Chemistry - A European Journal

Cover image for Vol. 23 Issue 42

Editor: Neville Compton, Deputy Editors: Anne Deveson, Elisabeth Roedern

Impact Factor: 5.317

ISI Journal Citation Reports © Ranking: 2016: 29/166 (Chemistry Multidisciplinary)

Online ISSN: 1521-3765

Associated Title(s): Angewandte Chemie International Edition, Chemistry – An Asian Journal, ChemistryOpen, ChemistrySelect, ChemBioChem, ChemCatChem, ChemElectroChem, ChemMedChem, ChemPhotoChem, ChemPhysChem, ChemPlusChem, ChemSusChem, European Journal of Inorganic Chemistry, European Journal of Organic Chemistry

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July 28, 2017

Hot Paper: Tetrameric and Dimeric [N⋅⋅⋅I+⋅⋅⋅N] Halogen-Bonded Supramolecular Cages

Lotta Turunen, Dr. Anssi Peuronen, Samu Forsblom, Dr. Elina Kalenius, Dr. Manu Lahtinen and Prof. Kari Rissanen

Tetrameric and Dimeric [N⋅⋅⋅I+⋅⋅⋅N] Halogen-Bonded Supramolecular Cages

My body is a cage: Applying the robust [N⋅⋅⋅Ag+⋅⋅⋅N][RIGHTWARDS ARROW][N⋅⋅⋅I+⋅⋅⋅N] cation exchange reaction to silver metallocages from tripodal N-donor halogen ligands results in the corresponding halonium cages (see figure).

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July 28, 2017

Hot Paper: Selective Catalytic Performances of Noble Metal Nanoparticle@MOF Composites: The Concomitant Effect of Aperture Size and Structural Flexibility of MOF Matrices

Luning Chen, Dr. Wenwen Zhan, Huihuang Fang, Zhenmin Cao, Chaofan Yuan, Prof. Zhaoxiong Xie, Prof. Qin Kuang and Prof. Lansun Zheng

Selective Catalytic Performances of Noble Metal Nanoparticle@MOF Composites: The Concomitant Effect of Aperture Size and Structural Flexibility of MOF Matrices

Going through the motions: Two composite catalysts (Pt@ZIF-8 and Pt@ZIF-71) were designed and synthesized to investigate the concomitant effect of aperture size and structural flexibility of metal–organic framework matrices in catalysis. Compared to the Pt NPs sheathed with the rigid MOFs (Pt@ZIF-71), the Pt@ZIF-8 composite catalyst exhibited higher conversion but lower selectivity owing to the flexible structure of ZIF-8 matrices.

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July 28, 2017

Hot Paper: Vertical-Aligned Li2S–Graphene Encapsulated within a Carbon Shell as a Free-Standing Cathode for Lithium–Sulfur Batteries

Donghuang Wang, Dr. Xinhui Xia, Dr. Yadong Wang, Dong Xie, Yu Zhong, Dr. Jianbo Wu, Dr. Xiuli Wang and Prof. Jiangping Tu

Vertical-Aligned Li2S–Graphene Encapsulated within a Carbon Shell as a Free-Standing Cathode for Lithium–Sulfur Batteries

Support your local batteries! A facile strategy is demonstrated for fabricating free-standing vertical graphene (VG) supported Li2S encapsulated within carbon shell (VG/Li2S-C) cathode, which exhibits enhanced electrochemical performance with high capacity and noticeable cycles due to the unique architecture coherent conductive network and good blocking layer for polysulfides (see figure).

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July 28, 2017

Hot Paper: An Exceptionally Water Stable Metal–Organic Framework with Amide-Functionalized Cages: Selective CO2/CH4 Uptake and Removal of Antibiotics and Dyes from Water

Wei-Guang Jin, Wei Chen, Pei-Hang Xu, Xin-Wen Lin, Prof. Dr. Xiao-Chun Huang, Prof. Dr. Guang-Hui Chen, Prof. Dr. Fushen Lu and Prof. Dr. Xiao-Ming Chen

An Exceptionally Water Stable Metal–Organic Framework with Amide-Functionalized Cages: Selective CO2/CH4 Uptake and Removal of Antibiotics and Dyes from Water

Waterproof MOF: An exceptionally water stable metal–organic framework (MOF) with amide-functionalized cages (see figure), namely, PCN-124-stu(Cu), was synthesized, and its porous structure exhibits selective adsorption CO2/CH4. Furthermore, PCN-124-stu(Cu) can serve as a platform for removal of antibiotic and dye pollutants from water.

