Angewandte Chemie International Edition

Cover image for Vol. 53 Issue 45

Editor: Peter Gölitz, Deputy Editors: Neville Compton, Haymo Ross

Online ISSN: 1521-3773

Associated Title(s): Angewandte Chemie, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemistryOpen, ChemPlusChem, Zeitschrift für Chemie

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To improve the discoverability of Communications, we ask authors to supply an abstract as the first paragraph from now on. In this abstract, the motivation for the work, the methods applied, the results, and the conclusions drawn should be presented (maximum 1000 characters).


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Kari Rissanen

“In a spare hour, I read a good science fiction novel. My favorite saying is “better late than never” ...” This and more about Kari Rissanen can be found on page 12012.

Angew. Chem. Int. Ed.2014, 53, No. 45, 12012

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October 29, 2014

Angewandte Chemie 45/2014: Mechanics and Chemistry

Angewandte Chemie 45/2014: Mechanics and ChemistryIn this issue, P. Fratzl et al. review the mechanical role of metal ions in biogenic protein-based materials. How do protein–metal interactions influence properties such as hardness, toughness, adhesion, and self-healing? The Highlights deal with the characterization of nanoporous solids by three complementary techniques (J. M. Thomas and R. K. Leary) and the conversion of CO2 to methane on copper surfaces (M. Behrens).

In the Communications section, M. Sprik et al. describe how to align electronic and protonic energy levels of proton-coupled electron transfer in water oxidation on aqueous titania (see picture). D. P. Fairlie et al. succeeded in making a cyclic heptapeptide orally bioavailable. W.-J. Xiao et al. reveal the photocatalytic generation of N-centered hydrazonyl radicals, and G. R. Newkome et al. report on the fractal design and chemical reality of a self-assembled terpyridine-CdIISierpinski triangle.

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The Smallest Marches to a Different Tune

Fundamental change in the nature of chemical bonding upon isotopic substitution

The Smallest Marches to a Different Tune - Fundamental change in the nature of chemical bonding upon isotopic substitution

Isotopes are atoms of the same element that have the same number of protons but a different number of neutrons. Because of the resulting differences in mass ratios, isotope effects can significantly influence the formation and breaking of chemical bonds in the course of chemical reactions. In extreme cases, isotopic substitution can even cause a fundamental change in the type of chemical bond, as reported by scientists in the journal Angewandte Chemie.

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alkynes · asymmetric catalysis · asymmetric synthesis · C-H activation · copper · cycloaddition · density functional calculations · electrochemistry · fluorescence · gold · heterocycles · heterogeneous catalysis · homogeneous catalysis · magnetic properties · nanoparticles · nanostructures · natural products · NMR spectroscopy · organocatalysis · oxidation · palladium · peptides · polymers · rhodium · ruthenium · self-assembly · structure elucidation · supramolecular chemistry · synthetic methods · total synthesis

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