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Eunkyung Yang, Christian Ruzié, Michael Krayer, James R. Diers, Dariusz M. Niedzwiedzki, Christine Kirmaier, Jonathan S. Lindsey, David F. Bocian and Dewey Holten Photophysical Properties and Electronic Structure of Bacteriochlorin–Chalcones with Extended Near-Infrared Absorption Photochemistry and Photobiology 89

Article first published online: 19 MAR 2013 | DOI: 10.1111/php.12053

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The photophysical properties (Φs, Φf, Φic, Φisc, τT, kf, kic, kisc) of nine free-base bacteriochlorins bearing chalcone, extended chalcone or reverse chalcone substituents have been characterized and interpreted with the aid of molecular-orbital calculations. The bacteriochlorins absorb strongly in the 780–800 nm region and provide models for photosynthetic bacteriochlorophylls.

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