Angewandte Chemie International Edition

Cover image for Vol. 54 Issue 32

Editor: Peter Gölitz, Deputy Editors: Neville Compton, Haymo Ross

Online ISSN: 1521-3773

Associated Title(s): Angewandte Chemie, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemistryOpen, ChemPlusChem, Zeitschrift für Chemie

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Here's a selection of upcoming papers. Also see the EarlyView page for the latest papers published online. Click on the VIP logos of upcoming articles to read their abstracts.

Borylene Complexes

Holger Braunschweig*[WWW], Melanie Forster, Thomas Kupfer, Fabian Seeler

Borylene Transfer under Thermal Conditions for the Synthesis of Rhodium and Iridium Borylene Complexes
[Communication]

Coming soon.

Perovskite Phases

Man-Rong Li, Maria Retuerto, Zheng Deng, Peter W. Stephens, Mark Croft, Qingzhen Huang, Hui Wu, Xiaoyu Deng, Gabriel Kotliar, Javier Sánchez-Benítez, Joke Hadermann, David Walker, Martha Greenblatt*

Giant Magnetoresistance in the Half-Metallic Double-Perovskite Ferrimagnet Mn2FeReO6
[Communication]

Published online on August 1, 2015.
DOI: 10.1002/anie.201506456

Electrochemistry

Timothy A. Brown, Hao Chen*, Richard N. Zare*

Detection of the Short-Lived Radical Cation Intermediate in the Electrooxidation of N,N-Dimethylaniline by Mass Spectrometry
[Communication]
(VIP - Read Abstract)

Coming soon.

Wearable Electronics

Ye Zhang, Yang Zhao, Xunliang Cheng, Wei Weng, Jing Ren, Xin Fang, Yishu Jiang, Peining Chen, Zhitao Zhang, Yonggang Wang, Huisheng Peng*

Realizing both High Energy and High Power Densities by Twisting Three Carbon-Nanotube-Based Hybrid Fibers
[Communication]

Coming soon.

Frustrated Lewis Pairs

Yoichi Hoshimoto*, Takuya Kinoshita, Masato Ohashi, Sensuke Ogoshi*

A Strategy to Control the Reactivation of Frustrated Lewis Pairs from Shelf-Stable Carbene Borane Complexes
[Communication]

Coming soon.

Homogeneous Catalysis

Mathew D. Anker, Michael S. Hill*, John P. Lowe, Mary F. Mahon

Alkaline-Earth-Promoted CO Homologation and Reductive Catalysis
[Communication]

Published online on July 28, 2015.
DOI: 10.1002/anie.201505851

Pyrotechnics

Jesse J. Sabatini*, Ernst-Christian Koch*, Jay C. Poret, Jared D. Moretti, Seth M. Harbol

Chlorine-Free Red-Burning Pyrotechnics
[Communication]

Coming soon.

Isomerization

Andrew J. Warner, James R. Lawson, Valerio Fasano, Michael J. Ingleson*

Formation of C(sp2)–Boronate Esters by Borylative Cyclization of Alkynes Using BCl3
[Communication]

Published online on August 1, 2015.
DOI: 10.1002/anie.201505810

Origin of Life

Neha P. Kamat, Sylvia Tobé, Ian T. Hill, Jack W. Szostak*

Electrostatic Localization of RNA to Protocell Membranes by Cationic Hydrophobic Peptides
[Communication]

Published online on July 30, 2015.
DOI: 10.1002/anie.201505742

Cation–π Interactions

Manon Isaac, Sergey A. Denisov, Amandine Roux, Daniel Imbert, Gediminas Jonusauskas, Nathan D. McClenaghan*, Olivier Sénèque*

Lanthanide Luminescence Modulation by Cation–π Interaction in a Bioinspired Scaffold: Selective Detection of Copper(I)
[Communication]

Published online on July 30, 2015.
DOI: 10.1002/anie.201505733

Aza-Diels–Alder Reactions

Haifeng Zheng, Xiaohua Liu*, Chaoran Xu, Yong Xia, Lili Lin, Xiaoming Feng*

Regio- and Enantioselective Aza-Diels–Alder Reactions of 3-Vinylindoles: A Concise Synthesis of the Antimalarial Spiroindolone NITD609
[Communication]

