Angewandte Chemie International Edition

Cover image for Vol. 54 Issue 5

Editor: Peter Gölitz, Deputy Editors: Neville Compton, Haymo Ross

Online ISSN: 1521-3773

Associated Title(s): Angewandte Chemie, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemistryOpen, ChemPlusChem, Zeitschrift für Chemie

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Here's a selection of upcoming papers. Also see the EarlyView page for the latest papers published online. Click on the VIP logos of upcoming articles to read their abstracts.

Borylene Complexes

Holger Braunschweig*[WWW], Melanie Forster, Thomas Kupfer, Fabian Seeler

Borylene Transfer under Thermal Conditions for the Synthesis of Rhodium and Iridium Borylene Complexes
[Communication]

Coming soon.

Natural Product Synthesis

Hugh Nakamura, Chihiro Tsukano, Motohiro Yasui, Shinsuke Yokouchi, Masayuki Igarashi, Yoshiji Takemoto*

Total Synthesis of (−)-Caprazamycin A
[Communication]

Coming soon.

Morphology Transformation

Jeehong Kim[WWW], Kangkyun Baek*, Dinesh Shetty, Narayanan Selvapalam, Gyeongwon Yun, Nam Hoon Kim, Young Ho Ko, Kyeng Min Park, Ilha Hwang, Kimoon Kim*

Reversible Morphological Transformation between Polymer Nanocapsules and Thin Films through Dynamic Covalent Self-Assembly
[Communication]

Coming soon.

Synthetic Methods

Appaso Mahadev Jadhav, Vinayak Vishnu Pagar, Deepak B. Huple, Rai-Shung Liu*

Zinc(II)-Catalyzed Intermolecular Hydrative Aldol Reactions of 2-En-1-ynamides with Aldehydes and Water to form Branched Aldol Products Regio- and Stereoselectively
[Communication]

Coming soon.

Synthetic Methods

Ala Bunescu[WWW], Qian Wang, Jieping Zhu*

Copper-Catalyzed Cyanomethylation of Allylic Alcohols with Concomitant 1,2-Aryl Migration: Efficient Synthesis of Functionalized Ketones Containing an α-Quaternary Center
[Communication]

Published online on January 16, 2015.
DOI: 10.1002/anie.201411657

Gas Separation

Yi Liu*, Jia Hong Pan, Nanyi Wang, Frank Steinbach, Xinlei Liu, Jürgen Caro*

Remarkably Enhanced Gas Separation by Partial Self-Conversion of a Laminated Membrane to Metal–Organic Frameworks
[Communication]
(VIP - Read Abstract)

Coming soon.

Polymer Gels

Takeshi Ueki, Yutaro Nakamura[WWW], Ryoji Usui, Yuzo Kitazawa, Soonyong So, Timothy P. Lodge*[WWW], Masayoshi Watanabe*

Photoreversible Gelation of a Triblock Copolymer in an Ionic Liquid
[Communication]

Coming soon.

Biocatalysis

Karel Hernandez, Igor Zelen, Giovanna Petrillo, Isabel Usón, Claudia M. Wandtke, Jordi Bujons, Jesús Joglar, Teodor Parella, Pere Clapés*

Engineered l-Serine Hydroxymethyltransferase from Streptococcus thermophilus for the Synthesis of α,α-Dialkyl-α-Amino Acids
[Communication]

Coming soon.

Supramolecular Chemistry

Ichiro Hisaki*, Shoichi Nakagawa, Norimitsu Tohnai, Mikiji Miyata*

C3-Symmetric Macrocycle-Based, Hydrogen-Bonded, Multiporous Hexagonal Network as Motif of Porous Molecular Crystals
[Communication]

Coming soon.

Peptides

Roger Prades, Benjamí Oller-Salvia, Susanne M. Schwarzmaier, Javier Selva, María Moros, Matilde Balbi, Valeria Grazú, Jesus M. de La Fuente, Gustavo Egea, Nikolaus Plesnila, Meritxell Teixidó*, Ernest Giralt*

Applying the Retro-Enantio Approach to Obtain a Peptide Capable of Overcoming the Blood-Brain Barrier
[Communication]

Coming soon.

Asymmetric Catalysis

Adrian B. Pritzius, Bernhard Breit*

Asymmetric Rhodium-Catalyzed Addition of Thiols to Allenes: Synthesis of Branched Allylic Thioethers and Sulfones
[Communication]

Published online on January 16, 2015.
DOI: 10.1002/anie.201411402

Spin-State Change

Dipankar Sahoo, Matthew G. Quesne, Sam P. de  Visser*, Sankar Prasad Rath*

Hydrogen-Bonding Interactions Trigger a Spin-Flip in Iron(III) Porphyrin Complexes
[Communication]

Coming soon.

