Angewandte Chemie International Edition

Cover image for Vol. 53 Issue 39

Editor: Peter Gölitz, Deputy Editors: Neville Compton, Haymo Ross

Online ISSN: 1521-3773

Associated Title(s): Angewandte Chemie, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemistryOpen, ChemPlusChem, Zeitschrift für Chemie

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Here's a selection of upcoming papers. Also see the EarlyView page for the latest papers published online. Click on the VIP logos of upcoming articles to read their abstracts.

Borylene Complexes

Holger Braunschweig*[WWW], Melanie Forster, Thomas Kupfer, Fabian Seeler

Borylene Transfer under Thermal Conditions for the Synthesis of Rhodium and Iridium Borylene Complexes
[Communication]

Coming soon.

Boron Peroxide from O2

Justin T. Henthorn, Theodor Agapie*

Dioxygen Reactivity with a Ferrocene–Lewis Acid Pairing: Reduction to a Boron Peroxide in the Presence of Tris(pentafluorophenyl)borane
[Communication]

Coming soon.

Metallacarboranes

Wing Y. Man, Sergey Zlatogorsky, Hugo Tricas, David Ellis, Georgina M. Rosair, Alan J. Welch*

How to Make 8,1,2-closo-MC2B9 Metallacarboranes
[Communication]

Coming soon.

Water

Dietmar Paschek*, Ralf Ludwig*

Advancing into Water´s "No Man´s Land": Two Liquid States?
[Highlight]

Coming soon.

Organometallic Clusters

Jesús Campos*, Liam S. Sharninghausen, Robert H. Crabtree*, David Balcells*

A Carbene-Rich but Carbonyl-Poor [Ir6(IMe)8(CO)2H14]2+ Polyhydride Cluster as a Deactivation Product from Catalytic Glycerol Dehydrogenation
[Communication]

Coming soon.

Diastereoselectivity

Ryosuke Takeda, Akie Kawamura, Aki Kawashima, Tatsunori Sato, Hiroki Moriwaki*, Kunisuke Izawa, Kenichi Akaji, Shuni Wang, Hong Liu*, José Luis Aceña, Vadim A. Soloshonok*

Chemical Dynamic Kinetic Resolution and S/R Interconversion of Unprotected α-Amino Acids
[Communication]

Coming soon.

Bacterial Resistance

Franz von Nussbaum*, Guido Schiffer*

Aspergillomarasmine A, an Inhibitor of Bacterial Metallo-β-Lactamases Conferring blaNDM and blaVIM Resistance
[Highlight]

Coming soon.

Natural Products

Noriyasu Ishikawa, Hidenori Tanaka, Fumi Koyama, Hiroshi Noguchi, Clay C. C. Wang, Kinya Hotta, Kenji Watanabe*

Non-Heme Dioxygenase Catalyzes Atypical Oxidations of 6,7-Bicyclic Systems to form the 6,6-Quinolone Core of Viridicatin-Type Fungal Alkaloid
[Communication]

Coming soon.

Sodium-Ion Batteries

Zhe Hu, Lixiu Wang, Kai Zhang, Jianbin Wang, Fangyi Cheng, Zhanliang Tao, Jun Chen*

MoS2 Nanoflowers with Expanded Interlayers as High-Performance Anode for Sodium-Ion Batteries
[Communication]

Coming soon.

Supercapacitors

Shan Gao, Yongfu Sun*, Fengcai Lei, Liang Liang, Jiawei Liu, Wentuan Bi, Bicai Pan, Yi Xie*

Ultrahigh Energy Density Realized by a Single-Layer β-Co(OH)2 All-Solid-State Asymmetric Supercapacitor
[Communication]
(VIP - Read Abstract)

Coming soon.

Asymmetric Hydrogenation

Peng Yang, Haiyan Xu, Jianrong (Steve) Zhou*

Nickel-Catalyzed Asymmetric Transfer Hydrogenation of Olefins for the Synthesis of α- and β-Amino Acids
[Communication]

Published online on September 15, 2014.
DOI: 10.1002/anie.201407744

Elusive Isomers

Xiaoqing Zeng*, Andrea Flores Antognini, Helmut Beckers*, Helge Willner

Isomers of Disulfur Dinitride, S2N2
[Communication]

Published online on September 15, 2014.
DOI: 10.1002/anie.201407538

Oxidation of Furans

Dimitris Kalaitzakis, Myron Triantafyllakis, Ioanna Alexopoulou, Manolis Sofiadis, Georgios Vassilikogiannakis*

One-Pot Transformation of Simple Furans into 4-Hydroxy-2-cyclopentenones in Water
[Communication]

Coming soon.