Published online on July 29, 2015.
DOI: 10.1002/anie.201505717

Biocatalysis

Eduardo Busto*, Robert C. Simon, Wolfgang Kroutil*

Vinylation of Unprotected Phenols Using a Biocatalytic System
[Communication]

Published online on July 30, 2015.
DOI: 10.1002/anie.201505696

Transition-Metal Catalysis

Stefan A. Künzi, Juan Manuel Sarria Toro, Tim den Hartog, Peter Chen*

Nickel-Catalyzed Cyclopropanation with NMe4OTf and nBuLi
[Communication]

Published online on July 29, 2015.
DOI: 10.1002/anie.201505482

Raman Spectroscopy

Shojiro Haraguchi, Miwa Hara, Takahito Shingae, Masato Kumauchi, Wouter D. Hoff, Masashi Unno*

Experimental Detection of the Intrinsic Difference in Raman Optical Activity of a Photoreceptor Protein under Preresonance and Resonance Conditions
[Communication]

Published online on July 27, 2015.
DOI: 10.1002/anie.201505466

Smart Drug Delivery

Viktoriia Postupalenko, Dominique Desplancq, Igor Orlov, Youri Arntz, Danièle Spehner, Yves Mely, Bruno P. Klaholz, Patrick Schultz, Etienne Weiss, Guy Zuber*

Protein Delivery System Containing a Nickel-Immobilized Polymer for Multimerization of Affinity-Purified His-Tagged Proteins Enhances Cytosolic Transfer
[Communication]

Published online on July 31, 2015.
DOI: 10.1002/anie.201505437

Oligosaccharides

Lin Liu, Jingying Zha, Antonio DiGiandomenico, Douglas McAllister, C. Kendall Stover, Qun Wang*, Geert-Jan Boons*

Synthetic Enterobacterial Common Antigen (ECA) for the Development of a Universal Immunotherapy for Drug-Resistant Enterobacteriaceae
[Communication]

Published online on July 27, 2015.
DOI: 10.1002/anie.201505420

High-Pressure NMR Spectroscopy

Vitali Tugarinov*, David S. Libich, Virginia Meyer, Julien Roche, G. Marius Clore*

The Energetics of a Three-State Protein Folding System Probed by High-Pressure Relaxation Dispersion NMR Spectroscopy
[Communication]

Coming soon.

Asymmetric Annulation

Miyuki Hatano, Takahiro Nishimura*

Hydroxoiridium/Chiral Diene Complexes as Effective Catalysts for Asymmetric Annulation of α-Oxo- and Iminocarboxamides with 1,3-Dienes
[Communication]

Published online on July 29, 2015.
DOI: 10.1002/anie.201505382

Synthetic Methods

Laurence Burroughs, Lee Eccleshare, John Ritchie, Omkar Kulkarni, Barry Lygo, Simon Woodward*, William Lewis

One-Pot Cannizzaro Cascade Synthesis of ortho-Fused Cycloocta-2,5-dien-1-ones from 2-Bromo(hetero)aryl Aldehydes
[Communication]

Published online on July 31, 2015.
DOI: 10.1002/anie.201505347

Energy Conversion

Qunwei Tang*, Huihui Zhang, Yuanyuan Meng, Benlin He, Liangmin Yu*

Dissolution Engineering of Platinum Alloy Counter Electrodes in Dye-Sensitized Solar Cells
[Communication]

Published online on July 28, 2015.
DOI: 10.1002/anie.201505339

Heterocycle Synthesis

Yoichiro Kuninobu*, Masahiro Nagase, Motomu Kanai*

Benzylic C(sp3)–H Perfluoroalkylation of Six-Membered Heteroaromatic Compounds
[Communication]

Published online on July 31, 2015.
DOI: 10.1002/anie.201505335

Zeolite Catalysts

Limin Ren, Qiang Guo, Prashant Kumar, Marat Orazov, Dandan Xu, Saeed M. Alhassan, K. Andre Mkhoyan, Mark E. Davis, Michael Tsapatsis*

Self-Pillared, Single-Unit-Cell Sn-MFI Zeolite Nanosheets and Their Use for Glucose and Lactose Isomerization
[Communication]
(VIP) title=

Published online on July 27, 2015.
DOI: 10.1002/anie.201505334

Supramolecular Chemistry

Michael Yanney*, Frank R. Fronczek, Andrzej Sygula*

A 2:1 Receptor/C60 Complex as a Nanosized Universal Joint
[Communication]

Coming soon.