Dendrimer Synthesis

Sandra García-Gallego, Daniel Hult, Johan V. Olsson, Michael Malkoch*

Fluoride-Promoted Esterification with Imidazolide-Activated Compounds: A Modular and Sustainable Approach to Dendrimers
[Communication]

Coming soon.

Copper Complexes

Andrew M. Romine, Noel Nebra, Andrey I. Konovalov, Eddy Martin, Jordi Benet-Buchholz, Vladimir V. Grushin*

Easy Access to the Copper(III) Anion [Cu(CF3)4]
[Communication]

Coming soon.

DNA Intercalators

Sasha Stimpson, Dan R. Jenkinson, Andrew Sadler, Mark Latham, Dr Ashley Wragg, Anthony J. H. M. Meijer, Jim A. Thomas*

Tuning the Excited State of Water-Soluble IrIII-Based DNA Intercalators that are Isostructural with [RuII(NN)2(dppz)] Light-Switch Complexes
[Communication]

Coming soon.

Supramolecular Chemistry

Julia Guilleme, María J. Mayoral, Joaquín Calbo, Juan Aragó, Pedro M. Viruela, Enrique Ortí*, Tomás Torres*, David González-Rodríguez*

Non-Centrosymmetric Homochiral Supramolecular Polymers of Tetrahedral Subphthalocyanine Molecules
[Communication]

Published online on January 21, 2015.
DOI: 10.1002/anie.201411272

Main-Group Multiple Bonds

Daniel Geiß, Marius I. Arz, Martin Straßmann, Gregor Schnakenburg, Alexander C. Filippou*

Si=P Double Bonds: Experimental and Theoretical Study of a NHC-stabilized Phosphasilenylidene
[Communication]

Published online on January 19, 2015.
DOI: 10.1002/anie.201411264

Gas Adsorption

Ning Huang, Xiong Chen, Rajamani Krishna, Donglin Jiang*

Two-Dimensional Covalent Organic Frameworks for Carbon Dioxide Capture through Channel-Wall Functionalization
[Communication]

Coming soon.

Blood–Brain Barrier

Xiaoli Wei, Changyou Zhan*, Qing Shen, Wei Fu, Cao Xie, Jie Gao, Chunmei Peng, Ping Zheng, Weiyue Lu*

A d-Peptide Ligand of Nicotine Acetylcholine Receptors for Brain-Targeted Drug Delivery
[Communication]
(VIP) title=

Published online on January 19, 2015.
DOI: 10.1002/anie.201411226

Reaction Mechanisms

Martin Pawliczek, Tobias F. Schneider[WWW], Christian Maaß, Dietmar Stalke, Daniel B. Werz*

Formal anti-Carbopalladation Reactions of Non-Activated Alkynes: Requirements, Mechanistic Insights, and Applications
[Communication]

Coming soon.

Enzymatic Electrodes

Oscar Gutiérrez-Sanz, Cristina Tapia, Marta C. Marques, Sonia Zacarias, Marisela Vélez, Inês A. C. Pereira, Antonio L. De Lacey*

Induction of a Proton Gradient across a Gold-Supported Biomimetic Membrane by Electroenzymatic H2 Oxidation
[Communication]

Published online on January 19, 2015.
DOI: 10.1002/anie.201411182

Electrochemistry

Hong Nhan Nong, Hyung-Suk Oh, Tobias Reier, Elena Willinger, Marc-Georg Willinger, Valeri Petkov, Detre Teschner*, Peter Strasser*

Oxide-Supported IrNiOx Core–Shell Particles as Efficient, Cost-Effective, and Stable Catalysts for Electrochemical Water Splitting
[Communication]

Coming soon.

Heterocycle Synthesis

Chen Chen, Longlei Hou, Mian Cheng, Jianhua Su, Xiaofeng Tong*

Palladium(0)-Catalyzed Iminohalogenation of Alkenes: Synthesis of 2-Halomethyl Dihydropyrroles and Mechanistic Insights into the Alkyl Halide Bond Formation
[Communication]

Coming soon.

