Advanced Synthesis & Catalysis

Cover image for Vol. 359 Issue 18

Early View (Online Version of Record published before inclusion in an issue)

Editor: Joe P. Richmond, Chairman of the Editorial Board: Eric N. Jacobsen

Impact Factor: 5.646

ISI Journal Citation Reports © Ranking: 2016: 2/72 (Chemistry Applied); 4/59 (Chemistry Organic)

Online ISSN: 1615-4169

Associated Title(s): Angewandte Chemie International Edition, Asian Journal of Organic Chemistry, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemCatChem, European Journal of Organic Chemistry

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  1. 1 - 48
  1. Communications

    1. Tandem Cross Coupling Reaction of Alcohols for Sustainable Synthesis of β-Alkylated Secondary Alcohols and Flavan Derivatives

      Sujan Shee, Bhaskar Paul, Dibyajyoti Panja, Bivas Chandra Roy, Kaushik Chakrabarti, Kasturi Ganguli, Ayan Das, Dr. Gourab Kanti Das and Dr. Sabuj Kundu

      Version of Record online: 19 SEP 2017 | DOI: 10.1002/adsc.201700722

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    2. Copper-Catalyzed Aerobic Annulation of Hydrazones: Direct Access to Cinnolines

      Chunling Lan, Zhuang Tian, Xuchun Liang, Mingchun Gao, Wenting Liu, Yu An, Wencheng Fu, Guanming Jiao, Junjie Xiao and Bin Xu

      Version of Record online: 18 SEP 2017 | DOI: 10.1002/adsc.201700669

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  2. Updates

  3. Communications

    1. Desymmetrization of Cyclopentenediones via Organocatalytic Cross-Dehydrogenative Coupling

      Fabrizio Vetica, Stephen Bailey, Pankaj Chauhan, Mathias Turberg, Adjmal Ghaur, Gerhard Raabe and Dieter Enders

      Version of Record online: 18 SEP 2017 | DOI: 10.1002/adsc.201700917

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  4. Updates

    1. A Visible-Light-Driven, Metal-free Route to Aromatic Amides via Radical Arylation of Isonitriles

      Marco Malacarne, Stefano Protti and Maurizio Fagnoni

      Version of Record online: 15 SEP 2017 | DOI: 10.1002/adsc.201700619

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  5. Cover Pictures

    1. You have free access to this content
      Acceptorless and Base-Free Dehydrogenation of Cyanohydrin with (η6-Arene)halide(Bidentate Phosphine)ruthenium(II) Complex

      Kicheol Kim, Adhitya Mangala Putra Moeljadi, Hajime Hirao and Soon Hyeok Hong

      Version of Record online: 14 SEP 2017 | DOI: 10.1002/adsc.201701132

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      The front cover picture, provided by Kicheol Kim, illustrates the development of a ruthenium catalytic system for acyl cyanide synthesis via acceptorless dehydrogenation of cyanohydrins. As opposed to the thermodynamically preferred elimination of hydrogen cyanide, the dehydrogenation of cyanohydrins could be kinetically controlled with ruthenium(II) bidentate phosphine complexes. Effects of ligands and counter anions in the ruthenium catalyst were investigated to modulate catalytic activity and selectivity. Details can be found in the communication on pages ###–### (K. Kim, A. M. P. Moeljadi, H. Hirao, S. H. Hong, Adv. Synth. Catal. 2017, 359, ###–###; DOI: 10.1002/adsc.201700786).

  6. Communications

  7. Updates

  8. Full Papers

    1. A Biocatalytic One-Pot Approach for the Preparation of Lignin Oligomers Using an Oxidase/Peroxidase Cascade Enzyme System

      Mohamed H. M. Habib, Peter J. Deuss, Nikola Lončar, Milos Trajkovic and Marco W. Fraaije

      Version of Record online: 14 SEP 2017 | DOI: 10.1002/adsc.201700650

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    2. Synthesis of Indolo-1,2-Benzothiazines from Sulfoximines and 3-Diazoindolin-2-imines

      Gi Hoon Ko, Jeong-Yu Son, Hyunseok Kim, Chanyoung Maeng, Yonghyeon Baek, Boram Seo, Kyusik Um and Phil Ho Lee

      Version of Record online: 14 SEP 2017 | DOI: 10.1002/adsc.201700764

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  9. Updates

    1. Rhodium-Catalyzed Synthesis of Multiaryl-substituted Naphthols via a Removable Directing Group

      Lianhui Wang, Yunliang Yu, Mengqi Yang, Changsheng Kuai, Dingding Cai, Jinfeng Yu and Xiuling Cui

