Chemistry - A European Journal
© WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Editor: Neville Compton, Deputy Editors: Anne Deveson, Elisabeth Roedern
Impact Factor: 5.771
ISI Journal Citation Reports © Ranking: 2015: 24/163 (Chemistry Multidisciplinary)
Online ISSN: 1521-3765
Associated Title(s): Angewandte Chemie International Edition, Chemistry – An Asian Journal, ChemistryOpen, ChemistrySelect, ChemBioChem, ChemCatChem, ChemElectroChem, ChemMedChem, ChemPhotoChem, ChemPhysChem, ChemPlusChem, ChemSusChem, European Journal of Inorganic Chemistry, European Journal of Organic Chemistry
Recently Published Articles
- Constructing a Nonfluorescent Conformation of AIEgen: A Tetraphenylethene Embedded in the Calixarene's Skeleton
Bin Han, Dr. Xi Wang, Yan Gao and Dr. Ming Bai
Version of Record online: 28 SEP 2016 | DOI: 10.1002/chem.201604062
Switching off the light: Utilizing the diphenylmethane nature of the meso-position of calixarene, a tetraphenylethene unit could be embedded in the calix scaffold. This bottom rim modification adjusts the conformation of the calixarene. In the cone conformation, a nonfluorescent conformation of tetraphenylethene could be obtained.
- Efficient Self-Contained Photoacid Generator System Based on Photochromic Terarylenes
Ruiji Li, Dr. Takuya Nakashima, Rui Kanazawa, Dr. Olivier Galangau and Prof. Tsuyoshi Kawai
Version of Record online: 28 SEP 2016 | DOI: 10.1002/chem.201603768
Let there be acid: An elimination reaction of an acid molecule was combined as a subsequent reaction of a photochromic 6π-electrocyclization reaction of terarylenes, which was applied in a chemically amplified resist system (see figure).
- Ate Complexes in Iron-Catalyzed Cross-Coupling Reactions
Tobias Parchomyk and Prof. Dr. Konrad Koszinowski
Version of Record online: 28 SEP 2016 | DOI: 10.1002/chem.201603574
Iron up close and personal: Analysis of iron-catalyzed cross-coupling reactions by electrospray-ionization mass spectrometry finds a multitude of anionic organoferrate complexes covering a remarkable range of different oxidation states. Gas-phase fragmentation experiments afford in-depth insight into the reactivity of these elusive species.
- Aggregation-Induced Emission and Sensing Characteristics of Triarylborane–Oligothiophene–Dicyanovinyl Triads
George Rajendra Kumar, Samir Kumar Sarkar and Prof. Dr. Pakkirisamy Thilagar
Version of Record online: 28 SEP 2016 | DOI: 10.1002/chem.201603349
Hazard detectors: The design and synthesis of a series of triarylborane–oligothiophene–dicyanovinyl triads 4–6 (A–D–A’) is reported (see figure). The optical properties of 4–6 were elegantly modulated by judiciously varying the number of thiophenyl spacer between the acceptors. Compounds 5 and 6 are AIE active and also exhibit significant luminescence in a PMMA matrix. Filter paper strips coated with compounds 5 and 6 can detect F− and CN− in aqueous media with different colorimetric responses.
- Copper Complexes of New Redox-Active 4,5-Bisguanidino-Substituted Benzodioxole Ligands: Control of the Electronic Structure by Counter-Ligands, Solvent, and Temperature
David Fridolin Schrempp, Dr. Elisabeth Kaifer, Prof. Hubert Wadepohl and Prof. Hans-Jörg Himmel
Version of Record online: 28 SEP 2016 | DOI: 10.1002/chem.201602402
Redox-active guys: The electronic structure of mononuclear copper complexes featuring new redox-active 4,5-bisguanidino-substituted benzodioxole ligands can be controlled by several parameters and a temperature-dependent equilibrium between two tautomeric forms (CuII/neutral ligand and CuI/radical monocationic ligand) can be achieved. One electron removal leads to a redox-induced electron transfer (RIET; see figure).