3D Macrocycles

Ryota Inoue[WWW], Masashi Hasegawa*, Tohru Nishinaga, Kenji Yoza, Yasuhiro Mazaki

Efficient Synthesis, Structure, and Complexation Studies of Electron-Donating Thiacalix[n]dithienothiophene
[Communication]

Published online on January 16, 2015.
DOI: 10.1002/anie.201410970

Enzyme Kinetics

Simon de Vries*, Katerina Dörner, Marc J. F. Strampraad, Thorsten Friedrich*

Electron Tunneling Rates in Respiratory Complex I Are Tuned for Efficient Energy Conversion
[Communication]
(VIP) title=

Published online on January 19, 2015.
DOI: 10.1002/anie.201410967

Photocatalysis

Chengsi Pan, Tsuyoshi Takata*, Mamiko Nakabayashi, Takao Matsumoto, Naoya Shibata, Yuichi Ikuhara, Kazunari Domen*

A Complex Perovskite-Type Oxynitride: The First Photocatalyst for Water Splitting Operable at up to 600 nm
[Communication]

Coming soon.

Hydrogen Oxidation

Hyosun Lee, Ievgen I. Nedrygailov, Changhwan Lee, Gabor A. Somorjai*, Jeong Young Park*

Chemical-Reaction-Induced Hot Electron Flows on Platinum Colloid Nanoparticles under Hydrogen Oxidation: Impact of Nanoparticle Size
[Communication]

Coming soon.

Copper Arenes

Ashley M. Wright, Benjamin J. Irving, Guang Wu, Anthony J. H. M. Meijer, Trevor W. Hayton*

A Copper(I)–Arene Complex With an Unsupported η6 Interaction
[Communication]

Coming soon.

Photoactivation

Florian Buhr, Jörg Kohl-Landgraf, Susanne tom Dieck, Cyril Hanus, Deep Chatterjee, Andreas Hegelein, Erin M. Schuman, Josef Wachtveitl, Harald Schwalbe*

Design of Photocaged Puromycin for Nascent Polypeptide Release and Spatiotemporal Monitoring of Translation
[Communication]

Coming soon.

DNA Nanotechnology

Guangbao Yao, Jiang Li, Jie Chao, Hao Pei, Huajie Liu, Yun Zhao, Jiye Shi, Qing Huang, Lianhui Wang, Wei Huang, Chunhai Fan*

Gold-Nanoparticle-Mediated Jigsaw-Puzzle-like Assembly of Supersized Plasmonic DNA Origami
[Communication]

Coming soon.

Polymer Photoreactions

Kai Hiltebrandt, Thomas Pauloehrl, James P. Blinco, Katharina Linkert, Hans G. Börner, Christopher Barner-Kowollik*

λ-Orthogonal Pericyclic Macromolecular Photoligation
[Communication]

Coming soon.

Ammonia Decomposition

Jianping Guo[WWW], Peikun Wang, Guotao Wu, Anan Wu, Daqiang Hu, Zhitao Xiong, Junhu Wang, Pei Yu, Fei Chang, Zheng Chen, Ping Chen*

Lithium Imide Synergy with 3d Transition-Metal Nitrides Leading to Unprecedented Catalytic Activities for Ammonia Decomposition
[Communication]
(VIP - Read Abstract)

Coming soon.

Sustainable Chemistry

Tadahisa Iwata*

Biodegradable and Bio-Based Polymers: Future Prospects of Eco-Friendly Plastics
[Essay]

Published online on January 21, 2015.
DOI: 10.1002/anie.201410770

Encoded Libraries

Raphael M. Franzini, Torun Ekblad, Nan Zhong, Moreno Wichert, Willy Decurtins, Angela Nauer, Mauro Zimmermann, Florent Samain, Jörg Scheuermann, Peter J. Brown, Jonathan Hall, Susanne Gräslund, Herwig Schüler, Dario Neri*

Identification of Structure–Activity Relationships from Screening a Structurally Compact DNA-Encoded Chemical Library
[Communication]

Coming soon.

Organocatalysis

Ane Orue[WWW], Uxue Uria, Efraim Reyes*, Luisa Carrillo, Jose L. Vicario*

Catalytic Enantioselective [5+2] Cycloaddition between Oxidopyrylium Ylides and Enals under Dienamine Activation
[Communication]

Coming soon.

