Journal of Physical Organic Chemistry

Cover image for Vol. 26 Issue 6

Editor-in-Chief: Luis Echegoyen

Impact Factor: 1.963

ISI Journal Citation Reports © Ranking: 2011: 31/56 (Chemistry Organic); 69/134 (Chemistry Physical)

Online ISSN: 1099-1395

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  1. Effect of microheterogeneity of CF3CH2OH–H2O mixed solvent on reactions of carbocations from 1,2,2,3-tetramethyl-1,2-dihydroquinoline

    Tatiana D. Nekipelova, Olga N. Lygo, Evgenii N. Khodot and Lidiya N. Kurkovskaya

    Article first published online: 22 MAY 2013 | DOI: 10.1002/poc.3135

    Thumbnail image of graphical abstract

    The maximum value of the rate constant of the intermediate carbocation decay and the formation of oligomeric products in the photolysis of 1,2,2,3-tetramethyl-1,2-dihydroquinoline () in the TFE-H2O mixture 3 : 7 (v/v) were accounted for by the formation of a pseudo-phase of TFE clusters, where the molecules of 1 are concentrated, and the carbocations are generated. TFE, H2O, and compete in the combination reaction with the carbocation.

  2. Issue Information (pages i–iii)

    Article first published online: 22 MAY 2013 | DOI: 10.1002/poc.3038

  3. Use of N-chloro-N-methyl-p-toluenesulfonamide in N-chlorination reactions

    Cristina Pastoriza, Juan Manuel Antelo and Juan Crugeiras

    Article first published online: 20 MAY 2013 | DOI: 10.1002/poc.3127

    Thumbnail image of graphical abstract

    N-chloro-N-methyl-p-toluensulfonamide is a particularly chlorinating agent. The kinetic behaviour has been studied in the formation reaction of N-chloramines using ten nitrogenous compounds.

  4. Effect of aromaticity on the rate of azaquinone methide-mediated release of benzylic phenols

    Kyle M. Schmid and Scott T. Phillips

    Article first published online: 20 MAY 2013 | DOI: 10.1002/poc.3129

    Thumbnail image of graphical abstract

    In small molecule models of stimuli-induced degradable polymers, less aromatic releasing units provide faster rates of azaquinone methide-mediated release of benzylic phenols than highly aromatic releasing units.

  5. Spectroscopic characterization, photoinduced processes and cytotoxic properties of substituted N-ethyl selenadiazoloquinolones

    Zuzana Barbieriková, Maroš Bella, Ľudmila Sekeráková, Jozef Lietava, Miroslava Bobeničová, Dana Dvoranová, Viktor Milata, Jana Sádecká, Dominika Topoľská, Tomáš Heizer, Roman Hudec, Adriana Czímerová, Soňa Jantová and Vlasta Brezová

    Article first published online: 20 MAY 2013 | DOI: 10.1002/poc.3133

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    7-R-9-ethyl-6,9-dihydro-6-oxo-[1,2,5]selenadiazolo[3,4-h]quinolines and 6-ethyl-6,9-dihydro-9-oxo-[1,2,5]selenadiazolo[3,4-f]quinoline were synthesized and characterized by UV/vis, FT-IR and fluorescence spectroscopy; the generation of superoxide radical anions and singlet oxygen was monitored by electron paramagnetic resonance spin trapping technique and sterically hindered amine oxidation.

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