Chemistry - A European Journal
Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Editor: Neville Compton, Deputy Editors: Anne Deveson, Elisabeth Roedern
Impact Factor: 5.831
ISI Journal Citation Reports © Ranking: 2012: 21/152 (Chemistry Multidisciplinary)
Online ISSN: 1521-3765
Associated Title(s): Angewandte Chemie International Edition, Chemistry – An Asian Journal, ChemistryOpen, ChemBioChem, ChemCatChem, ChemElectroChem, ChemMedChem, ChemPhysChem, ChemPlusChem, ChemSusChem, European Journal of Inorganic Chemistry, European Journal of Organic Chemistry
The cover picture shows the highest occupied molecular orbital of hemispiro[2.2]octaplane, which is a lone pair at the central carbon atom. This is responsible for the remarkably high basicity (greater than that for “proton sponge”) predicted for hemispiro[2.2]octaplane and related hemialkaplanes (depicted around the edges). The structures and properties predicted by ab initio molecular orbital calculations for these novel hydrocarbons are described in detail by D. R. Rasmussen and L. Radom on p. 2470 ff.