      Version of Record online: 12 SEP 2017 | DOI: 10.1002/adsc.201700726

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  10. Communications

    1. Copper-Catalyzed Decarboxylative Alkylation of Terminal Alkynes

      Changqing Ye, Yajun Li and Hongli Bao

      Version of Record online: 12 SEP 2017 | DOI: 10.1002/adsc.201700798

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    2. A Cooperative Ternary Catalysis System for Asymmetric Lactonizations of α-Ketoesters

      Kathleen J. R. Murauski, Daniel M. Walden, Paul Ha-Yeon Cheong and Karl A. Scheidt

      Version of Record online: 11 SEP 2017 | DOI: 10.1002/adsc.201701015

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  11. Updates

    1. Transition Metal-Catalysed Intramolecular Carbenoid C−H Insertion for Pyrrolidine Formation by Decomposition of α-Diazoesters

      Daniel Solé, Arianna Amenta, Francesco Mariani, M.-Lluïsa Bennasar and Israel Fernández

      Version of Record online: 8 SEP 2017 | DOI: 10.1002/adsc.201700840

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  12. Communications

    1. Metal-Free Nitration of the C(sp3)−H Bonds of 2-Oxindoles through Radical Coupling Reaction at Room Temperature

      Wen-Ting Wei, Wen-Ming Zhu, Wei-Wei Ying, Yi-Ning Wang, Wen-Hui Bao, Le-Han Gao, Yun-Jie Luo and Hongze Liang

      Version of Record online: 8 SEP 2017 | DOI: 10.1002/adsc.201700870

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    2. Diastereoselective Synthesis of Nine-Membered Heterocycles via the Cycloaddition and Sequential Rearrangement of N-Vinyl Nitrones with Isocyanates

      Ning Zou, Ji-Wen Jiao, Yu Feng, Chun-Hua Chen, Cui Liang, Gui-Fa Su and Dong-Liang Mo

      Version of Record online: 8 SEP 2017 | DOI: 10.1002/adsc.201700685

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  13. Full Papers

  14. Communications

    1. Copper(I)-Catalyzed Synthesis of 4,5-Dihydropyrazolo[1,5-a]pyrimidines via Cascade Transformation of N-Propargylic Sulfonylhydrazones with Sulfonyl Azides

      Zong-Cang Ding, Xiao-Ming An, Jia-Hao Zeng, Zhao-Ning Tang and Zhuang-Ping Zhan

      Version of Record online: 7 SEP 2017 | DOI: 10.1002/adsc.201700635

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    2. Palladium-Catalyzed Isocyanide Insertion with Allylic Esters: Synthesis of N-(But-2-enoyl)-N-(tert-butyl)benzamide Derivatives via Intramolecular Acyl Transfer Termination

      Si Chen, Wan-Xu Wei, Jia Wang, Yu Xia, Yi Shen, Xin-Xing Wu, Huanwang Jing and Yong-Min Liang

      Version of Record online: 7 SEP 2017 | DOI: 10.1002/adsc.201700765

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  15. Updates

  16. Communications

  17. Full Papers

    1. A General and Practical Approach for the Synthesis of 1,2,4-Trioxanes Catalyzed by Silica-Ferric Chloride

      Mo Zhang, Yi Han, Jia-Liang Niu and Zhan-Hui Zhang

      Version of Record online: 6 SEP 2017 | DOI: 10.1002/adsc.201700671

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  18. Cover Pictures

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      Site-Selective Rhodium(III)-Catalyzed C−H Amination of 7-Azaindoles with Anthranils: Synthesis and Anticancer Evaluation

      Mijin Jeon, Jihye Park, Prasanta Dey, Yongguk Oh, Hyunjung Oh, Sangil Han, Sung Hee Um, Hyung Sik Kim, Neeraj Kumar Mishra and In Su Kim

      Version of Record online: 6 SEP 2017 | DOI: 10.1002/adsc.201701100

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      The front cover picture, provided by Kim, Mishra and co-workers, illustrates the synthetic strategy for the formation of ortho-aminated N-aryl-7-azaindoles based on the rhodium(III)- or iridium(III)-catalyzed C−H functionalization using anthranils and azides. The synthesized 7-azaindoles were readily transformed into biologically relevant azaindoloacridines, azaindoloacridones, and bis-indoles. Notably, all synthetic products were evaluated for anticancer activity against human breast adenocarcinoma cells, human renal carcinoma cells, and human prostate adenocarcinoma cells. Some of 7-azaindole derivatives displayed potent cytotoxicity competitive with anticancer doxorubicin. Details can be found in the communication on pages XXXX–XXXX (M. Jeon, J. Park, P. Dey, Y. Oh, H. Oh, S. Han, S. H. Um, H. S. Kim, N. K. Mishra, I. S. Kim, Adv. Synth. Catal. 2017, 359, XXXX–XXXX; DOI 10.1002/adsc.201700800).

