ChemPhysChem

Cover image for Vol. 17 Issue 16

Editor: Greta Heydenrych; Editorial Board Chairs: Christian Amatore, Michael Grätzel, Michel Orrit

Impact Factor: 3.138

ISI Journal Citation Reports © Ranking: 2015: 8/35 (Physics Atomic Molecular & Chemical); 50/144 (Chemistry Physical)

Online ISSN: 1439-7641

Associated Title(s): Advanced Materials, ChemBioChem, ChemCatChem, ChemElectroChem, ChemPhotoChem, ChemSusChem, Small

13_17/2012Cover Picture: Stable and Temperature-Responsive Surfactant-Free Foamulsions with High Oil-Volume Fraction (ChemPhysChem 17/2012)

On p. 3777 A. R. Patel, K. P. Velikov et al. present a surfactant-free food-grade approach to generate complex multiphase systems (foamulsions) with a high oil-volume fraction (ϕoil=0.5) stabilized by molecular complexes of two food-grade materials (methylcellulose and tannic acid). Enhanced stability of the foams in the presence of a high amount of oil is likely due to the increased bulk viscoelasticity of the dispersions caused by the jamming of oil droplets around the air bubbles. The preferred localization of the oil in the foam phase is exploited to generate intensely colored foams by the incorporation of oil-soluble colorants, thus providing an interesting alternative to solve a long-standing problem of generating richly colored stable foams. Further, due to the temperature-dependent gelling of the molecular complexes and the consequent coalescence of densely-packed oil droplets, the foamulsions show temperature responsiveness by quickly destabilizing at 65 °C. This interesting functional property of the generated foamulsion can find important applications in washing operations and oil and material recovery processes, where stabilization and controlled destabilization of foams is desired.

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