Theranostic Iridium Complexes

Liang He, Cai-Ping Tan*, Rui-Rong Ye, Yi-Zhi Zhao, Ya-Hong Liu, Qiang Zhao, Liang-Nian Ji, Zong-Wan Mao*

Theranostic Iridium(III) Complexes as One- and Two-Photon Phosphorescent Trackers to Monitor Autophagic Lysosomes
[Communication]

Coming soon.

Electron-Induced decomposition

Katrin Tanzer, Linda Feketeová*, Benjamin Puschnigg, Paul Scheier, Eugen Illenberger, Stephan Denifl*

Reactions in Nitroimidazole Triggered by Low-Energy (0–2 eV) Electrons: Methylation at N1-H Completely Blocks Reactivity
[Communication]

Published online on September 15, 2014.
DOI: 10.1002/anie.201407452

Nanocluster Self-Assembly

Zhennan Wu, Yanchun Li, Jiale Liu, Zhongyuan Lu, Hao Zhang*, Bai Yang

Colloidal Self-Assembly of Catalytic Copper Nanoclusters into Ultrathin Ribbons
[Communication]

Published online on September 15, 2014.
DOI: 10.1002/anie.201407390

Nucleophile-Selective Cross-Coupling

Julian Linshoeft, Evan J. Baum, Andreas Hussain, Paul J. Gates, Christian Näther, Anne Staubitz*

Highly Tin-Selective Stille Coupling: Synthesis of a Polymer Containing a Stannole in the Main Chain
[Communication]

Coming soon.

Cluster Compounds

Jordi Poater, Miquel Solà*, Clara Viñas, Francesc Teixidor*

π Aromaticity and Three-Dimensional Aromaticity: Two sides of the Same Coin?
[Communication]

Published online on September 15, 2014.
DOI: 10.1002/anie.201407359

Helical Structures

Takeshi Yamamoto, Yuto Akai, Michinori Suginome*

Chiral Palladacycle Catalysts Generated on a Single-Handed Helical Polymer Skeleton for Asymmetric Arylative Ring Opening of 1,4-Epoxy-1,4-dihydronaphthalene
[Communication]

Coming soon.

Carbon Dioxide Reduction

Enguerrand Blondiaux[WWW], Jacky Pouessel, Thibault Cantat*

Carbon Dioxide Reduction to Methylamines under Metal-Free Conditions
[Communication]

Coming soon.

Single-Molecule Magnets

Lucile Chatelain, James P. S. Walsh, Jacques Pécaut, Floriana Tuna, Marinella Mazzanti*

Self-Assembly of a 3d–5f Trinuclear Single-Molecule Magnet from a Pentavalent Uranyl Complex
[Communication]

Coming soon.

Amyloid Formation

Jitendra K. Das[WWW], Shyam S. Mall, Aritra Bej, Sujoy Mukherjee*

Conformational Flexibility Tunes the Propensity of Transthyretin to Form Fibrils Through Non-Native Intermediate States
[Communication]

Coming soon.

Selective Hydrogenation

Hongbo Zhang[WWW], Xiang-Kui Gu, Christian Canlas, A. Jeremy Kropf, Payoli Aich, Jeffrey P. Greeley, Jeffrey W. Elam, Randall J. Meyers, James A. Dumesic, Peter C. Stair, Christopher L. Marshall*

Atomic Layer Deposition Overcoating: Tuning Catalyst Selectivity for Biomass Conversion
[Communication]

Coming soon.

Porous Polymer Films

Wei Wang, Can Du, Xiaofan Wang, Xiaohua He*, Jiaping Lin, Lei Li*, Shaoliang Lin*

Directional Photomanipulation of Breath Figure Arrays
[Communication]

Coming soon.