Asymmetric Cyclization

Wenzhen Fu, Ming Nie, Aizhen Wang, Ziping Cao, Wenjun Tang*

Highly Enantioselective Nickel-Catalyzed Intramolecular Reductive Cyclization of Alkynones
[Communication]

Published online on January 16, 2015.
DOI: 10.1002/anie.201410700

Liquid Crystals

Matthias Lehmann*, Markus Hügel

A Perfect Match: Fullerene Guests in Star-Shaped Oligophenylenevinylene Mesogens
[Communication]

Coming soon.

Sustainable Polymers

Nathan J. Van Zee, Geoffrey W. Coates*

Alternating Copolymerization of Propylene Oxide with Biorenewable Terpene-Based Cyclic Anhydrides: A Sustainable Route to Aliphatic Polyesters with High Glass Transition Temperatures
[Communication]

Coming soon.

Perfluorinated Alkoxides

Benson J. Jelier, Jon L. Howell, Craig D. Montgomery, Daniel B. Leznoff, Chadron M. Friesen*

A Convenient Route to Tetraalkylammonium Perfluoroalkoxides from Hydrofluoroethers
[Communication]

Coming soon.

Biocatalysis

Sandy Schmidt, Christian Scherkus, Jan Muschiol, Ulf Menyes, Till Winkler, Werner Hummel, Harald Gröger, Andreas Liese, Hans-Georg Herz, Uwe T. Bornscheuer*

An Enzyme Cascade Synthesis of ε-Caprolactone and its Oligomers
[Communication]

Published online on January 21, 2015.
DOI: 10.1002/anie.201410633

Multicomponent Reactions

Wenfang Xiong, Chaorong Qi*, Haitao He, Lu Ouyang, Min Zhang, Huanfeng Jiang*

Base-Promoted Coupling of Carbon Dioxide, Amines, and N-Tosylhydrazones: A Novel and Versatile Approach to Carbamates
[Communication]

Coming soon.

Battery Electrodes

Jian Zhu, Da Deng*

Wet-Chemical Synthesis of Phase-Pure FeOF Nanorods as High-Capacity Cathodes for Sodium-Ion Batteries
[Communication]

Coming soon.

Boron Compounds

Guillaume Berionni[WWW], Artem I. Leonov, Peter Mayer, Armin R. Ofial, Herbert Mayr*

Fine-Tuning the Nucleophilic Reactivities of Boron Ate Complexes Derived from Aryl and Heteroaryl Boronic Esters
[Communication]

Coming soon.

Bioinspired Asymmetric Catalysis

Olaf Cussó, Xavi Ribas, Julio Lloret-Fillol, Miquel Costas*

Synergistic Interplay of a Non-Heme Iron Catalyst and Amino Acid Co-Ligands in H2O2 Activation for Asymmetric Epoxidation of α-Alkyl-Substituted Styrenes
[Communication]
(VIP) title=

Published online on January 19, 2015.
DOI: 10.1002/anie.201410557

Cascade C–H Activation

Weibo Yang, Shengqing Ye, Dewey Fanning, Timothy Coon, Yvonne Schmidt, Paul Krenitsky, Dean Stamos*, Jin-Quan Yu*

Orchestrated Triple C–H Activation Reactions Using Two Directing Groups: Rapid Assembly of Complex Pyrazoles
[Communication]

Published online on January 16, 2015.
DOI: 10.1002/anie.201410462

Gene Delivery

Mao Li, Stefanie Schlesiger, Shirley K. Knauer, Carsten Schmuck*

A Tailor-Made Specific Anion-Binding Motif in the Side Chain Transforms a Tetrapeptide into an Efficient Vector for Gene Delivery
[Communication]

Coming soon.

Color Switching

Wenshou Wang, Yifan Ye, Ji Feng, Miaofang Chi, Jinghua Guo, Yadong Yin*

Enhanced Photoreversible Color Switching of Redox Dyes Catalyzed by Barium-Doped TiO2 Nanocrystals
[Communication]

Published online on January 16, 2015.
DOI: 10.1002/anie.201410408

C–H Activation

Yang Wang[WWW], Vladimir Gevorgyan*

General Method for the Synthesis of Salicylic Acids from Phenols through Palladium-Catalyzed Silanol-Directed C–H Carboxylation
[Communication]

Published online on January 21, 2015.
DOI: 10.1002/anie.201410375

Heterogeneous Catalysis

Shuliang Yang, Changyan Cao*, Yongbin Sun, Peipei Huang, Fangfang Wei, Weiguo Song*

Nanoscale Magnetic Stirring Bars for Heterogeneous Catalysis in Microscopic Systems
[Communication]

Coming soon.