  19. Communications

    1. Metal-Free O-Arylation of Carboxylic Acid by Active Diaryliodonium(III) Intermediates Generated in situ from Iodosoarenes

      Toshifumi Dohi, Daichi Koseki, Kohei Sumida, Kana Okada, Serina Mizuno, Asami Kato, Koji Morimoto and Yasuyuki Kita

      Version of Record online: 5 SEP 2017 | DOI: 10.1002/adsc.201700843

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  20. Updates

  21. Communications

    1. Construction of Pyridazine Analogues via Rhodium-mediated C-H Activation

      Chao Yang, Feifei Song, Jiean Chen and Yong Huang

      Version of Record online: 31 AUG 2017 | DOI: 10.1002/adsc.201700905

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  22. Updates

    1. Synthesis of Fluorinated Benzo[a]quinolizidines via Visible Light-induced Tandem Substitution of Two Fluorine Atoms in a CF3 Group

      Haoguo Chen, Tiebo Xiao, Linyong Li, Devireddy Anand, Yuwei He and Lei Zhou

      Version of Record online: 29 AUG 2017 | DOI: 10.1002/adsc.201700852

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  23. Communications

    1. Chiral Magnesium(II) Complex-Catalyzed Enantioselective Desymmetrization of meso-Aziridines with Pyrazoles

      Xiangqiang Li, Jing Guo, Lili Lin, Haipeng Hu, Fenzhen Chang, Xiaohua Liu and Xiaoming Feng

      Version of Record online: 24 AUG 2017 | DOI: 10.1002/adsc.201700888

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    2. Ruthenium on Carbon Catalysed Carbon-Carbon Cleavage of Aryl Alkyl Ketones and Aliphatic Aldehydes in Aqueous Media

      Tomohiro Hattori, Hiroki Okami, Tomohiro Ichikawa, Shigeki Mori, Yoshinari Sawama, Yasunari Monguchi and Hironao Sajiki

      Version of Record online: 22 AUG 2017 | DOI: 10.1002/adsc.201700774

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    3. Acceptorless and Base-free Dehydrogenation of Cyanohydrin with (η6-Arene)halide(Bidentate Phosphine)ruthenium(II) Complex

      Kicheol Kim, Adhitya Mangala Putra Moeljadi, Hajime Hirao and Soon Hyeok Hong

      Version of Record online: 22 AUG 2017 | DOI: 10.1002/adsc.201700786

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    4. Double Carbonylation Using Glyoxal (HCOCOH): A Practical Copper-Promoted Synthesis of Isatins from Primary and Secondary Anilines

      Suzie Hui Chin Kuan, Wei Sun, Lu Wang, Chungu Xia, Meng Guan Tay and Chao Liu

      Version of Record online: 22 AUG 2017 | DOI: 10.1002/adsc.201700583

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    5. Synthesis of Fused Heterocycles via One-pot Oxidative O-Arylation, Pd-Catalyzed C(sp3)-H Arylation

      Fenglin Hong, Nannan Lu, Beili Lu and Jiajia Cheng

      Version of Record online: 21 AUG 2017 | DOI: 10.1002/adsc.201700761

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  24. Updates

    1. Expeditious Synthesis of Enantioenriched Tetrahydropyrans via Chemoselective C−N bond Cleavage of Aza-Oxa-Bicyclo[3.2.1]Octanes

      Cecilia Sasso D'Elia, Sébastien Goudedranche, Thierry Constantieux, Marco Bella, Damien Bonne and Jean Rodriguez

      Version of Record online: 17 AUG 2017 | DOI: 10.1002/adsc.201700735

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    2. Catalytic Asymmetric Epoxidation of Electron-Deficient Enynes Promoted by Chiral N,N′-Dioxide-Scandium(III) Complex

      Hang Zhang, Qian Yao, Lili Lin, Chaoran Xu, Xiaohua Liu and Xiaoming Feng

      Version of Record online: 10 AUG 2017 | DOI: 10.1002/adsc.201700555

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  25. Communications

  26. Updates

  27. Communications

    1. Catalytic Asymmetric [4+1] Cyclization of ortho-Quinone Methides with 3-Chlorooxindoles

      Xiao-Li Jiang, Si-Jia Liu, Yu-Qi Gu, Guang-Jian Mei and Feng Shi

      Version of Record online: 19 JUN 2017 | DOI: 10.1002/adsc.201700487

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