonium sulfides and thiolated aromatic linkers showing the largest effects.

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