Bioinorganic Drugs

Sandra Meieranz, Maria Stefanopoulou, Gerhard Rubner, Kerstin Bensdorf, Dominic Kubutat, William S. Sheldrick, Ronald Gust*

The Biological Activity of Zeise´s Salt and its Derivatives
[Communication]

Coming soon.

Heterogeneous Catalysis

Alexander Zellner, Rainer Suntz*, Olaf Deutschmann*

Two-Dimensional Spatial Resolution of Concentration Profiles in Catalytic Reactors by Planar Laser-Induced Fluorescence: NO Reduction over Diesel Oxidation Catalysts
[Communication]

Published online on January 16, 2015.
DOI: 10.1002/anie.201410324

Reaction Intermediates

Claudio Iacobucci, Samantha Reale, Jean-François Gal, Francesco De Angelis*

Dinuclear Copper Intermediates in Copper(I)-Catalyzed Azide–Alkyne Cycloaddition Directly Observed by Electrospray Ionization Mass Spectrometry
[Communication]

Coming soon.

Peptidomimetics

Elizabeth A. German[WWW], Jonathan E. Ross, Peter C. Knipe, Michaela F. Don, Sam Thompson*, Andrew D. Hamilton*

β-Strand Mimetic Foldamers Rigidified through Dipolar Repulsion
[Communication]

Published online on January 19, 2015.
DOI: 10.1002/anie.201410290

Synthetic Methods

Carlos González-Rodríguez*[WWW], José Ramón Suárez, Jesús A. Varela, Carlos Saá*

Nucleophilic Addition of Amines to Ruthenium Carbenes: ortho-(Alkynyloxy)benzylamine Cyclizations towards 1,3-Benzoxazines
[Communication]

Published online on January 16, 2015.
DOI: 10.1002/anie.201410284

Biradicaloids

Alexander Hinz[WWW], Axel Schulz*, Alexander Villinger

Stable Heterocyclopentane-1,3-diyls
[Communication]

Coming soon.

NMR Spectroscopy

Ilya Kuprov, David M. Hodgson, Johannes Kloesges, Christopher I. Pearson, Barbara Odell, Timothy D. W. Claridge*

Anomalous Nuclear Overhauser Effects in Carbon-Substituted Aziridines: Scalar Cross-Relaxation of the First Kind
[Communication]

Coming soon.

Heterogeneous MOFs

Hiroyasu Furukawa*, Ulrich Müller*, Omar M. Yaghi*

"Heterogeneity within Order" in Metal–Organic Frameworks
[Review]

Published online on January 21, 2015.
DOI: 10.1002/anie.201410252

Photovoltaics

Samuel D. Stranks*, Pabitra K. Nayak, Wei Zhang, Thomas Stergiopoulos, Henry J. Snaith*

Formation of Thin Films of Organic–Inorganic Perovskites for High-Efficiency Solar Cells
[Minireview]

Coming soon.

Ionic Liquids

Seung Joon Yoo, Long-Ji Li, Cheng-Chu Zeng, R. Daniel Little*

Polymeric Ionic Liquid and Carbon Black Composite as a Reusable Supporting Electrolyte: Modification of the Electrode Surface
[Communication]

Coming soon.

Asymmetric Catalysis

Christopher T. Check, Ki Po Jang, C. Benjamin Schwamb, Alexander S. Wong, Michael H. Wang, Karl A. Scheidt*

Ferrocene-Based Planar Chiral Imidazopyridinium Salts for Catalysis
[Communication]

Coming soon.

Black Phosphorus

Juanxia Wu, Nannan Mao, Liming Xie, Hua Xu*, Jin Zhang*

Identifying the Crystalline Orientation of Black Phosphorus Using Angle-Resolved Polarized Raman Spectroscopy
[Communication]

Coming soon.

Enzymatic C–S Coupling

Kristina V. Goncharenko, Allegra Vit, Wulf Blankenfeldt*, Florian P. Seebeck*

Structure of the Sulfoxide Synthase EgtB from the Ergothioneine Biosynthetic Pathway
[Communication]

Published online on January 16, 2015.
DOI: 10.1002/anie.201410045

Carbohydrates

Angie Garcia, Douglas A. L. Otte, Walter A. Salamant, Jillian R. Sanzone, K. A. Woerpel*

Acceleration of Acetal Hydrolysis by Remote Alkoxy Groups: Evidence for Electrostatic Effects on the Formation of Oxocarbenium Ions
[Communication]

Coming soon.

