Advanced Materials

Cover image for Vol. 24 Issue 8

Editor-in-Chief: Peter Gregory, Deputy Editors: David Flanagan, Martin Ottmar

Online ISSN: 1521-4095

Associated Title(s): Advanced Energy Materials, Advanced Engineering Materials, Advanced Functional Materials, Advanced Healthcare Materials, Small

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  1. A Graphite-Like Zero Gap Semiconductor with an Interlayer Separation of 2.8 Å

    Moni Baskey and Shyamal K Saha

    Article first published online: 23 FEB 2012 | DOI: 10.1002/adma.201104717

    Thumbnail image of graphical abstract

    The synthesis of a highly crystalline graphite-like new material with an interlayer separation of 2.8 Å is demonstrated by re-stacking GO sheets in the form of a thin film. The optical absorption spectra and electrical data indicate that the new crystal phase is an indirect zero gap semiconductor.

  2. Creation of Nanostuctures by Extreme Conditions: High-Pressure Synthesis of Ultrahard Nanocrystalline Cubic Boron Nitride

    Vladimir L. Solozhenko, Oleksandr O. Kurakevych and Yann Le Godec

    Article first published online: 23 FEB 2012 | DOI: 10.1002/adma.201104361

    Thumbnail image of graphical abstract

    The synthesis of high-purity bulk nanostructured cubic boron nitride (cBN) at 20 GPa and 1770 K by direct phase transformation of graphite-like BN with an “ideal random layer” structure is reported. The two-times increase of hardness of nano-cBN (HV = 85 GPa) with respect to conventional polycrystalline cBN (HV ∼ 45 GPa) is evidently a result of nanosize effects.

  3. Unraveling the Mechanism of Molecular Doping in Organic Semiconductors

    Alexander Mityashin, Yoann Olivier, Tanguy Van Regemorter, Cedric Rolin, Stijn Verlaak, Nicolas G. Martinelli, David Beljonne, Jérôme Cornil, Jan Genoe and Paul Heremans

    Article first published online: 23 FEB 2012 | DOI: 10.1002/adma.201104269

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    The mechanism by which molecular dopants donate free charge carriers to the host organic semiconductor is investigated and is found to be quite different from the one in inorganic semiconductors. In organics, a strong correlation between the doping concentration and its charge donation efficiency is demonstrated. Moreover, there is a threshold doping level below which doping simply has no electrical effect.

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