Chemistry - A European Journal

Cover image for Vol. 22 Issue 23

Editor: Neville Compton, Deputy Editors: Anne Deveson, Elisabeth Roedern

Impact Factor: 5.731

ISI Journal Citation Reports © Ranking: 2014: 22/157 (Chemistry Multidisciplinary)

Online ISSN: 1521-3765

Associated Title(s): Angewandte Chemie International Edition, Chemistry – An Asian Journal, ChemistryOpen, ChemistrySelect, ChemBioChem, ChemCatChem, ChemElectroChem, ChemMedChem, ChemPhysChem, ChemPlusChem, ChemSusChem, European Journal of Inorganic Chemistry, European Journal of Organic Chemistry

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Recently Published Articles

  1. Direct Metal-Free Entry to Aminocyclobutenes or Aminocyclobutenols from Ynamides: Synthetic Applications

    Prof. Dr. Benito Alcaide, Prof. Dr. Pedro Almendros and Carlos Lázaro-Milla

    Version of Record online: 27 MAY 2016 | DOI: 10.1002/chem.201601044

    Thumbnail image of graphical abstract

    Bis(triflyl)aminocyclobutenes, 2-amino-3-(triflyl)cyclobut-2-enols, or aminocyclobutenyl ethers from ynamides are prepared by a regioselective [2+2] cycloaddition or a cyclization/hydroxylation (hydroalkoxylation) sequence. These functionalized aminocyclobutenes are coverted into α-amino-β,γ-unsaturated ketones or 3-(triflyl)buta-1,3-dien-2-amines through 4 π-electrocyclic ring-opening reactions.

  2. Aniline-Promoted Cyclization–Replacement Cascade Reactions of 2-Hydroxycinnamaldehydes with Various Carbonic Nucleophiles through In Situ Formed N,O-Acetals

    Chenguang Yu, He Huang, Xiangmin Li, Prof. Dr. Yueteng Zhang, Hao Li and Prof. Dr. Wei Wang

    Version of Record online: 27 MAY 2016 | DOI: 10.1002/chem.201601112

    Thumbnail image of graphical abstract

    Cascade catalysis: New reactivity of N,O-acetals has been harnessed in an aminocatalytic cascade fashion for the efficient synthesis of 2-substituted 2H-chromenes.

  3. Manganese-Mediated C−H Alkylation of Unbiased Arenes Using Alkylboronic Acids

    Dr. Susana Castro, Juan J. Fernández, Prof. Dr. Francisco J. Fañanás, Dr. Rubén Vicente and Prof. Félix Rodríguez

    Version of Record online: 27 MAY 2016 | DOI: 10.1002/chem.201601482

    Thumbnail image of graphical abstract

    The alkylation of simple arenes, usually performed by the traditional Friedel–Crafts reaction, may also be achieved by an alternative and competitive method involving alkylboronic acids as alkylating reagents and a manganese(III) salt as promoter (see scheme).

  4. The Origin of Anti-Markovnikov Regioselectivity in Alkene Hydroamination Reactions Catalyzed by [Rh(DPEphos)]+

    Almudena Couce-Rios, Prof. Dr. Agustí Lledós and Dr. Gregori Ujaque

    Version of Record online: 25 MAY 2016 | DOI: 10.1002/chem.201504645

    Thumbnail image of graphical abstract

    Crossing paths: The reaction mechanism for intermolecular hydroamination of alkenes catalyzed by [Rh(DPEphos)]+ complex was analyzed by means of DFT calculations (see scheme). Hydroamination (alkene vs. amine activation routes) as well as oxidative amination pathways were analyzed.

  5. Supramolecular Gels by Design: Towards the Development of Topical Gels for Self-Delivery Application

    Rumana Parveen and Prof. Dr. Parthasarathi Dastidar

    Version of Record online: 25 MAY 2016 | DOI: 10.1002/chem.201600105

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    Anti-inflammatory gel: A supramolecular synthon approach has been adopted to generate a series of simple organic salts of ibuprofen. These are capable of forming topical gels, which proved to be useful both in vitro and in vivo to treat skin inflammation.

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