Oxygen Evolution Reaction

Youwen Liu, Chong Xiao*, Mengjie Lyu, Yue Lin, Weizheng Cai, Pengcheng Huang, Wei Tong, Youming Zou, Yi Xie*

Ultrathin Co3S4 Nanosheets that Synergistically Engineer Spin States and Exposed Polyhedra that Promote Water Oxidation under Neutral Conditions
[Communication]

Published online on July 31, 2015.
DOI: 10.1002/anie.201505320

Pseudoreversible Reaction

William Mahy, Pawel Plucinski, Jesús Jover, Christopher G. Frost*

Ruthenium-Catalyzed O- to S-Alkyl Migration: A Pseudoreversible Barton–McCombie Pathway
[Communication]

Published online on July 28, 2015.
DOI: 10.1002/anie.201505280

Water Splitting

Liang Liang, Hao Cheng, Fengcai Lei, Jun Han, Shan Gao, Chengming Wang, Yongfu Sun*, Shaista Qamar, Shiqiang Wei*, Yi Xie*

Metallic Single-Unit-Cell Orthorhombic Cobalt Diselenide Atomic Layers: Robust Water-Electrolysis Catalysts
[Communication]

Published online on July 31, 2015.
DOI: 10.1002/anie.201505245

Peptides

Stefania Federico, Benjamin F. Pierce, Susanna Piluso, Christian Wischke, Andreas Lendlein, Axel T. Neffe*

Design of Decorin-Based Peptides that Bind to Collagen I and their Potential as Adhesion Moieties in Biomaterials
[Communication]

Published online on July 28, 2015.
DOI: 10.1002/anie.201505227

C–H Activation

Brian N. Laforteza, Kelvin S. L. Chan, Jin-Quan Yu*

Enantioselective ortho-C–H Cross-Coupling of Diarylmethylamines with Organoborons
[Communication]

Coming soon.

Photochemistry

Chenkun Zhou, Yu Tian, Zhao Yuan, Mingu Han, Jamie Wang, Lei Zhu, Maliheh Shaban Tameh, Chen Huang*, Biwu Ma*

Precise Design of Phosphorescent Molecular Butterflies with Tunable Photoinduced Structural Change and Dual Emission
[Communication]

Coming soon.

Natural Products

Yiyang Liu, Scott C. Virgil, Robert H. Grubbs*, Brian M. Stoltz*

Palladium-Catalyzed Decarbonylative Dehydration for the Synthesis of α-Vinyl Carbonyl Compounds and Total Synthesis of (−)-Aspewentins A, B, and C
[Communication]
(VIP) title=

Published online on July 31, 2015.
DOI: 10.1002/anie.201505161

Cycloaddition

Christian Ebner[WWW], Erick M. Carreira*

Pentafulvene for the Synthesis of Complex Natural Products: Total Syntheses of (±)-Pallambins A and B
[Communication]

Published online on July 31, 2015.
DOI: 10.1002/anie.201505126

Aromaticity

Fengkun Chen, Yong Seok Hong, Soji Shimizu, Dongho Kim*, Takayuki Tanaka*, Atsuhiro Osuka*

Synthesis of a Tetrabenzotetraaza[8]circulene by a "Fold-In" Oxidative Fusion Reaction
[Communication]

Published online on July 27, 2015.
DOI: 10.1002/anie.201505124

Atom–Molecule Reactions

Guoliang Li*, Qian-Shu Li, Yaoming Xie, Henry F. Schaefer III*

From Gas-Phase to Liquid-Water Chemical Reactions: The Fluorine Atom Plus Water Trimer System
[Communication]

Published online on July 29, 2015.
DOI: 10.1002/anie.201505075

Heterogeneous Catalysis

Gianvito Vilé, Davide Albani, Maarten Nachtegaal, Zupeng Chen, Dariya Dontsova, Markus Antonietti, Núria López*, Javier Pérez-Ramírez*

A Stable Single-Site Palladium Catalyst for Hydrogenations
[Communication]

Published online on July 31, 2015.
DOI: 10.1002/anie.201505073

Enzymes

Maximilian G. Plach, Patrick Löffler, Rainer Merkl, Reinhard Sterner*

Conversion of Anthranilate Synthase into Isochorismate Synthase: Implications for the Evolution of Chorismate-Utilizing Enzymes
[Communication]

Coming soon.