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July 28, 2017

Hot Paper: A Guide for the Design of Functional Polyaromatic Organophosphorus Materials

Philip Hindenberg, Alicia López-Andarias, Dr. Frank Rominger, Dr. Abel de Cózar and Dr. Carlos Romero-Nieto

A Guide for the Design of Functional Polyaromatic Organophosphorus Materials

Tracing the lines: Detailed investigations on a series of polycyclic organophosphorus materials containing six-membered phosphorus heterocycles reveal the key parameters for the synthesis of functional architectures with different electrochemical behaviors, fluorescence quantum yields up to 0.8, and versatile means to keep control over the nature of the photo-induced excited states and the 3D molecular arrangement in the solid state.

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July 28, 2017

VIP: High-Energy-Resolution X-ray Absorption Spectroscopy for Identification of Reactive Surface Species on Supported Single-Site Iridium Catalysts

Dr. Adam S. Hoffman, Dr. Dimosthenis Sokaras, Shengjie Zhang, Louise M. Debefve, Chia-Yu Fang, Dr. Alessandro Gallo, Dr. Thomas Kroll, Prof. Dr. David A. Dixon, Dr. Simon R. Bare and Prof. Dr. Bruce C. Gates

High-Energy-Resolution X-ray Absorption Spectroscopy for Identification of Reactive Surface Species on Supported Single-Site Iridium Catalysts

Beam me up, Scotty! High-energy-resolution X-ray absorption spectroscopy is combined with density functional theory and FEFF simulations ascribing spectral features to adsorbates on single-site supported iridium catalyst, pushing detection limits below those of conventional infrared spectroscopy.

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July 27, 2017

Hot Paper: Catalytic Dehydrogenative Coupling of Hydrosilanes with Alcohols for the Production of Hydrogen On-demand: Application of a Silane/Alcohol Pair as a Liquid Organic Hydrogen Carrier

David Ventura-Espinosa, Alba Carretero-Cerdán, Dr. Miguel Baya, Prof. Hermenegildo García and Dr. Jose A. Mata

Catalytic Dehydrogenative Coupling of Hydrosilanes with Alcohols for the Production of Hydrogen On-demand: Application of a Silane/Alcohol Pair as a Liquid Organic Hydrogen Carrier

On demand! An effective supported ruthenium catalyst on the surface of rGO controls the hydrogen production from hydrosilanes. The hydrogen storage properties show the potential application of the silane/alcohol pair as an efficient liquid organic hydrogen carrier.

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July 27, 2017

Hot Paper: Biphasic Liquid Crystal and the Simultaneous Measurement of Isotropic and Anisotropic Parameters by Spatially Resolved NMR Spectroscopy

Malin Reller, Svenja Wesp, Dr. Martin R. M. Koos, Prof. Dr. Michael Reggelin and Prof. Dr. Burkhard Luy

Biphasic Liquid Crystal and the Simultaneous Measurement of Isotropic and Anisotropic Parameters by Spatially Resolved NMR Spectroscopy

Two for One! A chiral polymer forming a biphasic lyotropic liquid crystalline sample is introduced, which allows measurement of both isotropic and anisotropic NMR data in a single sample. A characterization of the biphasic system, spatially discriminative NMR pulse sequences, and an example for prochiral assignment as well as enantiodiscrimination is provided.

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July 27, 2017

Hot Paper: Soluble Platinum Nanoparticles Ligated by Long-Chain N-Heterocyclic Carbenes as Catalysts

Dr. Luis M. Martínez-Prieto, Lena Rakers, Dr. Angela M. López-Vinasco, Dr. Israel Cano, Dr. Yannick Coppel, Dr. Karine Philippot, Prof. Frank Glorius, Prof. Bruno Chaudret and Prof. Piet W. N. M. van Leeuwen

Soluble Platinum Nanoparticles Ligated by Long-Chain N-Heterocyclic Carbenes as Catalysts

Telling a tall tail: soluble platinum nanoparticles ligated by two different long-chain N-heterocyclic carbenes (Pt@LC-IPr and Pt@LC-IMe) show marked differences in their catalytic activity depending on the bulkiness of the N-substituents. While Pt@LC-IMe behaves similarly to heterogeneous catalysts, the catalytic activity of Pt@LC-IPr parallels that of molecular complexes in the hydroboration of phenylacetylene.

