European Journal of Inorganic Chemistry

Cover image for Vol. 2015 Issue 25

Editor: Karen Hindson, Deputy Editor: Preeti Vashi

Impact Factor: 2.942

ISI Journal Citation Reports © Ranking: 2014: 8/44 (Chemistry Inorganic & Nuclear)

Online ISSN: 1099-0682

Associated Title(s): Angewandte Chemie International Edition, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemistryOpen, ChemCatChem, Zeitschrift für anorganische und allgemeine Chemie

2007_27/2007Regiospecific ortho-Aromatic Hydroxylation via Cyclonickelation Using Hydrogen Peroxide and Other Oxygen Donors: Synthesis of Metalloazosalophens (Eur. J. Inorg. Chem. 27/2007)

The cover picture shows the reaction sequence of an NiII-assisted regiospecific ortho-aromatic hydroxylation. Sequential events of orthonickelation, oxygen insertion into the Ni–C bond induced by H2O2 and demetallation have been demonstrated to be involved in the aromatic hydroxylation in 2-(arylazo)aniline. The H2O2-induced O insertion into the Ni–C bond led to the formation of metalloazosalophen analogues of metallosalophens for the first time. Details are discussed in the article by S. Chattopadhyay et al. on p. 4263 ff.

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