Proteasome Inhibition

Philipp Beck, Michèle Reboud-Ravaux, Michael Groll*

Identification of a β1/β2-Specific Sulfonamide Proteasome Ligand by Crystallographic Screening
[Communication]

Coming soon.

Total Synthesis

Yinan Zhang, Qing Ye, Xiachang Wang, Qing-Bai She, Jon S. Thorson*

A Divergent Enantioselective Strategy for the Synthesis of Griseusins
[Communication]

Published online on July 31, 2015.
DOI: 10.1002/anie.201505022

Programmable Materials

Thomas Heuser[WWW], Elisabeth Weyandt, Andreas Walther*

Biocatalytic Feedback-Driven Temporal Programming of Self-Regulating Peptide Hydrogels
[Communication]

Coming soon.

Cholesterol

Johan E. van Lier*, Natalia Mast, Irina A. Pikuleva*

Cholesterol Hydroperoxides as Substrates for Cholesterol-Metabolizing Cytochrome P450 Enzymes and Alternative Sources of 25-Hydroxycholesterol and other Oxysterols
[Communication]

Published online on July 31, 2015.
DOI: 10.1002/anie.201505002

Hypervalent Compounds

Vincent Corcé, Lise-Marie Chamoreau, Etienne Derat, Jean-Philippe Goddard*, Cyril Ollivier*, Louis Fensterbank*

Silicates as Latent Alkyl Radical Precursors: Visible-Light Photocatalytic Oxidation of Hypervalent Bis-Catecholato Silicon Compounds
[Communication]

Published online on July 27, 2015.
DOI: 10.1002/anie.201504963

Total Synthesis

Jae Hyun Kim, Seokwoo Lee, Sanghee Kim*

Biomimetic Total Synthesis of (−)-Penibruguieramine A Using Memory of Chirality and Dynamic Kinetic Resolution
[Communication]

Published online on July 31, 2015.
DOI: 10.1002/anie.201504954

Enantioselective Membranes

Xilun Weng, José E. Baez, Mariya Khiterer, Madelene Y. Hoe, Zongbi Bao, Kenneth J. Shea*

Chiral Polymers of Intrinsic Microporosity: Selective Membrane Permeation of Enantiomers
[Communication]

Coming soon.

MicroRNA Detection

Zongwen Jin, Daniel Geißler, Xue Qiu, K. David Wegner, Dr. Niko Hildebrandt*

A Rapid, Amplification-Free, and Sensitive Diagnostic Assay for Single-Step Multiplexed Fluorescence Detection of MicroRNA
[Communication]

Coming soon.

Iminoborane

Anindya K. Swarnakar[WWW], Christian Hering-Junghans, Koichi Nagata, Michael J. Ferguson, Robert McDonald, Norihiro Tokitoh, Eric Rivard*

Encapsulating Inorganic Acetylene, HBNH, Using Flanking Coordinative Interactions
[Communication]

Published online on July 27, 2015.
DOI: 10.1002/anie.201504867

CO Homologues

Günther Thiele, Yannick Franzke, Florian Weigend, Stefanie Dehnen*

{μ-PbSe}: A Heavy CO Homologue as an Unexpected Ligand
[Communication]

Published online on July 31, 2015.
DOI: 10.1002/anie.201504863

Supramolecular Chemistry

Colm Browne[WWW], William J. Ramsay, Tanya K. Ronson, John Medley-Hallam, Jonathan R. Nitschke*

Carbon Dioxide Fixation and Sulfate Sequestration by a Supramolecular Trigonal Bipyramid
[Communication]

Published online on August 1, 2015.
DOI: 10.1002/anie.201504856

Nanoporous Membranes

Damien Montarnal, Nicolas Delbosc, Cécile Chamignon, Marie-Alice Virolleaud, Yingdong Luo, Craig J. Hawker, Eric Drockenmuller, Julien Bernard*

Highly Ordered Nanoporous Films from Supramolecular Diblock Copolymers with Hydrogen-Bonding Junctions
[Communication]
(VIP) title=

Published online on July 31, 2015.
DOI: 10.1002/anie.201504838

Polymerization

Andrew W. Baggett, Fang Guo, Bo Li, Shih-Yuan Liu*, Frieder Jäkle*

Regioregular Synthesis of Azaborine Oligomers and a Polymer with a syn Conformation Stabilized by N–H···π Interactions
[Communication]

Coming soon.