Co-existing Excitons

Christian B. Winiger[WWW], Simon M. Langenegger, Gion Calzaferri*, Robert Häner*

Formation of Two Homo-chromophoric H-Aggregates in DNA-Assembled Alternating Dye Stacks
[Communication]

Coming soon.

Carbenes

Zhenxing Liu, Haocheng Tan, Long Wang, Tianren Fu, Ying Xia, Yan Zhang, Jianbo Wang*

Transition-Metal-Free Intramolecular Carbene Aromatic Substitution/Büchner Reaction: Synthesis of Fluorenes and [6,5,7]Benzo-fused Rings
[Communication]

Coming soon.

Synthetic Methods

Pablo Morán-Poladura, Eduardo Rubio, José M. González*

Intramolecular C–H Activation through Gold(I)-Catalyzed Reaction of Iodoalkynes
[Communication]

Coming soon.

Super-Wettability

Liping Wen, Ye Tian, Lei Jiang*

Bioinspired Super-Wettability from Fundamental Research to Practical Applications
[Review]

Coming soon.

Photocatalysis

Shanshan Chen[WWW], Shuai Shen, Guiji Liu, Yu Qi, Fuxiang Zhang*, Can Li*

Interface Engineering of CoOx/Ta3N5 Photocatalyst for Unprecedented Water Oxidation Performance under Visible Light Irradiation
[Communication]

Coming soon.

Solar Cells

Ishanie Rangeeka Perera, Torben Daeneke, Satoshi Makuta, Ze Yu, Yasuhiro Tachibana, Amaresh Mishra, Peter Bäuerle, C. André Ohlin, Udo Bach*, Leone Spiccia*

Application of the Tris(acetylacetonato)iron(III)/(II) Redox Couple in p-Type Dye-Sensitized Solar Cells
[Communication]

Coming soon.

Water Purification

Anthony G. Fane*, Rong Wang, Matthew X. Hu

Synthetic Membranes for Water Purification: Status and Future
[Review]

Coming soon.

Resveratrol

Bryan S. Matsuura, Mitchell H. Keylor, Bo Li, YuXuan Lin, Shelby Allison, Derek A. Pratt*, Corey R. J. Stephenson*

A Scalable Biomimetic Synthesis of Resveratrol Dimers and Systematic Evaluation of their Antioxidant Activities
[Communication]

Coming soon.

Drug Delivery

Joab O. Onyango, Michael S. Chung, Chee-Huat Eng, Lukas M. Klees, Rachel Langenbacher, Lan Yao*, Ming An*

Noncanonical Amino Acids to Improve the pH Response of pHLIP Insertion at Tumor Acidity
[Communication]

Coming soon.

Gallium Selenide

Xufan Li, Leonardo Basile, Mina Yoon, Cheng Ma, Alexander A. Puretzky, Jaekwang Lee, Juan C. Idrobo, Miaofang Chi, Christopher M. Rouleau, David B. Geohegan, Kai Xiao*

Revealing the Preferred Interlayer Orientations and Stackings of Two-Dimensional Bilayer Gallium Selenide Crystals
[Communication]

Coming soon.

Mechanophores

Doreen Schütze[WWW], Katharina Holz[WWW], Julian Müller, Martin K. Beyer*[WWW], Ulrich Lüning*, Bernd Hartke*

Pinpointing Mechanochemical Bond Rupture by Embedding the Mechanophore into a Macrocycle
[Communication]

Coming soon.

Lab-on-a-Chip

Christian Benz, Michael Boomhoff, Johannes Appun, Christoph Schneider, Detlev Belder*

Chip-Based Free-Flow Electrophoresis with Integrated Nanospray Mass-Spectrometry
[Communication]

Coming soon.

Radical Cascade Reactions

Wangqing Kong, Noelia Fuentes, Andres García-Domínguez, Estíbaliz Merino, Cristina Nevado*

Stereoselective Synthesis of Highly Functionalized Indanes and Dibenzocycloheptadienes through Complex Radical Cascade Reactions
[Communication]

Published online on January 16, 2015.
DOI: 10.1002/anie.201409659

Dyes

Daniel Jänsch, Chen Li, Long Chen, Manfred Wagner, Klaus Müllen*

Versatile Colorant Syntheses by Multiple Condensations of Acetyl Anilines with Perylene Anhydrides
[Communication]

Coming soon.

