Chemistry - A European Journal

Cover image for Vol. 22 Issue 23

Editor: Neville Compton, Deputy Editors: Anne Deveson, Elisabeth Roedern

Impact Factor: 5.731

ISI Journal Citation Reports © Ranking: 2014: 22/157 (Chemistry Multidisciplinary)

Online ISSN: 1521-3765

Associated Title(s): Angewandte Chemie International Edition, Chemistry – An Asian Journal, ChemistryOpen, ChemistrySelect, ChemBioChem, ChemCatChem, ChemElectroChem, ChemMedChem, ChemPhysChem, ChemPlusChem, ChemSusChem, European Journal of Inorganic Chemistry, European Journal of Organic Chemistry

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Recently Published Articles

  1. Effect of Hydrodynamic Forces on meso-(4-Sulfonatophenyl)-Substituted Porphyrin J-Aggregate Nanoparticles: Elasticity, Plasticity and Breaking

    Dr. Zoubir El-Hachemi, Prof. Teodor Silviu Balaban, Dr. J. Lourdes Campos, Sergio Cespedes, Dr. Joaquim Crusats, Dr. Carlos Escudero, Dr. Christina S. Kamma-Lorger, Prof. Joan Llorens, Dr. Marc Malfois, Prof. Geoffrey R. Mitchell, Dr. Ana P. Tojeira and Prof. Josep M. Ribó

    Version of Record online: 30 MAY 2016 | DOI: 10.1002/chem.201600874

    Thumbnail image of graphical abstract

    Forced into shape: Nanotubes of J aggregates may collapse to form plastic bilayered ribbons when deposited on surfaces, and may break upon sonication or vortexing into smaller nanoparticles, which then tend to aggregate into large colloidal particles (see figure).

  2. β,β-(1,4-Dithiino)subporphyrin Dimers Capturing Fullerenes with Large Association Constants

    Kota Yoshida and Prof. Dr. Atsuhiro Osuka

    Version of Record online: 30 MAY 2016 | DOI: 10.1002/chem.201601152

    Thumbnail image of graphical abstract

    β,β-(1,4-Dithiino)subporphyrin dimers were synthesized and their complexation behaviors with fullerenes were investigated. The syn dimer captures both C60 and C70 with high association constants (ca. 106m−1) in toluene solution, with 1:1 and 2:1 complexation stoichiometries, respectively. The anti dimer forms a supramolecular complex with both C60 and C70 in the solid state; the fullerenes are sandwiched between each subporphyrin unit of two anti dimers.

  3. Generalization of the Copper to Late-Transition-Metal Transmetallation to Carbenes beyond N-Heterocyclic Carbenes

    Dr. Yannick D. Bidal, Orlando Santoro, Dr. Mohand Melaimi, Dr. David B. Cordes, Prof. Alexandra M. Z. Slawin, Prof. Guy Bertrand and Dr. Catherine S. J. Cazin

    Version of Record online: 30 MAY 2016 | DOI: 10.1002/chem.201601254

    Thumbnail image of graphical abstract

    Copper to carbene made easy! The NHC-CuI transmetallation reaction is expanded to Group 9 metals, and generalized to other carbenes such as MICs, aNHCs, and CAACs to generate a library of transition-metal complexes. Since all copper-complex precursors are made by direct metallation of easy-to-handle carbene conjugate acids with copper oxide, the methodology reported here allows for the preparation of a variety of carbene complexes without the use of highly sensitive reagents.

  4. Ordered Layered Dendrimers Constructed from Two Known Dendrimer Families: Inheritance and Emergence of Properties

    Dr. Hanna Dib, Cyrille Rebout, Dr. Régis Laurent, Sonia Mallet-Ladeira, Dr. Alix Sournia-Saquet, Dr. Menyhárt B. Sárosi, Prof. Dr. Evamarie Hey-Hawkins, Dr. Jean-Pierre Majoral, Dr. Béatrice Delavaux-Nicot and Dr. Anne-Marie Caminade

    Version of Record online: 30 MAY 2016 | DOI: 10.1002/chem.201601354

    Thumbnail image of graphical abstract

    More than the sum of parts: New dendrimers have been synthesized that are intrinsically composed in alternation of building blocks pertaining to two known families of dendrimers: the phosphorhydrazone dendrimers and the triazine-piperazine dendrimers. These mixed dendrimers with layered controlled architecture have inherited properties from their parents, but have also their own original properties.

  5. A Visible-Light-Triggered Conformational Diastereomer Photoswitch in a Bridged Azobenzene

    Claire Deo, Dr. Nicolas Bogliotti, Dr. Rémi Métivier, Dr. Pascal Retailleau and Prof. Juan Xie

    Version of Record online: 30 MAY 2016 | DOI: 10.1002/chem.201601400

    Thumbnail image of graphical abstract

    Flick of the Z-switch: Photoswitchable conformational diastereoisomers Z1 and Z2 are based on a bridged azobenzene structure. Z1 and Z2 can be interconverted by visible light via the less stable E-isomer with high photostability and good photochemical quantum yields.

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