Light-Emitting Diodes

Hoang-Duy Nguyen, Chun Che Lin, Ru-Shi Liu*

Waterproof Alkyl Phosphate Coated Fluoride Phosphors for Optoelectronic Materials
[Communication]

Published online on July 27, 2015.
DOI: 10.1002/anie.201504791

Chiral Anion Catalysis

Jie Yu, Hua-Jie Jiang, Ya Zhou, Shi-Wei Luo, Liu-Zhu Gong*

Sodium Salts of Anionic Chiral Cobalt(III) Complexes as Catalysts of the Enantioselective Povarov Reaction
[Communication]

Published online on July 31, 2015.
DOI: 10.1002/anie.201504790

Luminescent Materials

Cheng Gu, Ning Huang, Yang Wu, Hong Xu, Donglin Jiang*

Design of Highly Photofunctional Porous Polymer Films with Controlled Thickness and Prominent Microporosity
[Communication]

Published online on July 31, 2015.
DOI: 10.1002/anie.201504786

Artificial Base Pairs

Armando R. Hernandez, Yaming Shao, Shuichi Hoshika, Zunyi Yang, Sandip A. Shelke, Julien Herrou, Hyo-Joong Kim, Myong-Jung Kim, Joseph A. Piccirilli*, Steven A. Benner*

A Crystal Structure of a Functional RNA Molecule Containing an Artificial Nucleobase Pair
[Communication]

Coming soon.

Fast Photoreactions

Jan O. Mueller, Friedrich G. Schmidt, James P. Blinco*, Christopher Barner-Kowollik*

Visible-Light-Induced Click Chemistry
[Communication]

Published online on July 27, 2015.
DOI: 10.1002/anie.201504716

Asymmetric Catalysis

Ren-Rong Liu, Shi-Chun Ye, Chuan-Jun Lu, Gui-Lin Zhuang, Jian-Rong Gao, Yi-Xia Jia*

Dual Catalysis for the Redox Annulation of Nitroalkynes with Indoles: Enantioselective Construction of Indolin-3-ones Bearing Quaternary Stereocenters
[Communication]

Coming soon.

Multicomponent Reactions

Junliang Wu, Naohiko Yoshikai*

Modular Synthesis of Multisubstituted Furans through Palladium-Catalyzed Three-Component Condensation of Alkynylbenziodoxoles, Carboxylic Acids, and Imines
[Communication]

Published online on July 31, 2015.
DOI: 10.1002/anie.201504687

Organocatalysis

Andrei Ungureanu, Alison Levens, Lisa Candish, David W. Lupton*

N-Heterocyclic Carbene Catalyzed Synthesis of δ-Sultones via α,β-Unsaturated Sulfonyl Azolium Intermediates
[Communication]

Coming soon.

Main-Group Radicals

Ryan J. Schwamm, Jeffrey R. Harmer, Matthias Lein, Christopher M. Fitchett, Simon Granville, Martyn P. Coles*

Isolation and Characterization of a Bismuth(II) Radical
[Communication]

Published online on July 28, 2015.
DOI: 10.1002/anie.201504632

Asymmetric Catalysis

Jianguang Liu, Yingying Tian, Jialing Shi, Shasha Zhang, Qian Cai*

An Enantioselective Synthesis of Spirobilactams through Copper-Catalyzed Intramolecular Double N-Arylation and Phase Separation
[Communication]

Published online on July 30, 2015.
DOI: 10.1002/anie.201504589

Diborane(6)

Johannes Landmann, Jan A. P. Sprenger, Michael Hailmann, Vera Bernhardt-Pitchougina, Helge Willner, Nikolai Ignat´ev, Eduard Bernhardt*, Maik Finze*

The Hexacyanodiborane(6) Dianion [B2(CN)6]2−
[Communication]

Published online on July 29, 2015.
DOI: 10.1002/anie.201504579

Iron–Sulfur–Gold Clusters

Danielle J. Crouthers, Shengda Ding, Jason A. Denny, Ryan D. Bethel, Chung-Hung Hsieh, Michael B. Hall, Marcetta Y. Darensbourg*

A Reduced 2Fe2S Cluster Probe of Sulfur–Hydrogen versus Sulfur–Gold Interactions
[Communication]

Coming soon.

