Applied Organometallic Chemistry

Cover image for Vol. 29 Issue 2

Early View (Online Version of Record published before inclusion in an issue)

Editor-in-Chief Cornelis J. Elsevier

Impact Factor: 2.017

ISI Journal Citation Reports © Ranking: 2013: 21/71 (Chemistry Applied); 21/45 (Chemistry Inorganic & Nuclear)

Online ISSN: 1099-0739

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  1. 1 - 13
  1. Book Reviews

  2. Full Papers

    1. A versatile method for the synthesis of diaryl and alkyl aryl ketones via palladium-catalysed cross-coupling reaction of arylboronic acids with acyl chlorides

      Fatemeh Rafiee and Abdol R. Hajipour

      Article first published online: 23 JAN 2015 | DOI: 10.1002/aoc.3269

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      The catalytic activity of (BeDABCO)2Pd2Cl6 catalyst was investigated in the synthesis of diaryl and alkyl aryl ketones via cross-coupling reactions of various acyl halides with arylboronic acids.

    2. SnS and SnS2 thin films deposited using a spin-coating technique from intramolecularly coordinated organotin sulfides

      Tomáš Řičica, Lukáš Střižík, Libor Dostál, Marek Bouška, Milan Vlček, Ludvík Beneš, Tomáš Wágner and Roman Jambor

      Article first published online: 23 JAN 2015 | DOI: 10.1002/aoc.3267

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      Application of intramolecularly coordinated organotin(II) sulfide ({2,6-(Me2NCH2)2C6H3}Sn)2(μ-S) (1), organotin(II) thiophenolate {2,6-(Me2NCH2)2C6H3}Sn(SPh) (2) and organotin(IV) heptasulfide {2,6-(Me2NCH2)2C6H3}2Sn2S7 (3) as potential single-source precursors (SSPs) for deposition of SnS or SnS2 thin films using a spin-coating method is reported. While 1 is not a suitable SSP, 2 and 3 were successfully applied for the preparation of amorphous semiconducting thin films of SnS and SnS2, respectively.

    3. Design, synthesis and in vitro cytotoxicity of novel dinuclear platinum(II) complexes with a tetradentate carrier ligand

      Chuan-Zhu Gao, Tian-Shuai Wang, Yan Zhang, Ji Chen, Yun-Xu Qian, Bo Yang and Ying-Jie Zhang

      Article first published online: 23 JAN 2015 | DOI: 10.1002/aoc.3257

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      With the intention of developing new kinds of platinum metallic antitumor drugs which can take full advantages of the merits of oxaliplatin, dinuclear platinum complexes and intercalative interactions, four novel dinuclear platinum complexes with a chiral tetradentate ligand, (1R,1′R,2R,2′R)-N1,N1′-(1,2-phenylenebis(methylene))dicyclohexane-1,2-diamine, were designed, synthesized and characterized, and their in vitro cytotoxicity against four human cancer cell lines was evaluated. Results indicate that compound H4 will be a promising lead compound for further biological evaluations.

    4. Cu(II)–Schiff base complex-functionalized magnetic Fe3O4 nanoparticles: a heterogeneous catalyst for various oxidation reactions

      Arash Ghorbani-Choghamarani, Zahra Darvishnejad and Masoomeh Norouzi

      Article first published online: 15 JAN 2015 | DOI: 10.1002/aoc.3266

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      Nanomagnetic Fe3O4-Cu(II)-Schiff base prepared via post-grafting method. This compound characterized by FT-IR, TGA and SEM techniques and evaluated as catalyst for the oxidation of sulfides and thiols.

    5. Direct arylation of imidazo[2,1-b]thiazoles and thiazoles with aryl iodides via CuCl2/PPh3-catalyzed C–H bond functionalization

      Yuchang Ma, Min Na, Yanfang Gu, Guoli Huang, Xia Li and Yegao Chen

      Article first published online: 15 JAN 2015 | DOI: 10.1002/aoc.3263

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      A new CuCl2/PPh3-catalyzed arylation of imidazo[1,2-b]thiazoles and thiazoles with aryl iodides has been developed. Preliminary mechanistic studies of this arylation are also reported. This protocol provides a straightforward and operationally simple method for the synthesis of trisubstituted imidazo[1,2-b]thiazoles and trisubstituted thiazoles.