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July 25, 2017

Hot Paper: Selectivity of C−H versus C−F Bond Oxygenation by Homo- and Heterometallic Fe4, Fe3Mn, and Mn4 Clusters

Dr. Graham de Ruiter, Kurtis M. Carsch, Dr. Michael K. Takase and Prof. Theodor Agapie

Selectivity of C−H versus C−F Bond Oxygenation by Homo- and Heterometallic Fe4, Fe3Mn, and Mn4 Clusters

Oxygen atom transfer: The selectivity of intramolecular C(sp2)−H versus C(sp2)−F bond oxygenation was examined with a new series of [LM3(PhPz)3OM′][OTf]2 (M, M′=Fe or Mn) clusters. The distribution of metal centers within these clusters provided insight into how a single metal center (Fe vs. Mn) can control the selectivity of oxygenation chemistry. Although for iron (M=Fe, M′=Fe) essentially exclusive C(sp2)−F bond oxygenation was observed, with manganese (M=Fe or Mn, M′=Mn), C(sp2)−H oxygenation was preferred (see scheme).

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July 25, 2017

Hot Paper: Nitrato-Functionalized Task-Specific Ionic Liquids as Attractive Hypergolic Rocket Fuels

Dr. Yi Wang, Dr. Shi Huang, Dr. Wenquan Zhang, Dr. Tianlin Liu, Dr. Xiujuan Qi and Prof. Qinghua Zhang

Nitrato-Functionalized Task-Specific Ionic Liquids as Attractive Hypergolic Rocket Fuels

Fly me to the moon: A series of nitrato-functionalized hypergolic ionic liquids were synthesized, which exhibited improved comprehensive performances including higher densities, higher density-specific impulse, larger combustion flames and longer violent combustion durations upon contact with the oxidizer white fuming nitric acid.

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July 22, 2017

Hot Paper: Rhodium-Catalyzed Silylative and Germylative Cyclization with Dehydrogenation Leading to 9-Sila- and 9-Germafluorenes: A Combined Experimental and Computational Mechanistic Study

Dr. Masahito Murai, Ryo Okada, Dr. Sobi Asako and Prof. Dr. Kazuhiko Takai

Rhodium-Catalyzed Silylative and Germylative Cyclization with Dehydrogenation Leading to 9-Sila- and 9-Germafluorenes: A Combined Experimental and Computational Mechanistic Study

Activating the unactivated: The combination of [RhCl(cod)]2 and PPh3 is used to catalyze the oxidant-free dehydrogenative silylation and germylation of unactivated C(sp2)−H bonds under neutral conditions (see scheme). The experimentally obtained unique reactivity is supported by the results of theoretical calculations, and a plausible reaction mechanism, including insights into why the current transformation does not require hydrogen acceptors and heteroatom-containing directing groups, is proposed.

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July 28, 2017
Hot Paper: Tetrameric and Dimeric [N⋅⋅⋅I+⋅⋅⋅N] Halogen-Bonded Supramolecular Cages

July 28, 2017
Hot Paper: Selective Catalytic Performances of Noble Metal Nanoparticle@MOF Composites: The Concomitant Effect of Aperture Size and Structural Flexibility of MOF Matrices

July 28, 2017
Hot Paper: Vertical-Aligned Li2S–Graphene Encapsulated within a Carbon Shell as a Free-Standing Cathode for Lithium–Sulfur Batteries

July 28, 2017
Hot Paper: An Exceptionally Water Stable Metal–Organic Framework with Amide-Functionalized Cages: Selective CO2/CH4 Uptake and Removal of Antibiotics and Dyes from Water

July 28, 2017
Hot Paper: A Guide for the Design of Functional Polyaromatic Organophosphorus Materials

July 28, 2017
VIP: High-Energy-Resolution X-ray Absorption Spectroscopy for Identification of Reactive Surface Species on Supported Single-Site Iridium Catalysts

July 27, 2017
Hot Paper: Catalytic Dehydrogenative Coupling of Hydrosilanes with Alcohols for the Production of Hydrogen On-demand: Application of a Silane/Alcohol Pair as a Liquid Organic Hydrogen Carrier

July 27, 2017
Hot Paper: Biphasic Liquid Crystal and the Simultaneous Measurement of Isotropic and Anisotropic Parameters by Spatially Resolved NMR Spectroscopy