Membrane Proteins

Keiichi Inoue, Masae Konno, Rei Abe-Yoshizumi, Hideki Kandori*

The Role of the NDQ Motif in Sodium-Pumping Rhodopsins
[Communication]

Published online on July 27, 2015.
DOI: 10.1002/anie.201504549

Epoxidation Catalysis

Xiaofang Yang, Shyam Kattel, Ke Xiong, Kumudu Mudiyanselage, Sergei Rykov, Sanjaya D. Senanayake, José A. Rodriguez, Ping Liu, Dario J. Stacchiola, Jingguang G. Chen*

Direct Epoxidation of Propylene over Stabilized Cu+ Surface Sites on Titanium-Modified Cu2O
[Communication]

Published online on July 27, 2015.
DOI: 10.1002/anie.201504538

Nanotheranostics

Wenpei Fan, Wenbo Bu*, Zhen Zhang, Bo Shen, Hui Zhang, Qianjun He, Dalong Ni, Zhaowen Cui, Kuaile Zhao, Jiwen Bu, Jiulin Du, Jianan Liu, Jianlin Shi*

X-ray Radiation-Controlled NO-Release for On-Demand Depth-Independent Hypoxic Radiosensitization
[Communication]

Published online on July 30, 2015.
DOI: 10.1002/anie.201504536

Heterocycle Synthesis

Shashikant U. Dighe, Sushobhan Mukhopadhyay, Shivalinga Kolle, Sanjeev Kanojiya, Sanjay Batra*

Synthesis of 3,4,5-Trisubstituted Isoxazoles from Morita–Baylis–Hillman Acetates by an NaNO2/I2-Mediated Domino Reaction
[Communication]

Published online on July 27, 2015.
DOI: 10.1002/anie.201504529

C–H Activation

Xiaolei Huang, Yan Wang, Jingbo Lan, Jingsong You*

Rhodium(III)-Catalyzed Activation of C(sp3)–H Bonds and Subsequent Intermolecular Amidation at Room Temperature
[Communication]

Published online on July 31, 2015.
DOI: 10.1002/anie.201504507

Biosynthesis

Micah T. Nelp, Vahe Bandarian*

A Single Enzyme Transforms a Carboxylic Acid into a Nitrile through an Amide Intermediate
[Communication]

Published online on July 30, 2015.
DOI: 10.1002/anie.201504505

Photocatalysis

Oliver Puntigam, László Könczöl, László Nyulászi*, Dietrich Gudat*

Specific Photochemical Dehydrocoupling of N-Heterocyclic Phosphanes and Their Use in the Photocatalytic Generation of Dihydrogen
[Communication]

Published online on July 27, 2015.
DOI: 10.1002/anie.201504504

EPR Spectroscopy

Antonio Fernandez, Eufemio Moreno Pineda, Christopher A. Muryn, Stephen Sproules, Fabrizio Moro, Grigore A. Timco, Eric J. L. McInnes, Richard E. P. Winpenny*

g-Engineering in Hybrid Rotaxanes To Create AB and AB2 Electron Spin Systems: EPR Spectroscopic Studies of Weak Interactions between Dissimilar Electron Spin Qubits
[Communication]

Published online on July 29, 2015.
DOI: 10.1002/anie.201504487

Cluster Compounds

Takane Imaoka, Hirokazu Kitazawa, Wang-Jae Chun, Kimihisa Yamamoto*

Finding the Most Catalytically Active Platinum Clusters With Low Atomicity
[Communication]

Published online on July 27, 2015.
DOI: 10.1002/anie.201504473

Hybrid Polymers

Benjamin W. Rawe, Derek P. Gates*

Poly(p-phenylenediethynylene phosphane): A Phosphorus-Containing Macromolecule that Displays Blue Fluorescence Upon Oxidation
[Communication]

Published online on July 28, 2015.
DOI: 10.1002/anie.201504464

Mercury Pollutants

Mainak Banerjee, Ramesh Karri, Kuber Singh Rawat, Karthick Muthuvel, Biswarup Pathak, Gouriprasanna Roy*

Chemical Detoxification of Organomercurials
[Communication]

Published online on July 31, 2015.
DOI: 10.1002/anie.201504413

Perovskite Phases

Sa Chen, Ran Shang, Bing-Wu Wang, Zhe-Ming Wang*, Song Gao*

An A-Site Mixed-Ammonium Solid Solution Perovskite Series of [(NH2NH3)x(CH3NH3)1−x][Mn(HCOO)3] (x=1.00–0.67)
[Communication]

Coming soon.