    6. Crystal structures and antimicrobial and cytotoxic activities of zinc(II), nickel(II) and copper(II) complexes of N-(piperidylthiocarbonyl)benzamide

      Juan Xie, Zhongqin Cheng, Wen Yang, Huanhuan Liu, Weiqun Zhou, Mengying Li and Yunlong Xu

      Article first published online: 15 JAN 2015 | DOI: 10.1002/aoc.3262

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      A new zinc(II) complex of N-(piperidylthiocarbonyl)benzamide, [ZnL2], has been synthesized and characterized. Its antimicrobial activities were evaluated against fungi and bacteria together with the free ligand, [NiL2] and [CuL2]. The cytotoxic activities of the complexes against hepatocellular carcinoma and breast carcinoma were also investigated.

  3. Book Reviews

  4. Full Papers

    1. Copper nanoparticles on dichromium trioxide: a highly efficient catalyst from copper chromium hydrotalcite for oxidant-free dehydrogenation of alcohols

      Yaoqin Zhu, Mengnan Shen, Yonggen Xia and Ming Lu

      Article first published online: 8 JAN 2015 | DOI: 10.1002/aoc.3261

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      Copper nanoparticles on dichromium trioxide: a highly efficient catalyst from copper chromium hydrotalcite for oxidant-free dehydrogenation of alcohols.

    2. Facile construction of symmetric biaryls using (BeDABCO)2Pd2Cl6 as an efficient and highly active catalyst under microwave irradiation

      Abdol Reza Hajipour and Fatemeh Rafiee

      Article first published online: 8 JAN 2015 | DOI: 10.1002/aoc.3260

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      The catalytic activity of (BeDABCO)2Pd2Cl6 catalyst was investigated in the synthesis of symmetric biaryls via homo-coupling reactions of various aryl halides.

    3. Silica–acetylacetone-supported palladium nanoparticles as an efficient and reusable catalyst in the Heck–Mizoroki C[BOND]C cross-coupling reaction

      Abdolreza Hajipour, Zohre Shirdashtzade and Ghobad Azizi

      Article first published online: 8 JAN 2015 | DOI: 10.1002/aoc.3259

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      In this paper, preparation of supported palladium nanoparticles on acetyl acetone modified silica gel and its catalytic application for Heck olefination of aryl halides is investigated.

    4. Benzimidazole-based silver(I)–N-heterocyclic carbene complexes as anti-bacterials: synthesis, crystal structures and nucleic acids interaction studies

      Patrick O. Asekunowo, Rosenani A. Haque, Mohd. R. Razali and Srinivasa Budagumpi

      Article first published online: 16 DEC 2014 | DOI: 10.1002/aoc.3256

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      A new series of mononuclear and dinuclear Ag(I)–N-heterocyclic carbene complexes of benzimidazolium salts were synthesized. These compounds were examined for their anti-bacterial activities. The benzimidazolium salts did not act as anti-bacterial agents at the working concentrations, but showed good bacteriostatic activity when combined with silver.

    5. Synthesis, characterization and corrosion inhibition in acid medium of l-histidine Schiff base complexes

      Kamal Y. El-Baradie, Nadia A. El-Wakiel and Hoda A. El-Ghamry

      Article first published online: 4 DEC 2014 | DOI: 10.1002/aoc.3255

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      The corrosion inhibition effect of l-histidine Schiff bases and their Co(II), Ni(II) and Cu(II) complexes on aluminium sheets in 2.0 M H2SO4 was studied using the weight loss method. The inhibition efficiency was found to increase with increasing inhibitor concentration and temperature. The increase in inhibition efficiency with increasing temperature is suggestive of a chemical adsorption process.

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