July 27, 2017
Hot Paper: Soluble Platinum Nanoparticles Ligated by Long-Chain N-Heterocyclic Carbenes as Catalysts

July 25, 2017
Hot Paper: Selectivity of C−H versus C−F Bond Oxygenation by Homo- and Heterometallic Fe4, Fe3Mn, and Mn4 Clusters

July 25, 2017
Hot Paper: Nitrato-Functionalized Task-Specific Ionic Liquids as Attractive Hypergolic Rocket Fuels

July 22, 2017
Hot Paper: Rhodium-Catalyzed Silylative and Germylative Cyclization with Dehydrogenation Leading to 9-Sila- and 9-Germafluorenes: A Combined Experimental and Computational Mechanistic Study

July 22, 2017
Hot Paper: N-Heterocyclic Phosphenium Complex of Manganese: Synthesis and Catalytic Activity in Ammonia Borane Dehydrogenation

July 21, 2017
Hot Paper: Photoelectrochemical H2 Generation from Suboxide TiO2 Nanotubes: Visible-Light Absorption versus Conductivity

July 21, 2017
Hot Paper: Self-Assembly of Cyclohelicate [M3L3] Triangles Over [M4L4] Squares, Despite Near-Linear Bis-terdentate L and Octahedral M

July 21, 2017
Hot Paper: Synthesis and Antigenic Evaluation of Oligosaccharide Mimics of Vi Antigen from Salmonella typhi

July 21, 2017
Hot Paper: On the Accessible Reaction Channels of Vinyl Gold(I) Species: π- and σ-Pathways

July 21, 2017
VIP: Nonheme Iron-Oxo-Catalyzed Methane Formation from Methyl Thioethers: Scope, Mechanism, and Relevance for Natural Systems

July 19, 2017
Hot Paper: PCR Incorporation of Polyoxometalate Modified Deoxynucleotide Triphosphates and Their Application in Molecular Electrochemical Sensing of Yersinia pestis

July 18, 2017
Hot Paper: Alternating Copolymer of Double Four Ring Silicate and Dimethyl Silicone Monomer–PSS-1

July 14, 2017
Hot Paper: The Solvent Induced Inter-Dimensional Phase Transformations of Cobalt Zeolitic-Imidazolate Frameworks

July 14, 2017
Hot Paper: Coexistence of Strong Second Harmonic Generation Response and Wide Band Gap in AZn4Ga5S12 (A=K, Rb, Cs) with 3D Diamond-like Frameworks

July 14, 2017
Hot Paper: Visible-Light-Mediated Dual Decarboxylative Coupling of Redox-Active Esters with α,β-Unsaturated Carboxylic Acids

July 14, 2017
Hot Paper: Self-Assembly of Di-N-Heterocyclic Carbene-Gold-Adorned Corannulenes on C60

July 14, 2017
Hot Paper: Lipophilic N-Hydroxyphthalimide Catalysts for the Aerobic Oxidation of Cumene: Towards Solvent-Free Conditions and Back

July 13, 2017
Hot Paper: Temporal Control over Transient Chemical Systems using Structurally Diverse Chemical Fuels

July 13, 2017
Hot Paper: Catalytic Oxygenative Allylic Transposition of Alkenes into Enones with an Azaadamantane-Type Oxoammonium Salt Catalyst

July 12, 2017
Hot Paper: Design and Synthesis of a Series of Novel Mixed Borate and Carbonate Halides

July 12, 2017
Hot Paper: Water-Mediated Structural Transformations of CuII 5-Halonicotinates Coordination Networks with Distinct Mechanisms

July 12, 2017
Hot Paper: Stereospecific Winding of Polycyclic Aromatic Hydrocarbons into Trinacria Propellers

July 12, 2017
Hot Paper: Selective Bromination of Graphene Oxide by the Hunsdiecker Reaction

July 12, 2017
Hot Paper: Nitrogen and Fluorine-Codoped Carbon Nanowire Aerogels as Metal-Free Electrocatalysts for Oxygen Reduction Reaction

July 12, 2017
Hot Paper: Graphene/Group 5 Transition Metal Dichalcogenide Composites for Electrochemical Applications

July 12, 2017
Hot Paper: New Insights into the Role of Al2O3 in the Promotion of CuZnAl Catalysts: A Model Study

July 12, 2017
Hot Paper: Remarkable Modulation of Self-Assembly in Short γ-Peptides by Neighboring Ions and Orthogonal H-Bonding

