Journal of Polymer Science Part A: Polymer Chemistry
Copyright © 2012 Wiley Periodicals, Inc., A Wiley Company
Impact Factor: 3.543
ISI Journal Citation Reports © Ranking: 2012: 12/83 (Polymer Science)
Online ISSN: 1099-0518
Associated Title(s): Journal of Polymer Science Part B: Polymer Physics
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- Multifunctional linear methacrylate copolymer polyenes having pendant vinyl groups: Synthesis and photoinduced thiol-ene crosslinking polyaddition
So Young An, Ji Won Hwang, Kyung Nam Kim, Hyun Wook Jung, Seung Man Noh and Jung Kwon Oh
Article first published online: 10 DEC 2013 | DOI: 10.1002/pola.27035
UV-induced thiol-ene crosslinked films composed of linear methacrylate copolymers having pendant enes (MCPenes) are reported. Controlled radical polymerization to synthesize well-controlled pendant hydroxyl-containing copolymers (MCPOHs) was combined with the following facile carbodiimide coupling of the formed MCPOHs with enes to allow for the synthesis of well-controlled MCPenes with narrow molecular weight distribution. Under UV irradiation, the resulting MCPenes undergo thiol-ene polyaddition reactions with polythiols to form crosslinked films with a uniform network.
- You have free access to this contentCis/Cis-2,5-dipropenylthiophene monomers for high-molecular-weight poly(2,5-thienylene vinylene)s through acyclic diene metathesis polymerization
Yang Guoshun, Hu Keda and Qin Yang
Article first published online: 7 DEC 2013 | DOI: 10.1002/pola.27042
The synthesis of 2,5-dipropenylthiophene monomer possessing exclusively cis-double bond configurations through reduction of dipropynylthiophene precursor is reported. Lindlar's catalyst was found to be completely ineffective, while a dissolving metal method involving activated zinc proved successful in alkyne reduction to cis-alkenes with high yields and excellent selectivity. Acyclic diene metathesis polymerization of the monomer afforded poly(2,5-thienylene vinylene) polymer of high molecular weight.
- Synthesis, characterization, and applications in photovoltaic cells of oxetane-functionalized P3HT derivatives
Graça Brotas, Joana Farinhas, Quirina Ferreira, Rita Rodrigues, Inês L. Martins, Jorge Morgado and Ana Charas
Article first published online: 7 DEC 2013 | DOI: 10.1002/pola.27041
A series of new crosslinkable conjugated polymers, derivatives of region-regular poly(3-hexylthiophene), are synthesized and investigated in organic photovoltaic devices. The individual effect of the conditions employed in the crosslinking is investigated, and an overall beneficial effect upon crosslinking on the device stability is shown.
- Synthesis and electrochromic properties of triphenylamine containing copolymers: Effect of π-bridge on electrochemical properties
Serife O. Hacioglu, Sinem Toksabay, Merve Sendur and Levent Toppare
Article first published online: 6 DEC 2013 | DOI: 10.1002/pola.27030
Benzotriazole and triphenylamine bearing random copolymers are synthesized. Electrochemical and spectroelectrochemical properties of the P1, P2, and P3 are performed, and the results are highlighted. Promising properties of these materials make them good candidates for electrochromic devices and organic solar cells.
- Effect of permodified β-cyclodextrin on the photophysical properties of poly[2,7-(9,9-dioctylfluorene)-alt-(5,5′-bithiophene)] main chain polyrotaxanes
Aurica Farcas, Giulia Tregnago, Ana-Maria Resmerita, Sarah Taleb Dehkordi, Sophie Cantin, Fabrice Goubard, Pierre-Henri Aubert and Franco Cacialli
Article first published online: 3 DEC 2013 | DOI: 10.1002/pola.27034
Encapsulations of bithiophene units from poly[2,7-(9,9-dioctylfluorene)-alt-(5,5′ -bithiophene)] copolymer chains into persilylated or permethylated β-cyclodextrin cavities, leads to distinct improvements in the solubility, transparency and film forming ability. The photoluminescence exhibits a well-defined vibronic structure with a predominance of the 0-0 transition and a fluorescence lifetime which follows a mono-exponential decay. The increased height of the rod-like structures may indicate a higher tendency of the polyrotaxane chains to organize into fibers in the solid states.