Lipid Bilayers

Sun Hae Ra Shin, Hee-Young Lee, Kyle J. M. Bishop*

Amphiphilic Nanoparticles Control the Growth and Stability of Lipid Bilayers with Open Edges
[Communication]

Published online on July 28, 2015.
DOI: 10.1002/anie.201504362

Oxygen-Evolution Catalysts

Jun Wang, Kai Li, Hai-xia Zhong, Dan Xu, Zhong-li Wang, Zheng Jiang, Zhi-jian Wu, Xin-bo Zhang*

Synergistic Effect between Metal–Nitrogen–Carbon Sheets and NiO Nanoparticles for Enhanced Electrochemical Water-Oxidation Performance
[Communication]

Published online on July 28, 2015.
DOI: 10.1002/anie.201504358

Hybrid Materials

Ophélie Riou, Barbara Lonetti*, Reasmey P. Tan, Justine Harmel, Katerina Soulantica, Patrick Davidson, Anne-Françoise Mingotaud, Marc Respaud, Bruno Chaudret, Monique Mauzac

Room-Temperature, Strain-Tunable Orientation of Magnetization in a Hybrid Ferromagnetic Co Nanorod–Liquid Crystalline Elastomer Nanocomposite
[Communication]

Published online on July 27, 2015.
DOI: 10.1002/anie.201504320

Soft Matter

Kanghee Cho, Hyun Jong Lee, San Won Han, Ji Hong Min, Hansoo Park, Won-Gun Koh*

Multi-Compartmental Hydrogel Microparticles Fabricated by Combination of Sequential Electrospinning and Photopatterning
[Communication]

Published online on July 30, 2015.
DOI: 10.1002/anie.201504317

Radical Reactions

Jianquan Liu, Zhenhua Liu, Peiqiu Liao, Lin Zhang, Tao Tu, Xihe Bi*

Silver-Catalyzed Cross-Coupling of Isocyanides and Active Methylene Compounds by a Radical Process
[Communication]

Published online on July 27, 2015.
DOI: 10.1002/anie.201504254

Fluorescence Imaging

Paresh Agarwal, Brendan J. Beahm, Peyton Shieh, Carolyn R. Bertozzi*

Systemic Fluorescence Imaging of Zebrafish Glycans with Bioorthogonal Chemistry
[Communication]

Published online on July 31, 2015.
DOI: 10.1002/anie.201504249

Solid-Phase Synthesis

Longrui Chen, Mark O. Bovee, Betsegaw E. Lemma, Kimberlee S. M. Keithley, Sara L. Pilson, Michael G. Coleman*, James Mack*

An Inexpensive and Recyclable Silver-Foil Catalyst for the Cyclopropanation of Alkenes with Diazoacetates under Mechanochemical Conditions
[Communication]

Coming soon.

Hydrogen Trioxide

Gregor Strle, Janez Cerkovnik*

A Simple and Efficient Preparation of High-Purity Hydrogen Trioxide (HOOOH)
[Communication]

Published online on July 31, 2015.
DOI: 10.1002/anie.201504084

Photocatalysis

Jiang Wang[WWW], Nan Zheng*

The Cleavage of a C–C Bond in Cyclobutylanilines by Visible-Light Photoredox Catalysis: Development of a [4+2] Annulation Method
[Communication]

Published online on July 30, 2015.
DOI: 10.1002/anie.201504076

Allylic Compounds

Xiangyou Xing, Nicholas R. O′Connor, Brian M. Stoltz*

Palladium(II)-Catalyzed Allylic C–H Oxidation of Hindered Substrates Featuring Tunable Selectivity Over Extent of Oxidation
[Communication]

Published online on August 1, 2015.
DOI: 10.1002/anie.201504007

1,4-Rhodium(III) Migration

David J. Burns, Daniel Best, Martin D. Wieczysty, Hon Wai Lam*

All-Carbon [3+3] Oxidative Annulations of 1,3-Enynes by Rhodium(III)-Catalyzed C–H Functionalization and 1,4-Migration
[Communication]

Published online on July 29, 2015.
DOI: 10.1002/anie.201503978

Synthetic Methods

Kevin M. Arendt, Abigail G. Doyle*

Dialkyl Ether Formation by Nickel-Catalyzed Cross-Coupling of Acetals and Aryl Iodides
[Communication]

Published online on July 28, 2015.
DOI: 10.1002/anie.201503936

Electrocatalysis

Emily J. Thompson, Louise A. Berben*

Electrocatalytic Hydrogen Production by an Aluminum(III) Complex: Ligand-Based Proton and Electron Transfer
[Communication]

Coming soon.