July 12, 2017
Hot Paper: Metal–Ligand Complex-Induced Ultrafast Charge-Carrier Relaxation and Charge-Transfer Dynamics in CdX (X=S, Se, Te) Quantum Dots Sensitized with Nitrocatechol

July 12, 2017
VIP: CuAAC in a Distal Pocket: Metal Active-Template Synthesis of Strapped-Porphyrin [2]Rotaxanes

July 11, 2017
VIP: New Approach to 1,4-Benzoxazin-3-ones by Electrochemical C−H Amination

July 11, 2017
Hot Paper: Mechanochemical Synthesis of Phosphazane-Based Frameworks

July 08, 2017
Hot Paper: Tunable Wettability of Electrospun Polyurethane/Silica Composite Membranes for Effective Separation of Water-in-Oil and Oil-in-Water Emulsions

July 08, 2017
Hot Paper: Dual-Responsive Molecular Switches Based on Dithienylethene–RuII Organometallics in Self-Assembled Monolayers Operating at Low Voltage

July 08, 2017
Hot Paper: Self-Assembly of Perylenediimide–Single-Strand-DNA Conjugates: Employing Hydrophobic Interactions and DNA Base-Pairing To Create a Diverse Structural Space

July 07, 2017
Hot Paper: Universal Method for Large-Scale Synthesis of Layered Transition Metal Dichalcogenides

July 07, 2017
Hot Paper: Harnessing White-Light Luminescence via Tunable Singlet-and Triplet-Derived Emissions Based on Gold(III) Complexes *

July 07, 2017
Hot Paper: Interplay of Electronic Cooperativity and Exchange Coupling in Regulating the Reactivity of Diiron(IV)-oxo Complexes towards C−H and O−H Bond Activation

July 07, 2017
Hot Paper: Synthesis of a Single-Crystalline Macroporous Layered Silicate from a Macroporous UTL-Type Zeolite and Its Accelerated Intercalation

July 07, 2017
Hot Paper: Trifluoromethyl- and Fluoroalkylselenolations of Alkynyl Copper(I) Compounds

July 07, 2017
Hot Paper: Cobalt-Catalyzed Esterification of Amides

July 07, 2017
Hot Paper: The Kinetics of Growth of Metallo-supramolecular Polyelectrolytes in Solution

July 07, 2017
Hot Paper: Bioinspired Synthesis of Cu2+-Modified Covalent Triazine Framework: A New Highly Efficient and Promising Peroxidase Mimic

July 05, 2017
Hot Paper: Highly Stable Three-Dimensional Porous Nickel-Iron Nitride Nanosheets for Full Water Splitting at High Current Densities

July 04, 2017
Hot Paper: Small-Molecule Kinase-Inhibitors-Loaded Boron Cluster as Hybrid Agents for Glioma-Cell-Targeting Therapy

July 04, 2017
Hot Paper: Amorphous Nickel-Cobalt-Borate Nanosheet Arrays for Efficient and Durable Water Oxidation Electrocatalysis under Near-Neutral Conditions

July 04, 2017
Hot Paper: Fluidic Manufacture of Star-Shaped Gold Nanoparticles

July 04, 2017
Hot Paper: (E)-1,1,4,4-Tetramethyl-2-tetrazene (TMTZ): A Prospective Alternative to Hydrazines in Rocket Propulsion

July 04, 2017
VIP: Enhancing Catalytic Activity of Bioanode for Glucose Biofuel Cell by Compressing Enzyme, Mediator and Carbon Support through Centrifugation

July 04, 2017
VIP: Group 4 Metal Complexes of Phenylene–Salalen Ligands in rac-Lactide Polymerization Giving High Molecular Weight Stereoblock Poly(lactic acid)

June 30, 2017
Hot Paper: Tellurite-Squarate Driven Assembly of a New Family of Nanoscale Clusters Based on (Mo2O2S2)2+

June 30, 2017
Hot Paper: Mapping the Trajectory of Nucleophilic Substitution at Silicon Using a peri-Substituted Acenaphthyl Scaffold

June 30, 2017
Hot Paper: Gold(I)-Catalysed Asymmetric Hydroamination of Alkenes: A Silver- and Solvent-Dependent Enantiodivergent Reaction

June 30, 2017
Hot Paper: Exceptionally Long-Lived Photodriven Multi-Electron Storage without Sacrificial Reagents

June 30, 2017
VIP: Evaluation of the Medicinal Potential of Two Ruthenium(II) Polypyridine Complexes as One- and Two-Photon Photodynamic Therapy Photosensitizers