Electrocatalysis

Alexander K. Opitz*, Andreas Nenning, Christoph Rameshan, Raffael Rameshan, Raoul Blume, Michael Hävecker, Axel Knop-Gericke, Günther Rupprechter, Jürgen Fleig, Bernhard Klötzer

Enhancing Electrochemical Water-Splitting Kinetics by Polarization-Driven Formation of Near-Surface Iron(0): An In Situ XPS Study on Perovskite-Type Electrodes
[Communication]

Published online on January 21, 2015.
DOI: 10.1002/anie.201409527

Light-Emitting Diodes

Ali Hossain Khan, Amit Dalui, Soham Mukherjee, Carlo U. Segre, D. D. Sarma, Somobrata Acharya*

Efficient Solid-State Light-Emitting CuCdS Nanocrystals Synthesized in Air
[Communication]

Published online on January 16, 2015.
DOI: 10.1002/anie.201409518

Cluster Binding

Yuki Ishikawa, Seita Kimura, Kohei Takase, Koji Yamamoto, Yuki Kurashige, Takeshi Yanai, Tetsuro Murahashi*

Modulation of Benzene or Naphthalene Binding to Palladium Cluster Sites by the Backside-Ligand Effect
[Communication]

Coming soon.

Biocatalysis

Hans Renata, Z. Jane Wang, Frances H. Arnold*

Expanding the Enzyme Universe: Accessing Non-Natural Reactions by Mechanism-Guided Directed Evolution
[Review]

Coming soon.

Photocatalytic H2 Production

Michael G. Pfeffer, Bernhard Schäfer, Grigory Smolentsev, Jens Uhlig, Elena Nazarenko, Julien Guthmuller, Christian Kuhnt, Maria Wächtler, Benjamin Dietzek, Villy Sundström, Sven Rau*

Palladium versus Platinum: The Metal in the Catalytic Center of a Molecular Photocatalyst Determines the Mechanism of the Hydrogen Production with Visible Light
[Communication]

Coming soon.

2D Materials

Claudia Backes, Nina C. Berner, Xin Chen, Paul Lafargue, Pierre LaPlace, Mark Freeley, Georg S. Duesberg, Jonathan N. Coleman, Aidan R. McDonald*

Functionalization of Liquid-Exfoliated Two-Dimensional 2H-MoS2
[Communication]

Coming soon.

Heterogeneous Catalysis

Diego González-Flores, Irene Sánchez, Ivelina Zaharieva, Katharina Klingan, Jonathan Heidkamp, Petko Chernev, Prashanth W. Menezes, Matthias Driess, Holger Dau*, Mavis L. Montero*

Heterogeneous Water Oxidation: Surface Activity versus Amorphization Activation in Cobalt Phosphate Catalysts
[Communication]

Coming soon.

Structure of Boron

Mary Anne White*, Anthony B. Cerqueira, Catherine A. Whitman, Michel B. Johnson, Tadashi Ogitsu

Determination of Phase Stability of Elemental Boron
[Communication]

Coming soon.

Molecular Recognition

Harry Destecroix, Charles M. Renney, Tiddo J. Mooibroek, Tom S. Carter, Patrick F. N. Stewart, Matthew P. Crump, Anthony P. Davis*

Affinity Enhancement by Dendritic Side Chains in Synthetic Carbohydrate Receptors
[Communication]

Coming soon.

Heterogeneous Catalysis

Dohyung Kim, Kelsey K. Sakimoto, Dachao Hong, Peidong Yang*

Artificial Photosynthesis for Sustainable Fuel and Chemical Production
[Minireview]

Published online on January 21, 2015.
DOI: 10.1002/anie.201409116

Analytical Methods

Jérôme Querard, Tal-Zvi Markus, Marie-Aude Plamont, Carole Gauron, Pengcheng Wang, Agathe Espagne, Michel Volovitch, Sophie Vriz, Vincent Croquette, Arnaud Gautier*, Thomas Le Saux*, Ludovic Jullien*

Photoswitching Kinetics and Phase-Sensitive Detection Add Discriminative Dimensions for Selective Fluorescence Imaging
[Communication]

Published online on January 21, 2015.
DOI: 10.1002/anie.201408985

Synthetic Methods

Manabu Hatano[WWW], Kenji Yamashita, Mai Mizuno, Orie Ito, Kazuaki Ishihara*

C-Selective and Diastereoselective Alkyl Addition to β,γ-Alkynyl-α-imino Esters with Zinc(II)ate Complexes
[Communication]

