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Satoshi Kajiyama, Tatsuya Nishimura, Takeshi Sakamoto and Takashi Kato Aragonite Nanorods in Calcium Carbonate/Polymer Hybrids Formed through Self-Organization Processes from Amorphous Calcium Carbonate Solution Small 10

Version of Record online: 14 JAN 2014 | DOI: 10.1002/smll.201302745

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Nanostructured inorganic/polymer hybrids based on aragonite nanorods derived from aqueous suspensions of amorphous calcium carbonate (ACC) are prepared. ACC stabilized by an acidic polymer is crystallized gradually in a matrix of polymer films under ambient conditions. Thin-film hybrids composed of layers for calcite nanoparticles and aligned aragonite nanorods spontaneously develop in the polymer matrix.

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