Applied Organometallic Chemistry

Cover image for Vol. 28 Issue 11

Early View (Online Version of Record published before inclusion in an issue)

Editor-in-Chief Cornelis J. Elsevier

Impact Factor: 2.017

ISI Journal Citation Reports © Ranking: 2013: 20/44 (Chemistry Inorganic & Nuclear); 21/71 (Chemistry Applied)

Online ISSN: 1099-0739

VIEW

  1. 1 - 10
  1. Full Papers

    1. Metal–organic framework MIL-125(Ti) for efficient adsorptive removal of Rhodamine B from aqueous solution

      Hongxu Guo, Fan Lin, Jianhua Chen, Feiming Li and Wen Weng

      Article first published online: 23 OCT 2014 | DOI: 10.1002/aoc.3237

      Thumbnail image of graphical abstract

      A metal–organic framework material, MIL-125(Ti), was solvothermally prepared and characterized, and was then used as an adsorbent for Rhodamine B removal in aqueous solution.

    2. Comparison between various Keggin and Wells–Dawson sandwich-type polyoxometalates in catalytic oxidation of cyclooctene and cyclohexene with hydrogen peroxide

      Mostafa Riahi Farsani, Fariba Jalilian, Bahram Yadollahi and Hadi Amiri Rudbari

      Article first published online: 22 OCT 2014 | DOI: 10.1002/aoc.3235

      Thumbnail image of graphical abstract

      Tetra-n-butylammonium salts of [M4(PW9O34)2]m and [M4(P2W15O56)2]n were used as effective catalysts for the oxidation of cyclooctene and cyclohexene under various conditions. Wells–Dawson-type polyoxometalates were less active than Keggin ones. Higher conversions were obtained with Zn- and slightly lower with Fe-substituted polyoxometalates of both sandwich-type compounds.

    3. Polymer-anchored Ru(II) complex as an efficient catalyst for the synthesis of primary amides from nitriles and of secondary amides from alcohols and amines

      Sk Manirul Islam, Kajari Ghosh, Anupam Singha Roy and Rostam Ali Molla

      Article first published online: 21 OCT 2014 | DOI: 10.1002/aoc.3233

      Thumbnail image of graphical abstract

      A new polymer-anchored Ru(II) complex has been synthesized and characterized. The catalytic performance of this complex has been tested for the preparation of primary amides from hydration of nitriles. This catalyst is also effective in the preparation of secondary amides from alcohols and amines.

    4. Synthesis of diaryl thioethers from aryl halides and potassium thiocyanate

      Abdol R. Hajipour, Raheleh Pourkaveh and Hirbod Karimi

      Article first published online: 20 OCT 2014 | DOI: 10.1002/aoc.3230

      Thumbnail image of graphical abstract

      An efficient palladium catalyst was used for the synthesis of wide range of diaryl thioethers under relatively mild reaction conditions via cross-coupling of aryl halides with potassium thiocyanate.

    5. Synthesis and characterization of tributyltin derivatives from 4-oxo-4-(arylamino)butanoic acids and their in vitro biological activity against cervical cancer cell lines

      Irma Rojas-Oviedo, Carlos Camacho-Camacho, Luis Sánchez-Sánchez, Jorge Cárdenas, Hugo López-Muñoz, Hugo Eugenio-Robledo, Israel Velázquez and Rubén Alfredo Toscano

      Article first published online: 20 OCT 2014 | DOI: 10.1002/aoc.3231

      Thumbnail image of graphical abstract

      Uterine (cervix and corpus) cancer is one of the major causes of mortality in women in Mexico. Organotin carboxylated derivatives have been shown to have high cytotoxic activity against various cell lines of human origin. We describe the synthesis of three new tributyltin derivatives, the structures of which were confirmed using spectral data (1H NMR, 13C NMR, 119Sn NMR and infrared), elemental analyses, mass spectrometry and X-ray diffraction. All the compounds showed potency against HeLa, CaSki and ViBo.

    6. Photocatalysis of ethanol oxidation by tetrachloroferrate(III) supported on Dowex 2-X8

      Laura Schembri and Patrick E. Hoggard

      Article first published online: 15 OCT 2014 | DOI: 10.1002/aoc.3229

      Thumbnail image of graphical abstract

      Irradiated at wavelengths above 345 nm, ethanol is oxidized to acetaldehyde (and further to acetic acid) in the presence of FeCl4 supported on a Dowex 2-X8 anion exchange resin.

    7. Sulfamic acid heterogenized on functionalized magnetic Fe3O4 nanoparticles with diaminoglyoxime as a green, efficient and reusable catalyst for one-pot synthesis of substituted pyrroles in aqueous phase

      Hojat Veisi, Pourya Mohammadi and Javad Gholami

      Article first published online: 15 OCT 2014 | DOI: 10.1002/aoc.3228

      Thumbnail image of graphical abstract

      Sulfamic acid heterogenized on functionalized magnetic Fe3O4 nanoparticles with diaminoglyoxime as a green, efficient and reusable catalyst for one-pot synthesis of substituted pyrroles in aqueous phase.

    8. Catalytic activities in direct arylation of novel palladium N-heterocyclic carbene complexes

      Senem Akkoç and Yetkin Gök

      Article first published online: 15 OCT 2014 | DOI: 10.1002/aoc.3220

      Thumbnail image of graphical abstract

      Eight novel palladium N-heterocyclic carbene (Pd-NHC) complexes were synthesized by the reaction of chloro 1,3-dialkylbenzimidazol-2-ylidene silver(I) complexes with bis(benzonitrile)palladium(II) chloride in dichloromethane. These synthesized complexes were fully characterized using spectroscopic and elemental analysis techniques. These novel Pd-NHC complexes were tested as catalysts in the direct arylation of 2-n-butylthiophene, 2-n-butylfuran and 2-isopropylthiazole with various aryl bromides at 130°C for 1 h. The complexes showed very good catalytic activities.

    9. Suzuki–Miyaura reactions promoted by a PdCl2/sulfonate-tagged phenanthroline precatalyst in water

      Qi Li, Li-Ming Zhang, Jia-Jing Bao, Hong-Xi Li, Jing-Bo Xie and Jian-Ping Lang

      Article first published online: 10 OCT 2014 | DOI: 10.1002/aoc.3227

      Thumbnail image of graphical abstract

      The PdCl2/4-(1H-imidazo[4,5-f][1,10]phenanthrolin-1-yl)butane-1-sulfonate catalytic system was employed to catalyze the cross-coupling reaction of arylboronic acid with aryl halide in water. Such a catalytic system could be reused several times.

  2. Book Reviews

VIEW

  1. 1 - 10

SEARCH

SEARCH BY CITATION