Angewandte Chemie International Edition
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“My favorite time of day is the morning—quiet moments before everyone else is awake. In a spare hour, I go for a walk ...” This and more about Martin Oestreich can be found on page 11408.
Reviews from Our Sister Journals
- Giuseppe Marzano, Cosimo V. Ciasca, Francesco Babudri, Gabriele Bianchi, Andrea Pellegrino, Riccardo Po, Gianluca M. Farinola
Organometallic Approaches to Conjugated Polymers for Plastic Solar Cells: From Laboratory Synthesis to Industrial Production
Current organometallic approaches to the synthesis of polymers for plastic solar cells are reviewed, with emphasis also on the requirements for industrial scale-up. The number of synthetic steps for obtaining monomers, the efficiency of the polymerization protocols, and structural simplicity are key to making organic photovoltaics a viable energy source. [Microreview]
- Gregory Chatel, Karine De Oliveira Vigier, François Jérôme
Sonochemistry: What Potential for Conversion of Lignocellulosic Biomass into Platform Chemicals? [Review]
- Hyunjun Ji, Joonho Park, Moses Cho, Yousung Jung
Assessments of Semilocal Density Functionals and Corrections for Carbon Dioxide Adsorption on Metal–Organic Frameworks [Minireview]
- Lluís Blancafort
Photochemistry and Photophysics at Extended Seams of Conical Intersection [Review]
- Rahul R. Salunkhe, Ying-Hui Lee, Kuo-Hsin Chang, Jing-Mei Li, Patrice Simon, Jing Tang, Nagy L. Torad, Chi-Chang Hu, Yusuke Yamauchi
Nanoarchitectured Graphene-Based Supercapacitors for Next-Generation Energy-Storage Applications [Review]
- Pengbo Wan, Xiaodong Chen
Stimuli-Responsive Supramolecular Interfaces for Controllable Bioelectrocatalysis [Minireview]
- Raquel G. Soengas, Rita C. Acúrcio, Artur M. S. Silva
Recent Developments in the Chemistry of gem-Halonitro Compounds [Microreview]
- Aswathy Joseph, Suresh Mathew
Ferrofluids: Synthetic Strategies, Stabilization, Physicochemical Features, Characterization, and Applications [Review]
October 14, 2014
Angewandte Chemie 43/2014: Long-Term Stability
In this issue, S. Rohn et al. review the reactivity of glucosinolates and their breakdown products in foods. How do they affect the quality of food with regard to nutritional value, flavor, and beneficial health effects? In a Minireview, R. J. M. Nolte et al. discuss the advances in processive catalysis that have been made in emulating it through supramolecular chemistry. The Highlights deal with the trifluoromethanide anion (N. Santschi and R. Gilmour) and transition-metal-based 18F fluorination (S. H. Liang and N. Vasdev).
In the Communications section, I. Ivanović-Burmazović et al. describe the effect of confined space around a heme iron center (see picture). J. Ye et al. demonstrate photothermal conversion of CO2 into methane over Group VIII nanocatalysts as an option for solar fuel production. R. Giri et al. succeeded in the copper-catalyzed coupling of triaryl- and trialkylindium reagents with aryl iodides and bromides, and N. W. Mitzel et al. present the solid-state structure of pentafluoroethyllithium, a Li/F carbenoid.
A Matter of Preparation
Reactivity of glucosinolates and their breakdown products in foods
The taste and nutritional value of vegetables including broccoli, radishes, and cabbage are influenced by specific substances, namely glucosinolates (mustard oil glycosides) and their numerous breakdown products. The positive and negative effects of these compounds on human health are also the subjects of fierce debate. As it turns out, the actual substances present depend greatly on the preparation of the vegetables, report German scientists in the journal Angewandte Chemie.
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