Chemistry - A European Journal

Cover image for Vol. 20 Issue 17

Editor: Neville Compton, Deputy Editors: Anne Deveson, Elisabeth Roedern

Impact Factor: 5.831

ISI Journal Citation Reports © Ranking: 2012: 21/152 (Chemistry Multidisciplinary)

Online ISSN: 1521-3765

Associated Title(s): Angewandte Chemie International Edition, Chemistry – An Asian Journal, ChemistryOpen, ChemBioChem, ChemCatChem, ChemElectroChem, ChemMedChem, ChemPhysChem, ChemPlusChem, ChemSusChem, European Journal of Inorganic Chemistry, European Journal of Organic Chemistry

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January 30, 2014

ChemPlusChem 1/2014: New Features to Delight our Readers

ChemPlusChem 1/2014: New Features to Delight our Readers

In this issue, Petr Cigler, T. Govindaraju, and Radim Beranek are the first authors to feature as part of the new Early Career Series. Also, Petr Cigler was selected to give the inaugural interview, in which he discusses his career and research achievements. Of course the popular Cover Profiles continue, and an article on efficient DNA triplex–forming oligonucleotides by Vyacheslav Filichev and Carlos González is highlighted this month.

Take a look at this issue's hot papers by José López–de–Luzuriaga, Claudia Tomasini, Clair Carmalt, Silvia Cavalli and by our board members Eiji Yashima and Luisa De Cola.

Browse Issue 1/2014 now for free!

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Recently Published Articles

  1. Nanostructured Graphene/TiO2 Hybrids as High-Performance Anodes for Microbial Fuel Cells

    Cui-e Zhao, Wen-Jing Wang, Dong Sun, Dr. Xin Wang, Prof. Jian-Rong Zhang and Prof. Jun-Jie Zhu

    Article first published online: 17 APR 2014 | DOI: 10.1002/chem.201400272

    Thumbnail image of graphical abstract

    Microwave-assisted solvothermal synthesis of TiO2 on graphene led to the assembly of nanostructured G/TiO2 hybrids. The as-synthesized 20 % graphene /TiO2 hybrid exhibited effective bacterial adhesion (see figure) and high power density when used as an anode material in microbial fuel cells.

  2. Solvothermal Transformation of Calcium Oleate Precursor into Large-Sized Highly Ordered Arrays of Ultralong Hydroxyapatite Microtubes

    Dr. Bing-Qiang Lu, Prof. Dr. Ying-Jie Zhu, Feng Chen, Chao Qi, Xin-Yu Zhao and Jing Zhao

    Article first published online: 17 APR 2014 | DOI: 10.1002/chem.201400252

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    By the skin of your teeth: Tooth enamel consists of highly organized arrays of hydroxyapatite (HAP) crystallites. The solvothermal synthesis of millimeter-scale 3D highly ordered arrays of ultralong HAP microtubes inspired by tooth enamel is reported. The ordered HAP microtube arrays form the shell of a core–shell-structured oblate sphere with a core of unordered HAP nanorods and a diameter of 6 mm (see figure).

  3. Chemical and Toxicological Investigations of a Previously Unknown Poisonous European Mushroom Tricholoma terreum

    Xia Yin, Dr. Tao Feng, Prof. Jian-Hua Shang, Yun-Li Zhao, Fang Wang, Zheng-Hui Li, Ze-Jun Dong, Prof. Dr. Xiao-Dong Luo and Prof. Dr. Ji-Kai Liu

    Article first published online: 17 APR 2014 | DOI: 10.1002/chem.201400226

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    Murderous mushroom identified: A chemical investigation of the fruiting bodies of the mushroom Tricholoma terreum led to the isolation of 15 new triterpenoids including three that possessed a unique 5/6/7 trioxaspiroketal system and three that possessed an unprecedented carbon skeleton (see figure). Two compounds, saponaceolide B and saponaceolide M, were abundantly expressed in the mushroom and displayed acute toxicity, with LD50 values of 88.3 and 63.7 mg kg−1, respectively.

  4. All-Nitrogen Analogue of Ozone: Li3N3 Species

    Prof. Dr. Jared K. Olson, Alexander S. Ivanov and Prof. Dr. Alexander I. Boldyrev

    Article first published online: 17 APR 2014 | DOI: 10.1002/chem.201402572

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    Polynitrogen ozone-like molecule: A theoretical prediction of a new polynitrogen molecule is reported. The geometry, electronic, and structural properties of Li3N3 with an unusual N33− kernel were studied using ab initio calculations. Chemical bonding analysis of Li3N3 reveals the same bonding pattern as in ozone molecule (see figure).

  5. Multicomponent, Flow Diazotization/Mizoroki–Heck Coupling Protocol: Dispelling Myths about Working with Diazonium Salts

    Dr. Kumara S. Nalivela, Michael Tilley, Dr. Michael A. McGuire and Prof. Michael G. Organ

    Article first published online: 17 APR 2014 | DOI: 10.1002/chem.201402092

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    Diazonium salts in flow: A single pass flow diazotization/Mizoroki–Heck protocol has been developed for the production of cinnimoyl and styryl products. The factors that govern aryl diazonium salt stability have been examined in detail leading to the development of a MeOH/DMF co-solvent system in which the diazonium salts can be generated in the presence of all other reaction components and then coupled selectively (see scheme).

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