Target Identification

Chao Li[WWW], Ting Dong, Qiang Li, Xiaoguang Lei*

Probing the Anticancer Mechanism of (−)-Ainsliatrimer A through Diverted Total Synthesis and Bioorthogonal Ligation
[Communication]

Published online on September 15, 2014.
DOI: 10.1002/anie.201407225

Native Chemical Ligation

Andreas Reif, Sebastian Siebenhaar, Andrea Tröster, Marina Schmälzlein, Carolin Lechner, Phanindra Velisetty, Karen Gottwald, Claudia Pöhner, Irene Boos, Volker Schubert, Stefan Rose-John, Carlo Unverzagt*

Semisynthesis of Biologically Active Glycoforms of the Human Cytokine Interleukin 6
[Communication]
(VIP - Read Abstract)

Coming soon.

Electrocatalysis

Michael K. Coggins, Ming-Tian Zhang, Zuofeng Chen, Na Song, Thomas J. Meyer*

Single-Site Copper(II) Water Oxidation Electrocatalysis: Rate Enhancements with HPO42− as a Proton Acceptor at pH 8
[Communication]

Coming soon.

Radiochemistry

Steven H. Liang*, Neil Vasdev*

C(sp3)–18F Bond Formation by Transition-Metal-Based [18F]Fluorination
[Highlight]

Coming soon.

Reactive Intermediates

Eva Tudela, Jairo González, Rubén Vicente, Javier Santamaría, Miguel A. Rodríguez, Alfredo Ballesteros*

Mechanistic Studies on the Rearrangement of 1-Alkenyl-2-alkynylcyclopropanes: From Allylic Gold(I) Cations to Stable Carbocations
[Communication]

Published online on September 15, 2014.
DOI: 10.1002/anie.201407055

Carbon-Rich Porphyrins

Dominik Lungerich, Jakob F. Hitzenberger, Mario Marcia, Frank Hampel, Thomas Drewello*, Norbert Jux*

Superbenzene–Porphyrin Conjugates
[Communication]

Coming soon.

Terpenoids

Quentin Michaudel, Guillaume Journot, Alicia Regueiro-Ren, Animesh Goswami, Zhiwei Guo, Thomas P. Tully, Lufeng Zou, Raghunath O. Ramabhadran, Kendall N. Houk, Phil S. Baran*

Improving Physical Properties via C–H Oxidation: Chemical and Enzymatic Approaches
[Communication]

Coming soon.

Protein Ligation

Thomas G. Wucherpfennig[WWW], Vijaya R. Pattabiraman, Felix R. P. Limberg, Javier Ruiz-Rodríguez, Jeffrey W. Bode*[WWW]

Traceless Preparation of C-Terminal α-Ketoacids for Chemical Protein Synthesis by α-Ketoacid–Hydroxylamine Ligation: Synthesis of SUMO2/3
[Communication]

Coming soon.

Immunoproteasome Inhibition

Christian Dubiella, Haissi Cui, Malte Gersch, Arwin J. Brouwer, Stephan A. Sieber, Achim Krüger, Rob M. J. Liskamp*, Michael Groll*

Selective Inhibition of the Immunoproteasome by Ligand-Induced Crosslinking of the Active Site
[Communication]

Coming soon.

Surface Modification

Peter Ngene*, Ruud J. Westerwaal, Sumit Sachdeva, Wim Haije, Louis C. P. M. de  Smet, Bernard Dam

Polymer-Induced Surface Modifications of Pd-based Thin Films Leading to Improved Kinetics in Hydrogen Sensing and Energy Storage Applications
[Communication]

Coming soon.

Molecular Recognition

Toshifumi Takeuchi*, Takuya Mori, Atsushi Kuwahara, Takeo Ohta, Azusa Oshita, Hirobumi Sunayama, Yukiya Kitayama, Tooru Ooya

Conjugated-Protein Mimics with Molecularly Imprinted Reconstructible and Transformable Regions that are Assembled Using Space-Filling Prosthetic Groups
[Communication]

Coming soon.

