European Journal of Inorganic Chemistry

Cover image for Vol. 2013 Issue 16

Editor: Karen Hindson, Deputy Editor: Preeti Vashi

Impact Factor: 3.049

ISI Journal Citation Reports © Ranking: 2011: 12/44 (Chemistry Inorganic & Nuclear)

Online ISSN: 1099-0682

Associated Title(s): Angewandte Chemie International Edition, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemistryOpen, ChemCatChem, Zeitschrift für anorganische und allgemeine Chemie

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Inorganic Chemistry Meets Life Sciences

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The European Journal of Inorganic Chemistry covers all aspects of inorganic chemistry, including the exciting interface to the life sciences. Read the latest articles:

Francesca Di Sarra, Barbara Fresch, Riccardo Bini, Giacomo Saielli, Alessandro Bagno
Reactivity of Auranofin with Selenols and Thiols – Implications for the Anticancer Activity of Gold(I) Compounds [Full Paper]
Eur. J. Inorg. Chem.2013, 2718–2727.
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Fabio Arnesano, Maurizio Losacco, Giovanni Natile
An Updated View of Cisplatin Transport [Microreview]
Eur. J. Inorg. Chem.2013, 2701–2711.
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Elke Debroye, Svetlana V. Eliseeva, Sophie Laurent, Luce Vander Elst, Stéphane Petoud, Robert N. Muller, Tatjana N. Parac-Vogt
Lanthanide(III) Complexes of Diethylenetriaminepentaacetic Acid (DTPA)–Bisamide Derivatives as Potential Agents for Bimodal (Optical/Magnetic Resonance) Imaging [Full Paper]
Eur. J. Inorg. Chem.2013, 2629–2639.
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Recently Published Articles

  1. Small-Molecule Activation with Molybdenum(0) Complexes Supported by Mixed Imidazol-2-Ylidene/Phosphanyl Hybrid Ligands – Electronic and Structural Consequences of Substituting a Phosphane by a Carbene Group

    Christian Gradert, Jan Krahmer, Frank D. Sönnichsen, Christian Näther and Felix Tuczek

    Article first published online: 22 MAY 2013 | DOI: 10.1002/ejic.201300177

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    Mo carbonyl complexes with mixed N-heterocyclic carbene (NHC)/phosphane ligands and those with pure NHC and phosphane ligands are compared. Whereas the σ-donor strengths of phosphane and carbene groups are comparable, the π-acceptor interactions of the carbene moieties are exactly canceled by π-donor interactions.

  2. Redox-Induced Carbon–Carbon Bond Formation by Using Noninnocent Ligands

    Thomas W. Myers, Gereon M. Yee and Louise A. Berben

    Article first published online: 22 MAY 2013 | DOI: 10.1002/ejic.201300192

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    Oxidation of (IP)2Al(CH3) (IP = iminopyridine) with TrBPh4 (Tr = trityl) affords the C–C-coupled kinetic product [(IP)(Tr-IP)Al(CH3)][BPh4] in which the trityl radical and the IP radical have undergone C–C bond formation. Oxidation of (IP)2Al(CH3) with TrBArF24 affords the thermodynamic product [(IP)(IP)Al(CH3)][BarF24] {BArF24 = tetrakis[(3,5-trifluoromethyl)phenyl]borate}.

  3. Activating Azides and Alkynes for the Click Reaction with [Cu(aNHC)2I] or [Cu(aNHC)2]+ (aNHC = Triazole-Derived Abnormal Carbenes): Structural Characterization and Catalytic Properties

    Stephan Hohloch, Damaris Scheiffele and Biprajit Sarkar

    Article first published online: 22 MAY 2013 | DOI: 10.1002/ejic.201300150

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    Cationic copper(I) complexes containing two triazolylidene carbenes of the abnormal type are shown to be excellent catalysts for the [3+2] cycloaddition reaction between azides and alkynes. A range of azides and a couple of alkynes are activated by these copper(I) complexes towards the catalytic formation of the corresponding substituted 1,2,3-triazoles.

  4. Formation and Reactivity of the Terminal Vanadium Nitride Functionality

    Ba L. Tran, J. Krzystek, Andrew Ozarowski, Chung-Hsing Chen, Maren Pink, Jonathan A. Karty, Joshua Telser, Karsten Meyer and Daniel J. Mindiola

    Article first published online: 22 MAY 2013 | DOI: 10.1002/ejic.201300178

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    The transformation of VIII azides to the corresponding VV nitrides was investigated through isotopic labeling crossover experiments, SQUID magnetization, and multifrequency/high-field EPR studies. While Lewis bases inhibit the azide-to-nitride transformation, nitride complexes are formed by a bimetallic mechanism. Stoichiometric Lewis acid and catalytic amount of VII complex also rendered azide-to-nitride formation. However, Lewis bases inhibit formation of nitride product.

  5. Activation of E–H and E–E (E = S, O) Bonds by Heterobimetallic Zr/Co Complexes: Evidence for Both One- and Two-Electron Processes

    J. Wesley Napoline, Jeremy P. Krogman, Rena Shi, Subramaniam Kuppuswamy, Mark W. Bezpalko, Bruce M. Foxman and Christine M. Thomas

    Article first published online: 22 MAY 2013 | DOI: 10.1002/ejic.201300122

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    A highly reactive phosphanylamide-supported Zr/Co complex has been shown to react with alcohols, thiols, peroxides, and disulfides by means of a dissociative electron-transfer process occurring at Zr. A range of products are formed depending on the identity of the substrate, including both one- and two-electron oxidized products.

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