European Journal of Inorganic Chemistry

Cover image for Vol. 2017 Issue 24

Editor: Karen Hindson, Deputy Editor: Preeti Vashi

Impact Factor: 2.444

ISI Journal Citation Reports © Ranking: 2016: 13/46 (Chemistry Inorganic & Nuclear)

Online ISSN: 1099-0682

Associated Title(s): Angewandte Chemie International Edition, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemistryOpen, ChemCatChem, Zeitschrift für anorganische und allgemeine Chemie

2007_11/2007Mixed-Metal Dawson Sandwich Complexes: Synthesis, Spectroscopic Characterization and Electrochemical Behaviour of Na16[MIICo3(H2O)2(P2W15O56)2] (M = Mn, Co, Ni, Zn and Cd) (Eur. J. Inorg. Chem. 11/2007)

The cover picture shows the synthesis of the mixed-metal Dawson sandwich complexes [MCo3(H2O)2(P2W15O56)2]16− by the addition of the transition metal cation M2+ to the “lacunary” sandwich complex [NaCo3(H2O)2(P2W15O56)2]17−. This “lacunary” species is a good precursor for the preparation mixed-metal sanswich complexes, with promising interesting catalytic, electrocatalytic and magnetic properties. Details of the synthesis and the structural characterization in solution are discussed in the article by L. Ruhlmann and R. Thouvenot on p. 1493 ff.

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