European Journal of Inorganic Chemistry

Cover image for Vol. 2016 Issue 27

Editor: Karen Hindson, Deputy Editor: Preeti Vashi

Impact Factor: 2.686

ISI Journal Citation Reports © Ranking: 2015: 12/46 (Chemistry Inorganic & Nuclear)

Online ISSN: 1099-0682

Associated Title(s): Angewandte Chemie International Edition, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemistryOpen, ChemCatChem, Zeitschrift für anorganische und allgemeine Chemie

Reaction of 1,3,5-Triazacyclohexanes with TiCl4: Formation of Cationic Complexes (Eur. J. Inorg. Chem. 16/2005)

2005_16/2005The cover picture shows the first crystallographically characterized cationic triazacyclohexane complex of titanium. The hydrogen atoms of the ring-CH2 groups engage in C−H···Cl interactions with the anion (only the shortest shown) and give rise to two characteristic doublets in the 1H NMR spectrum with shifts that are highly dependent on the N-substituents, solvent and anion. The cationic complex is readily formed by the treatment of triazacyclohexanes with excess TiCl4 which often results in large crystals containing the Ti2Cl9 anion. Details are discussed in the article by R. D. Köhn et al. on p. 3217 ff.

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