Applied Organometallic Chemistry
© John Wiley & Sons, Ltd.
Editor-in-Chief Cornelis J. Elsevier
Impact Factor: 2.011
ISI Journal Citation Reports © Ranking: 2012: 17/44 (Chemistry Inorganic & Nuclear); 22/71 (Chemistry Applied)
Online ISSN: 1099-0739
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BEST PUBLICATION AWARD
2013 WINNER – Congratulations to the 2013 Best Publication Award Winners:
Linjun Shao (left), Jie Liu, Yuhang Ye, Chenze Qi (right) and Xian-Man Zhang
Polyacrylonitrile fiber mat-supported palladium catalyst for Mizoroki-Heck reaction in aqueous solution
Winner AOC Best Paper Award 2012:
An alternative CuCI-piperidine-catalyzed oxidative homocoupling of terminal alkynes affording 1,3-diynes in air
Ruimao Hua, Qingwei Zheng and Youzhi Wan from the Tsinghua University, Beijing , People’s Republic of China
Winner AOC Best Paper Award 2011:
Hemilabile-coordinated copper promoted amination of aryl halides with ammonia in aqueous ethylene glycol under atmosphere pressure
Zhennü Guo, Jiayi Guo, Ying Song, Limin Wang, Gang Zou East China University of Science and Technology, Shanghai, People’s Republic of China
Conversion of carbon dioxide to cyclic carbonates using diimine Ru(ll) complexes as catalysts
Mahmut Ulusoy, Engin Cetinkaya, Bekir Cetinkaya Department of Chemistry, Ege University, Turkey
Winner AOC Best Paper Award 2009:
Modifying the Structure of Dinuclear Ruthenium Complexes with Antitumor Activity
Maria G. Mendoza-Ferri¹, Christian G. Hartinger¹, Alexey A. Nazarov¹, Wolfgang Kandioller¹, Kay Severin² and Bernhard K. Keppler¹. ¹ University of Vienna, Institute of Inorganic Chemistry, Austria. ² Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), Switzerland
Recently Published Articles
- RuIII(OTf)SalophenCH2–NHSiO2–Fe: an efficient and magnetically recoverable catalyst for trimethylsilylation of alcohols and phenols with hexamethyldisilazane
Maryam Torki, Shahram Tangestaninejad, Valiollah Mirkhani, Majid Moghadam and Iraj Mohammadpoor-Baltork
Article first published online: 27 FEB 2014 | DOI: 10.1002/aoc.3125
Efficient trimethylsilylation of alcohols and phenols with hexamethyldisilazane (HMDS) catalyzed by ruthenium(III) complex of chloromethylated Salophen supported on nanomagnetic materials is reported. The RuIII(OTf)SalophenCH2-NHSiO2-Fe catalyzed trimethylsilylation of primery and secondary alcohols as well as phenols, and the corresponding TMS-ethers were obtained in high yields and short reaction times at room temperature. This new heterogenized trimethylsilylation catalyst is easily recovered with a magnet and showed no appreciable loss of activity even after five consecutive runs.
- The influence of triphenylantimony(V) catecholate and its spiroendoperoxide on lipid peroxidation
Ivan V. Smolyaninov, Natalia A. Antonova, Andrey I. Poddel'sky, Susanna A. Smolyaninova, Viktoria P. Osipova, Svetlana A. Luzhnova, Nadezhda T. Berberova and Yuri T. Pimenov
Article first published online: 27 FEB 2014 | DOI: 10.1002/aoc.3120
Triphenylantimony(V) 4-methoxy-3,6-di-tert-butylcatecholate and its spiroendoperoxide were examined in the process of lipid peroxidation (in vitro, in vivo) of the line BALB/c mice. The nature of antimony(V) compound - the catecholato form or its spiroendoperoxide derivative - has an opposite effect on the process of lipid peroxidation: the original catecholato complex exhibits inhibiting activity while the spiroendoperoxide plays the role of LP promoter.
- Synthesis of 1-silacyclopent-2-ene derivatives using 1,2-hydroboration, 1,1-organoboration and protodeborylation
Ezzat Khan, Oleg L. Tok and Bernd Wrackmeyer
Article first published online: 27 FEB 2014 | DOI: 10.1002/aoc.3121
The hydroboration followed by intramolecular 1,1-vinylboration of di(alkynyl)vinylsilanes proceeds at ambient temperature to afford 1-alkynyl-1-silacyclopent-2-ene derivatives in sufficiently high quantity. Further hydroboration of Si-C≡C- function was carried out at 80-100°C and 1-alkenyl-1-silacyclopent-2-ene derivatives were obtained. Reactions are highly sterioselective, ≥95% and no side products or isomers were detected. The protodeborylation with an excess amount of acetic acid is of particular interest, since it leaves all other bonds unaffected. The solution-state structural assignments of all new compounds i.e. di(alkyn-1-yl)vinylsilanes and 1-silacyclopent-2-ene derivatives, 1-10 were carried out using multinuclear magnetic resonance techniques (1H, 13C, 11B, 29Si NMR). The gas phase structures and 29Si NMR parameters of some examples 7a,b,10a were calculated and optimised by DFT methods [B3LYP/6-311+G/d,p) level of theory].
- Palladium-catalyzed carbonylation of quaternary ammonium halides to tertiary amides
Yizhu Lei, Rui Zhang, Linjuan Wu, Qing Wu, Hui Mei and Guangxing Li
Article first published online: 17 FEB 2014 | DOI: 10.1002/aoc.3126
Catalytic carbonylation of quaternary ammonium salts under anhydrous condition was investigated by ligand free palladium catalyst. Moderate to excellent yields of tertiary amides was obtained with a relatively low catalyst dosage. The commercial Pd/C catalyst also showed high active for this carbonylation reaction and could be easily recovered and reused.
- 2,5-Bis(2-(diphenylphosphino)phenyl)-1,3,4-oxadiazole ligands and their Cu(I) complexes for Sonogashira coupling reaction
Cai-Xia Lin, Jia-Fang Zhu, Qing-Shan Li, Li-Hua Ao, Yan-Juan Jin, Feng-Bo Xu, Fang-Zhong Hu and Yao-Feng Yuan
Article first published online: 14 FEB 2014 | DOI: 10.1002/aoc.3124
Two diphosphane ligands, 2,5-bis(2-(diphenylphosphino)-5-R)phenyl)-1,3,4-oxadiazole (L1, R = H, L2, R = OMe) and their dinuclear Cu(I) complexes (L1Cu and L2Cu), were synthesized, characterized and applied to catalyze Sonogashira coupling reactions of terminal alkynes and aryl halides in the presence of K2CO3 under Pd-free conditions. The coupling reactions catalyzed by L1 or L2 with Cu(MeCN)4ClO4in situ exhibited better yields than those by L1Cu or L2Cu. The coupling reactions of aryl iodides with electron-withdrawing groups showed better results.