European Journal of Inorganic Chemistry

Cover image for Vol. 2016 Issue 27

Editor: Karen Hindson, Deputy Editor: Preeti Vashi

Impact Factor: 2.686

ISI Journal Citation Reports © Ranking: 2015: 12/46 (Chemistry Inorganic & Nuclear)

Online ISSN: 1099-0682

Associated Title(s): Angewandte Chemie International Edition, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemistryOpen, ChemCatChem, Zeitschrift für anorganische und allgemeine Chemie

2009_21/2009Cyclometallated [C,N,O] Complexes as Metalloligands: Synthesis and Structural Characterisation of New Di-, Tri-, Tetra- and Pentanuclear Heterometallic Complexes (Eur. J. Inorg. Chem. 21/2009)

The cover picture shows (left) the new heteropentametallic [{Pd[4-[W(CO)5WNC5H4]C6H3C(H)=N{2'-(O)-5'-tBuC6H3}]}2(μ-PPh25-C5H4)Fe(η5-C5H4)PPh2)] and heterodimetallic [Pd{4-[RuCl2(CO)(PPh3)I2]NC5H3]C(H)=N[2'-(O)-5'-tBuC6H3]}(PPh3)] cyclometallated complexes synthesized from [C,N,O] palladacycles, which behave as metalloligands by coordination through the pyridine nitrogen atom. The crystal structure (right) shows the precursor for the tungsten complex, which like its chromium and molybdenum analogues, requires UV radiation in the preparative process. Details are discussed in the article by J. J. Fernández, J. M. Vila et al. on p. 3071 ff.

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