Angewandte Chemie International Edition

Cover image for Vol. 53 Issue 40

Editor: Peter Gölitz, Deputy Editors: Neville Compton, Haymo Ross

Online ISSN: 1521-3773

Associated Title(s): Angewandte Chemie, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemistryOpen, ChemPlusChem, Zeitschrift für Chemie

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Abstracts now required for Communications

To improve the discoverability of Communications, we ask authors to supply an abstract as the first paragraph from now on. In this abstract, the motivation for the work, the methods applied, the results, and the conclusions drawn should be presented (maximum 1000 characters).

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Harald Schwalbe

“My own favorite saying is “There are 1000 ways of getting no signal”. I admire my co-workers ...” This and more about Harald Schwalbe can be found on page 10576.

Angew. Chem. Int. Ed.2014, 53, No. 40, 10576-10577

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September 23, 2014

Angewandte Chemie 40/2014: Rich Chemistry

Angewandte Chemie 40/2014: Rich ChemistryIn this issue, G. Van Tendeloo et al. review the 3D characterization of noble-metal nanoparticles and their assemblies by electron tomography. How does this technique help to understand the connection between the properties and structure or composition of nanomaterials? In another Review, A.  C. Conibear and D.  J. Craik discuss the chemistry and biology of theta defensins. What are their applications and how are they biosynthesized and distributed in primates? In a Minireview, R.  J. Thomson et al. summarize the total synthesis of isodon diterpenes. The Highlights deal with supramolecular polymerization (Q. Zhang and H. Tian) and antibody conjugation (P. M. P. Gois et  al.).

In the Communications section, F. X. Gomis-Rüth et al. demonstrate how multiple stable conformations account for reversible oligomerization and autoinhibition of a metamorphic metallopeptidase (see picture). M.  V. Fedin et al. observed ultrafast photoswitching in a copper nitroxide based molecular magnet. H.  S. Choi et al. present phosphonated near-infrared fluorophores for bone imaging, and V.  K. Singh et al. report on an entry to enantiomerically enriched isoindolinones.

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Carbonic Acid—And Yet It Exists!

Preparation and characterization of gas-phase carbonic acid and its monomethyl ester

Carbonic Acid—And Yet It Exists! - Preparation and characterization of gas-phase carbonic acid and its monomethyl ester

Until fairly recently, scientists were convinced that carbonic acid (H2CO3) does not exist as a stable molecule. In the journal Angewandte Chemie, German researchers have now introduced a simple pyrolytic method for the production of gas-phase carbonic acid that allowed the spectroscopic characterization of gas-phase carbonic acid and its monomethyl ester.

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alkynes · asymmetric catalysis · asymmetric synthesis · C-H activation · copper · cycloaddition · density functional calculations · electrochemistry · fluorescence · gold · heterocycles · heterogeneous catalysis · homogeneous catalysis · magnetic properties · nanoparticles · nanostructures · natural products · NMR spectroscopy · organocatalysis · oxidation · palladium · peptides · polymers · rhodium · ruthenium · self-assembly · structure elucidation · supramolecular chemistry · synthetic methods · total synthesis