June 29, 2017
Hot Paper: Mesoporous Silica Scaffolds as Precursor to Drive the Formation of Hierarchical SAPO-34 with Tunable Acid Properties

June 28, 2017
Hot Paper: A New Electron-Rich Unit for Polymer Electron Acceptors: 4,4-Difluoro-4H-cyclopenta[2,1-b:3,4-b′]dithiophene

June 28, 2017
Hot Paper: Induction of Necroptosis in Cancer Stem Cells using a Nickel(II)-Dithiocarbamate Phenanthroline Complex

June 28, 2017
Hot Paper: Oxygen-Deficient Titanium Dioxide Nanosheets as More Effective Polysulfide Reservoirs for Lithium-Sulfur Batteries

June 28, 2017
Hot Paper: An Optimized Two-Photon Fluorescent Probe for Biological Sensing and Imaging of Catechol-O-Methyltransferase

June 28, 2017
Hot Paper: Interpretation of Seemingly Contradictory Data: Low NMR S2 Order Parameters Observed in Helices and High NMR S2 Order Parameters in Disordered Loops of the Protein hGH at Low pH

June 28, 2017
Hot Paper: Li12P3N9 with Non-Condensed [P3N9]12−-Rings and its High-Pressure Polymorph Li4PN3 with Infinite Chains of PN4-Tetrahedra

June 28, 2017
Hot Paper: Vicinal Difunctionalization of Alkenes through a Multicomponent Reaction with the Insertion of Sulfur Dioxide

June 28, 2017
Hot Paper: Helical Oligonaphthodioxepins Showing Intense Circularly Polarized Luminescence (CPL) in Solution and in the Solid State

June 28, 2017
Hot Paper: Inhibition of the Aggregation and Toxicity of the Minimal Amyloidogenic Fragment of Tau by Its Pro-Substituted Analogues

June 28, 2017
Hot Paper: Carbon Thin Film Wrapped around a Three-Dimensional Nitrogen-Doped Carbon Scaffold for Superior-Performance Supercapacitors

June 28, 2017
Hot Paper: Solid-State Gas Adsorption Studies with Discrete Palladium(II) [Pd2(L)4]4+ Cages

June 28, 2017
Hot Paper: Unsaturated Long-Chain Fatty Acids Are Preferred Ferritin Ligands That Enhance Iron Biomineralization

June 27, 2017
Hot Paper: 5-(Hetero)aryl-Substituted 9-Hydroxyphenalenones: Synthesis and Electronic Properties of Multifunctional Donor–Acceptor Conjugates

June 27, 2017
Hot Paper: Synthesis, Structure, and Reactivity of Ga-Substituted Distibenes and Sb-Analogues of Bicyclo[1.1.0]butane

June 27, 2017
Hot Paper: Halogen-Bonding-Mediated and Controlled Cationic Polymerization of Isobutyl Vinyl Ether: Expanding the Catalytic Scope of 2-Iodoimidazolium Salts

June 22, 2017
Hot Paper: A DNA-Based Label-Free Artificial Tongue for Pattern Recognition of Metal Ions

June 22, 2017
Hot Paper: From Ligand to Phosphor: Rapid, Machine-Assisted Synthesis of Substituted Iridium(III) Pyrazolate Complexes with Tuneable Luminescence

June 22, 2017
VIP: Superior Thermostability, Good Detonation Properties, Insensitivity, and the Effect on the Thermal Decomposition of Ammonium Perchlorate for a New Solvent-Free 3D Energetic PbII-MOF

June 21, 2017
Hot Paper: Synthesis of Poly-γ-S-2-methylbutyl-l-glutamate and Poly-γ-S-2-methylbutyl-d-glutamate and Their Use as Enantiodiscriminating Alignment Media in NMR Spectroscopy

June 21, 2017
Hot Paper: Artificial Enzyme-based Logic Operations to Mimic an Intracellular Enzyme-participated Redox Balance System

June 21, 2017
Hot Paper: Zinc-Coordinated Hierarchical Organization of Ligand-Stabilized Gold Nanoclusters for Chiral Recognition and Separation

June 20, 2017
Hot Paper: Formaldehyde-Extruding Homolytic Aromatic Substitution via C[RIGHTWARDS ARROW]O Transposition: Selective ‘Traceless-Linker’ access to Congested Biaryl Bonds

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