Asymmetric Catalysis

Ming Chen, John F. Hartwig*

Iridium-Catalyzed Regio- and Enantioselective Allylic Substitution of Silyl Dienolates Derived from Dioxinones
[Communication]

Published online on September 15, 2014.
DOI: 10.1002/anie.201406778

Synthetic Methods

Pieter Mampuys, Yanping Zhu, Tjøstil Vlaar, Eelco Ruijter*, Romano V. A. Orru*, Bert U. W. Maes*

Sustainable Three-Component Synthesis of Isothioureas from Isocyanides, Thiosulfonates, and Amines
[Communication]

Published online on September 15, 2014.
DOI: 10.1002/anie.201406717

Oxygen Evolution

Kripasindhu Sardar, Enrico Petrucco, Craig I. Hiley, Jonathan D. B. Sharman, Peter P. Wells, Andrea E. Russell*, Reza J. Kashtiban, Jeremy Sloan, Richard I. Walton*

Water-Splitting Electrocatalysis in Acid Conditions Using Ruthenate-Iridate Pyrochlores
[Communication]

Published online on September 15, 2014.
DOI: 10.1002/anie.201406668

Chaperones

Bettina K. Zierer, Matthias Weiwad, Martin Rübbelke, Lee Freiburger, Gunter Fischer, Oliver R. Lorenz, Michael Sattler, Klaus Richter*, Johannes Buchner*

Artificial Accelerators of the Molecular Chaperone Hsp90 Facilitate Rate-Limiting Conformational Transitions
[Communication]

Coming soon.

Cancer Sensitization

Jürgen Eirich, Simone Braig, Liliana Schyschka, Phil Servatius, Judith Hoffmann, Sabrina Hecht, Simone Fulda, Stefan Zahler, Iris Antes, Uli Kazmaier, Stephan A. Sieber*, Angelika M. Vollmar*

A Small Molecule Inhibits Protein Disulfide Isomerase and Triggers the Chemosensitization of Cancer Cells
[Communication]

Coming soon.

Frustrated Lewis Pairs

Yasuharu Hasegawa, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker*

Developing Phospha-Stork Chemistry Induced by a Borane Lewis Acid
[Communication]

Coming soon.

Surface Coordination Networks

Fabian Bebensee, Katrine Svane, Christian Bombis, Federico Masini, Svetlana Klyatskaya, Flemming Besenbacher, Mario Ruben, Bjørk Hammer*, Trolle R. Linderoth*

A Surface Coordination Network Based on Copper Adatom Trimers
[Communication]

Coming soon.

Heterocycle Synthesis

Xiao-Qiang Hu[WWW], Jia-Rong Chen*, Qiang Wei, Feng-Lei Liu, Qiao-Hui Deng, André M. Beauchemin, Wen-Jing Xiao*

Photocatalytic Generation of N-Centered Hydrazonyl Radicals: A Strategy for Hydroamination of β,γ-Unsaturated Hydrazones
[Communication]

Coming soon.

Heterocycles

Kiran Matcha, Andrey P. Antonchick*

Cascade Multicomponent Synthesis of Indoles, Pyrazoles, and Pyridazinones by Functionalization of Alkenes
[Communication]

Coming soon.

Photochemistry

Elena Arceo[WWW], Elisa Montroni, Paolo Melchiorre*

Photo-Organocatalysis of Atom-Transfer Radical Additions to Alkenes
[Communication]
(VIP - Read Abstract)

Coming soon.

Membrane Nanodiscs

David J. K. Swainsbury, Stefan Scheidelaar, Rienk van Grondelle, J. Antoinette Killian*, Michael R. Jones*

Bacterial Reaction Centers Purified with Styrene Maleic Acid Copolymer Retain Native Membrane Functional Properties and Display Enhanced Stability
[Communication]

Published online on September 15, 2014.
DOI: 10.1002/anie.201406412

Photocatalysis

Jyotsna Tripathy, Kiyoung Lee, Patrik Schmuki*

Tuning the Selectivity of Photocatalytic Synthetic Reactions using Modified TiO2 Nanotubes
[Communication]

Coming soon.

Nanoparticle Self-Assembly

Joao Paulo Coelho, Guillermo González-Rubio, Annette Delices, José Osío Barcina, Cástor Salgado, David Avila, Ovidio Peña-Rodríguez, Gloria Tardajos, Andrés Guerrero-Martínez*

Polyrotaxane-Mediated Self-Assembly of Gold Nanospheres into Fully Reversible Supercrystals
[Communication]

Coming soon.