Published online on January 16, 2015.
DOI: 10.1002/anie.201408916

Dual Catalysis

David C. Fabry, Meria A. Ronge, Jochen Zoller, Magnus Rueping*

C–H Functionalization of Phenols using Combined Ruthenium and Photoredox Catalysis: In Situ Generation of the Oxidant
[Communication]

Published online on January 21, 2015.
DOI: 10.1002/anie.201408891

Supramolecular Chemistry

Beulah E. McKenzie, Heiner Friedrich, Maarten J. M. Wirix, Joël F. de  Visser, Olivia R. Monaghan, Paul H. H. Bomans, Fabio Nudelman, Simon J. Holder*, Nico A. J. M. Sommerdijk*

Controlling Internal Pore Sizes in Bicontinuous Polymeric Nanospheres
[Communication]

Published online on January 16, 2015.
DOI: 10.1002/anie.201408811

G-Quadruplexes

Ren-yi Wu, Ke-wei Zheng, Jia-yu Zhang, Yu-hua Hao, Zheng Tan*

Formation of DNA:RNA Hybrid G-Quadruplex in Bacterial Cells and Its Dominance over the Intramolecular DNA G-Quadruplex in Mediating Transcription Termination
[Communication]

Coming soon.

C–H Amination

Dajian Zhu, Guoqiang Yang, Jian He, Ling Chu, Gang Chen, Wei Gong, Ke Chen, Martin D. Eastgate, Jin-Quan Yu*

Ligand-Promoted ortho-C–H Amination with Pd Catalysts
[Communication]

Published online on January 16, 2015.
DOI: 10.1002/anie.201408651

Ligand Design

Elke Persch, Oliver Dumele, François Diederich*

Molecular Recognition in Chemical and Biological Systems
[Review]

Coming soon.

Membranes

Remy Sounier, Gaetan Bellot, James J. Chou*

Mapping Conformational Heterogeneity of Mitochondrial Nucleotide Transporter in Uninhibited States
[Communication]

Published online on January 21, 2015.
DOI: 10.1002/anie.201408417

Polycyclic Amines

Chintada Nageswara Rao, Dieter Lentz, Hans-Ulrich Reissig*

Synthesis of Polycyclic Tertiary Carbinamines by Samarium Diiodide Mediated Cyclizations of Indolyl Sulfinyl Imines
[Communication]

Published online on January 21, 2015.
DOI: 10.1002/anie.201408324

3D Superstructures

Juan Yan, Chongya Hu, Ping Wang, Bin Zhao, Xiangyuan Ouyang, Juan Zhou, Rui Liu, Dannong He*, Chunhai Fan, Shiping Song*

Growth and Origami Folding of DNA on Nanoparticles for High-Efficiency Molecular Transport in Cellular Imaging and Drug Delivery
[Communication]

Published online on January 19, 2015.
DOI: 10.1002/anie.201408247

Aromaticity

Kévin Cocq, Valérie Maraval*, Nathalie Saffon-Merceron, Alix Saquet, Corentin Poidevin, Christine Lepetit, Remi Chauvin*

Carbo-Quinoids: Stability and Reversible Redox-Proaromatic Character towards Carbo-Benzenes
[Communication]

Coming soon.

Zintl Cluster Compounds

Christian B. Benda, Markus Waibel, Thomas F. Fässler*

On the Formation of Intermetalloid Clusters: Titanocene(III)diammin as a Versatile Reactant Toward Nonastannide Zintl Clusters
[Communication]

Coming soon.

Binary Superlattices

Sung-Hwan Lim[WWW], Hyung-Sik Jang, Jae-Min Ha, Tae-Hwan Kim, Pawel Kwasniewski, Theyencheri Narayanan, Kyeong Sik Jin, Sung-Min Choi*

Highly Ordered and Highly Aligned Two-Dimensional Binary Superlattice of a SWNT/Cylindrical-Micellar System
[Communication]

Coming soon.

Biphasic Catalysis

Marc Pera-Titus*[WWW], Loïc Leclercq, Jean-Marc Clacens, Floryan De Campo, Véronique Nardello-Rataj*

Pickering Interfacial Catalysis for Biphasic Systems: From Emulsion Design to Green Reactions
[Minireview]

Published online on January 21, 2015.
DOI: 10.1002/anie.201402069

Biofuel cells

Yang Hee Kim, Scott Banta*[WWW]

Oxidation of Methanol in an Enzymatic Biofuel Cell Using a Hydrogel Self-Assembled from Three Modified Dehydrogenases
[Communication]
(VIP - Read Abstract)

Coming soon.

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