European Journal of Inorganic Chemistry

Cover image for Vol. 2015 Issue 14

Editor: Karen Hindson, Deputy Editor: Preeti Vashi

Impact Factor: 2.965

ISI Journal Citation Reports © Ranking: 2013: 10/45 (Chemistry Inorganic & Nuclear)

Online ISSN: 1099-0682

Associated Title(s): Angewandte Chemie International Edition, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemistryOpen, ChemCatChem, Zeitschrift für anorganische und allgemeine Chemie

2006_11/2006Titanium–Alkaline Earth Molecular Oxides as Supports for Carbanions Derived from μ3-Ethylidyne Groups (Eur. J. Inorg. Chem. 11/2006)

The cover picture shows how the treatment of the oxide molecular model [{TiCp*(μ-O)}3(μ3-CMe)] (Cp* = η5-C5Me5) with alkaline earth metal amide and alkyl compounds produces the deprotonation of the μ3-ethylidyne fragment to give μ3-CCH2, μ3-CHCH or μ3-CCH2− carbanions. Simultaneously, the alkaline earth cation is incorporated through the oxygen atoms to build new cage structures. Details of this chemistry are described by M. Mena et al. on p. 2137 ff.

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