Asymmetric Catalysis

Xingzhong Zeng*, Joe J. Gao, Jinhua J. Song, Shengli Ma, Jean-Nicolas Desrosiers, Jason A. Mulder, Sonia Rodriguez, Melissa A. Herbage, Nizar Haddad, Bo Qu, Keith R. Fandrick, Nelu Grinberg, Heewon Lee, Xudong Wei, Nathan K. Yee, Chris H. Senanayake

Remarkable Enhancement of Enantioselectivity in the Asymmetric Conjugate Addition of Dimethylzinc to (Z)-Nitroalkenes with a Catalytic [(MeCN)4Cu]PF6–Hoveyda Ligand Complex
[Communication]

Published online on September 15, 2014.
DOI: 10.1002/anie.201406247

Actinide Chemistry

Wenshan Ren, Enwei Zhou, Bo Fang, Guohua Hou, Guofu Zi*, De-Cai Fang*, Marc D. Walter*

Experimental and Computational Studies on the Reactivity of a Terminal Thorium Imidometallocene towards Organic Azides and Diazoalkanes
[Communication]

Coming soon.

Olefination

Emma E. Coyle, Bryan J. Doonan, Andrew J. Holohan, Killian A. Walsh, Florie Lavigne, Elizabeth H. Krenske*, Christopher J. O´Brien*

Catalytic Wittig Reactions of Semi- and Nonstabilized Ylides Enabled by Ylide Tuning
[Communication]

Coming soon.

Ester Ligation

Thomas G. Wucherpfennig[WWW], Florian Rohrbacher, Vijaya R. Pattabiraman, Jeffrey W. Bode*[WWW]

Formation and Rearrangement of Homoserine Depsipeptides and Depsiproteins in the α-Ketoacid–Hydroxylamine Ligation with 5-Oxaproline
[Communication]

Coming soon.

Cell Differentiation

Tao Bai, Fang Sun, Lei Zhang, Andrew Sinclair, Sijun Liu, Jean-Rene Ella-Menye, Ying Zheng, Shaoyi Jiang*

Restraint of the Differentiation of Mesenchymal Stem Cells by a Nonfouling Zwitterionic Hydrogel
[Communication]

Coming soon.

P4 Functionalization

Jaap E. Borger, Andreas W. Ehlers, Martin Lutz, J. Chris Slootweg, Koop Lammertsma*

Functionalization of P4 using a Lewis Acid Stabilized Bicyclo[1.1.0]tetraphosphabutane Anion
[Communication]

Coming soon.

Organocatalysis

Daniel T. Ziegler, Lorena Riesgo, Takuya Ikeda, Yuji Fujiwara, Gregory C. Fu*

Biphenyl-Derived Phosphepines as Chiral Nucleophilic Catalysts: Enantioselective [4+1] Annulations To Form Functionalized Cyclopentenes
[Communication]

Coming soon.

Protein Separation

Avik Samanta, Bart Jan Ravoo*

Magnetic Separation of Proteins by a Self-Assembled Supramolecular Ternary Complex
[Communication]

Coming soon.

Drug Discovery

Alba Pérez-Perarnau, Sara Preciado, Claudia Mariela Palmeri, Cristina Moncunill-Massaguer, Daniel Iglesias-Serret, Diana M. González-Gironès, Miriam Miguel, Satoki Karasawa, Satoshi Sakamoto, Ana M. Cosialls, Camila Rubio-Patiño, José Saura-Esteller, Rosario Ramón, Laia Caja, Isabel Fabregat, Gabriel Pons, Hiroshi Handa, Fernando Albericio*, Joan Gil*, Rodolfo Lavilla*

A Trifluorinated Thiazoline Scaffold Leading to Pro-apoptotic Agents Targeting Prohibitins
[Communication]

Published online on September 17, 2014.
DOI: 10.1002/anie.201405758

Solid-State NMR Spectroscopy

Vipin Agarwal, Susanne Penzel, Kathrin Szekely, Riccardo Cadalbert, Emilie Testori, Andres Oss, Jaan Past, Ago Samoson*, Matthias Ernst*, Anja Böckmann*, Beat H. Meier*

De Novo 3D Structure Determination from Sub-milligram Protein Samples by Solid-State 100 kHz MAS NMR Spectroscopy
[Communication]
(VIP) title=

Published online on September 15, 2014.
DOI: 10.1002/anie.201405730

DNA nanotechnology

Jonathan R. Burns, Noura Al-Juffali, Sam M. Janes, Stefan Howorka*

Membrane-Spanning DNA Nanopores with Cytotoxic Effect
[Communication]

Coming soon.

