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Alissa M. Chan, Laura A. Peña, Rosa E. Segura, Ramya Auroprem, Brent M. Harvey, Caroline M. Brooke and Patrick E. Hoggard Photocatalysis of Chloroform Decomposition by the Hexachlororuthenate(IV) Ion Photochemistry and Photobiology 89

Article first published online: 8 NOV 2012 | DOI: 10.1111/php.12005

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In the presence of RuCl62−, chloroform decomposes under near-UV irradiation to phosgene and hydrogen chloride. The photoactive species is suggested to be RuCl5(CHCl3) .

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