Applied Organometallic Chemistry

Cover image for Vol. 29 Issue 9

Editor-in-Chief Cornelis J. Elsevier

Impact Factor: 2.248

ISI Journal Citation Reports © Ranking: 2014: 10/44 (Chemistry Inorganic & Nuclear); 19/70 (Chemistry Applied)

Online ISSN: 1099-0739

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BEST PUBLICATION AWARD

2014 WINNER – Congratulations to the 2014 Best Publication Award Winners:

Rosenani A. Haque, Muhammad Adnan Iqbal, Srinivasa Budagumpi, Mohamed B. Khadeer Ahamed, Amin M. S. Abdul Majid and Noorhafizah Hasanudin

Best Publication Award 2014

Binuclear meta-xylyl-linked Ag(I)-N-heterocyclic carbene complexes of N-alkyl/aryl-alkyl-substituted bis-benzimidazolium salts: synthesis, crystal structures and in vitro anticancer studies

Previous Winners

Winner AOC Best Paper Award 2013:

Linjun Shao (left), Jie Liu, Yuhang Ye, Chenze Qi (right) and Xian-Man Zhang

Polyacrylonitrile fiber mat-supported palladium catalyst for Mizoroki-Heck reaction in aqueous solution

Winner AOC Best Paper Award 2012:

An alternative CuCI-piperidine-catalyzed oxidative homocoupling of terminal alkynes affording 1,3-diynes in air
Ruimao Hua, Qingwei Zheng and Youzhi Wan from the Tsinghua University, Beijing , People’s Republic of China

Winner AOC Best Paper Award 2011:

Hemilabile-coordinated copper promoted amination of aryl halides with ammonia in aqueous ethylene glycol under atmosphere pressure
Zhennü Guo, Jiayi Guo, Ying Song, Limin Wang, Gang Zou East China University of Science and Technology, Shanghai, People’s Republic of China

Winner AOC Best Paper Award 2010:

Conversion of carbon dioxide to cyclic carbonates using diimine Ru(ll) complexes as catalysts
Mahmut Ulusoy, Engin Cetinkaya, Bekir Cetinkaya Department of Chemistry, Ege University, Turkey

Winner AOC Best Paper Award 2009:

Modifying the Structure of Dinuclear Ruthenium Complexes with Antitumor Activity
Maria G. Mendoza-Ferri¹, Christian G. Hartinger¹, Alexey A. Nazarov¹, Wolfgang Kandioller¹, Kay Severin² and Bernhard K. Keppler¹. ¹ University of Vienna, Institute of Inorganic Chemistry, Austria. ² Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), Switzerland

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Recently Published Articles

  1. Synthesis, structural characterization, density functional theory calculations and biological evaluation of a new organotin(IV) complex containing N-isonicotinyl-N',N″-diaryl phosphorictriamide as N-donor ligand

    Khodayar Gholivand, Maryam Rajabi, Niloufar Dorosti and Foroogh Molaei

    Article first published online: 1 SEP 2015 | DOI: 10.1002/aoc.3360

    Thumbnail image of graphical abstract

    A new Sn(IV) complex of N-isonicotinyl phosphoramide () was synthesized and characterized. DFT calculations were performed to compare the stability of the complex which showed N-ligated configuration, and its O-ligated form in the gas phase. The effectiveness of ligand and complex was measured against three human tumour cell lines and four bacteria. and ligand exhibit stronger cytotoxicities than cyclophosphamide. Preliminary in vitro studies showed that has antibacterial effects.

  2. Ruthenium(II) complexes derived from C2-symmetric ferrocene-based chiral bis(phosphinite) ligands: synthesis and catalytic activity towards the asymmetric reduction of acetophenones

    B. Ak, F. Durap, M. Aydemir and A. Baysal

    Article first published online: 27 AUG 2015 | DOI: 10.1002/aoc.3364

    Thumbnail image of graphical abstract

    A series of C2-symmetric bis(phosphinite) ruthenium complexes bearing ferrocenyl moieties were developed and evaluated for catalytic activity towards transfer hydrogenation of acetophenone derivatives using 2-propanol in the presence of NaOH. Almost complete conversion and moderate to excellent enantioselectivity were obtained using all the complexes as catalysts at 82°C.

  3. Synthesis, structure and biological activity of new 6,6-dimethyl-2-oxo-4-{2-[5-organylsilyl(germyl)]furan(thiophen)-2-yl}vinyl-5,6-dihydro-2H-pyran-3-carbonitriles

    Luba Ignatovich, Jana Spura, Velta Muravenko, Sergey Belyakov, Juris Popelis, Irina Shestakova, Ilona Domrachova, Anita Gulbe, Zhanna Rudevica and Ainars Leonchiks

    Article first published online: 25 AUG 2015 | DOI: 10.1002/aoc.3363

    Thumbnail image of graphical abstract

    New 6,6-dimethyl-2-oxo-4-{2-[5-alkylsilyl(germyl)]furan(thiophen)-2-yl}-5,6-dihydro-2H-pyran-3-carbonitriles have been prepared by condensation reaction of corresponding silicon- and germanium-containing furyl(thienyl)-2-carbaldehydes with 3-cyano-4,6,6-trimethyl-5,6-dihydropyran-2-one using piperidine acetate as the catalyst. The influence of the heterocycle and organoelement substituent structure on the cytotoxicity and on matrix metalloproteinase inhibition activity has been studied.

  4. Palladium-catalysed reductive carbonylation of aryl halides with iron pentacarbonyl for synthesis of aromatic aldehydes and deuterated aldehydes

    Nasser Iranpoor, Habib Firouzabadi, Elham Etemadi-Davan, Abed Rostami and Khashayar Rajabi Moghadam

    Article first published online: 25 AUG 2015 | DOI: 10.1002/aoc.3356

    Thumbnail image of graphical abstract

    The novel use of iron pentacarbonyl is described in the efficient Pd-catalysed conversion of aryl iodides, bromides and chlorides into their corresponding aryl aldehydes and/or aryl deuterated aldehydes.

  5. Palladium–quaternary phosphonium phase transfer catalyst brush assembly as reusable and environmentally benign catalyst for coupling of aryl halides and sodium tetraphenylborate in neat water

    Abdol R. Hajipour and Ghobad Azizi

    Article first published online: 18 AUG 2015 | DOI: 10.1002/aoc.3355

    Thumbnail image of graphical abstract

    A first example of simultaneous covalent anchoring of a palladate anion–phosphonium cation matrix on the surface of silica nanoparticles and application in the Suzuki coupling reaction of a variety of different haloarenes and sodium tetraphenylborate in neat aqueous media without the addition of any organic co-solvent are described.

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