Oxidation Catalysis

Weifeng Tu[WWW], Ya-Huei (Cathy) Chin*

Catalytic Consequences of the Thermodynamic Activities at Metal Cluster Surfaces and Their Periodic Reactivity Trend for Methanol Oxidation
[Communication]

Published online on September 15, 2014.
DOI: 10.1002/anie.201405232

C–C Activation

Ilan Marek*, Ahmad Masarwa, Pierre-Olivier Delaye, Markus Leibeling

Selective Carbon–Carbon Bond Cleavage for the Stereoselective Synthesis of Acyclic Systems
[Review]

Coming soon.

Nanoparticle Surfaces

Peter Felfer, Paul Benndorf, Anthony Masters, Thomas Maschmeyer*, Julie M. Cairney

Revealing the Distribution of the Atoms within Individual Bimetallic Catalyst Nanoparticles
[Communication]

Coming soon.

Biosensors

Yanyan Yu, Lin Zhang, Chenglin Li, Xiaoyu Sun, Daoquan Tang, Guoyue Shi*

A Method for Evaluating the Level of Soluble β-Amyloid (1–40/1–42) in Alzheimer´s Disease Based on the Binding of Gelsolin to β-Amyloid Peptides
[Communication]

Coming soon.

Solar Cells

Longbin Qiu, Jue Deng, Xin Lu, Zhibin Yang, Huisheng Peng*

Integrating Perovskite Solar Cells into a Flexible Fiber
[Communication]
(VIP) title=

Published online on September 17, 2014.
DOI: 10.1002/anie.201404973

Dissociation Dynamics

Frímann H. Omarsson, Nigel J. Mason*, E. Krishnakumar*, Oddur Ingólfsson*

State Selectivity and Dynamics in Dissociative Electron Attachment to CF3I Revealed through Velocity Slice Imaging
[Communication]

Published online on September 15, 2014.
DOI: 10.1002/anie.201403859

Binary Superlattices

Sung-Hwan Lim[WWW], Hyung-Sik Jang, Jae-Min Ha, Tae-Hwan Kim, Pawel Kwasniewski, Theyencheri Narayanan, Kyeong Sik Jin, Sung-Min Choi*

Highly Ordered and Highly Aligned Two-Dimensional Binary Superlattice of a SWNT/Cylindrical-Micellar System
[Communication]

Coming soon.

Aryl Ether Cross-Coupling

Matthias Leiendecker, Chien-Chi Hsiao, Lin Guo, Nurtalya Alandini, Magnus Rueping*

Metal-Catalyzed Dealkoxylative Caryl–C(sp3) Cross-Coupling—Replacement of Aromatic Methoxy Groups of Aryl Ethers by Employing a Functionalized Nucleophile
[Communication]

Coming soon.

C–H Functionalization

David C. Fabry, Jochen Zoller, Sadiya Raja, Magnus Rueping*

Combining Rhodium and Photoredox Catalysis for C–H Functionalizations of Arenes: Oxidative Heck Reactions with Visible Light
[Communication]

Published online on September 17, 2014.
DOI: 10.1002/anie.201400560

Photomechanics

Toru Ube[WWW], Tomiki Ikeda*

Photomobile Polymer Materials with Crosslinked Liquid-Crystalline Structures: Molecular Design, Fabrication, and Functions
[Minireview]

Published online on September 17, 2014.
DOI: 10.1002/anie.201400513

Biofuel cells

Yang Hee Kim, Scott Banta*[WWW]

Oxidation of Methanol in an Enzymatic Biofuel Cell Using a Hydrogel Self-Assembled from Three Modified Dehydrogenases
[Communication]
(VIP - Read Abstract)

Coming soon.

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