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Editor: Michael Rowan; Editorial Board Chairs: Uwe Bornscheuer, Luis A. Oro, Bert Weckhuysen
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ISI Journal Citation Reports © Ranking: 2014: 31/139 (Chemistry Physical)
Online ISSN: 1867-3899
March 24, 2015
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Recently Published Articles
- Copper-Modified Titanium Dioxide: A Simple Photocatalyst for the Chemoselective and Diastereoselective Hydrogenation of Alkynes to Alkenes under Additive-Free Conditions
Dr. Hiroshi Kominami, Megumi Higa, Taketo Nojima, Tomohiko Ito, Dr. Kousuke Nakanishi, Dr. Keiji Hashimoto and Dr. Kazuya Imamura
Version of Record online: 25 MAY 2016 | DOI: 10.1002/cctc.201600290
A “healthy” photocatalyst: Internal alkynes are chemoselectively and diastereoselectively hydrogenated to the corresponding cis-alkenes in alcoholic suspensions of a copper-loaded TiO2 photocatalyst without the use of additives and poisons often used in the case of Lindlar's catalyst.
- Regio- and Stereoselective Synthesis of Dithiocarbonates under Ambient and Solvent-Free Conditions
Johannes Diebler, Dr. Anke Spannenberg and Dr. Thomas Werner
Version of Record online: 25 MAY 2016 | DOI: 10.1002/cctc.201600242
One way or another: A novel method for the atom-economic addition of CS2 to terminal and internal epoxides based on lithium tert-butoxide as the catalyst is developed. This reaction proceeds regio- and stereoselectively. Experimental evidence and 13C NMR spectroscopy experiments support the proposed mechanism.
- Stabilizing Low-Silica Zeolites through Aluminum Sulfate Assisted Cannibalistic Dealumination
Zongbo Shi, Peng Ji, Zhiguo Zhu, Jin-gang Jiang, Dr. Wenhua Fu, Peng Wu, Prof. Yimeng Wang and Prof. Mingyuan He
Version of Record online: 24 MAY 2016 | DOI: 10.1002/cctc.201600211
Get cracking! A versatile dealumination strategy is proposed to stabilize NaY zeolites through cannibalistic interaction between the host framework Al and the guest aluminum sulfate. Possessing greatly enhanced hydrothermal stability, newly formed intracrystal mesopores, and an optimized distribution of framework Al, the resultant dealuminated Y zeolite catalysts can be utilized practically in the catalytic cracking of heavy oil.
- Copper-Catalyzed Intermolecular Aminooxygenation of Styrenes using N-Fluorobenzenesulfonimide and Simple Alcohols
Camilo Herrera-Leyton, Matías Madrid-Rojas, Jhon J. López, Prof. Dr. Álvaro Cañete, Dr. Patricio Hermosilla-Ibáñez and Prof. Dr. Edwin G. Pérez
Version of Record online: 24 MAY 2016 | DOI: 10.1002/cctc.201600254
Cheap and fast: A copper-catalyzed intermolecular aminoalkoxylation of styrenes is reported. The reaction is regioselective and takes place by a radical mechanism by using N-fluorobenzenesulfonimide (NFSI) as the oxidant and nitrogen source and different simple alcohols [e.g., MeOH, EtOH, or benzyl alcohol (BnOH)] as the alkoxy sources to afford 2-alkoxy-N-(bisphenylsulfonamido)phenethylamines.
- Novel Approach for the Characterization of Lewis Acidic Solid Catalysts by Solid-State NMR Spectroscopy
Swen Lang, Michael Benz, Utz Obenaus, Robin Himmelmann and Prof. Dr. Michael Hunger
Version of Record online: 24 MAY 2016 | DOI: 10.1002/cctc.201600372
NMR characterization of Lewis acid sites: Lewis acid sites on TiO2, γ-Al2O3, and lithium-exchanged zeolite Y were studied. 31P MAS NMR spectroscopy of the trimethylphosphine oxide-loaded catalysts allowed the identification of Lewis acid sites from the signals at 48–51 ppm. The site densities were determined by 1H MAS NMR spectroscopy of the ammonia-loaded catalysts and evaluation of the signals at −0.5–3 ppm.