Solar Cells

Yao Liu, Zachariah A. Page, Thomas P. Russell*, Todd Emrick*

Finely Tuned Polymer Interlayers Enhance Solar Cell Efficiency
[Communication]
(VIP) title=

Published online on August 1, 2015.
DOI: 10.1002/anie.201503933

Reaction Yields

Fateme S. Emami, Amir Vahid, Elizabeth K. Wylie, Sara Szymkuć, Piotr Dittwald, Karol Molga, Bartosz A. Grzybowski*

A Priori Estimation of Organic Reaction Yields
[Communication]

Published online on July 28, 2015.
DOI: 10.1002/anie.201503890

Lewis Acid Catalysts

Hiroyuki Miyamura, Arisa Sonoyama, Davit Hayrapetyan, Shū Kobayashi*

Self-Assembled Nanocomposite Organic Polymers with Aluminum and Scandium as Heterogeneous Water-Compatible Lewis Acid Catalysts
[Communication]

Published online on July 31, 2015.
DOI: 10.1002/anie.201503874

Organocatalysis

Lili Zong, Shubo Du, Kek Foo Chin, Chao Wang, Choon-Hong Tan*

Enantioselective Synthesis of Quaternary Carbon Stereocenters: Addition of 3-Substituted Oxindoles to Vinyl Sulfone Catalyzed by Pentanidiums
[Communication]

Published online on July 31, 2015.
DOI: 10.1002/anie.201503844

G-Quadruplexes

Surjendu Dey[WWW], Andres Jäschke*

Tuning the Stereoselectivity of a DNA-Catalyzed Michael Addition through Covalent Modification
[Communication]

Published online on July 30, 2015.
DOI: 10.1002/anie.201503838

Bridgehead Olefins

Elizabeth H. Krenske*[WWW], Craig M. Williams*

Do Anti-Bredt Natural Products Exist? Olefin Strain Energy as a Predictor of Isolability
[Communication]

Published online on July 31, 2015.
DOI: 10.1002/anie.201503822

Membranes

Yi Huang, Lei Wang, Zhuonan Song, Shiguang Li*, Miao Yu*

Growth of High-Quality, Thickness-Reduced Zeolite Membranes towards N2/CH4 Separation Using High-Aspect-Ratio Seeds
[Communication]

Coming soon.

Ion–DNA Interactions

Guillem Portella, Montserrat Terrazas, Núria Villegas, Carlos González, Modesto Orozco*

Can A Denaturant Stabilize DNA? Pyridine Reverses DNA Denaturation in Acidic pH
[Communication]

Published online on July 30, 2015.
DOI: 10.1002/anie.201503770

Bonding Analysis

Qingnan Zhang, Wan-Lu Li, Cong-Qiao Xu, Mohua Chen, Mingfei Zhou*, Jun Li*, Diego M. Andrada, Gernot Frenking*

Formation and Characterization of the Boron Dicarbonyl Complex [B(CO)2]
[Communication]

Coming soon.

Structure Elucidation

Felix Fahrnbauer, Tobias Rosenthal, Tilo Schmutzler, Gerald Wagner, Gavin B. M. Vaughan, Jonathan P. Wright, Oliver Oeckler*

Discovery and Structure Determination of an Unusual Sulfide Telluride through an Effective Combination of TEM and Synchrotron Microdiffraction
[Communication]

Published online on July 27, 2015.
DOI: 10.1002/anie.201503657

Molecular Evolution

Fabian Tolle, Gerhard M. Brändle, Daniel Matzner, Günter Mayer*

A Versatile Approach Towards Nucleobase-Modified Aptamers
[Communication]

Published online on July 30, 2015.
DOI: 10.1002/anie.201503652

Electrocatalysis

Kazuyuki Iwase, Tatsuro Yoshioka, Shuji Nakanishi, Kazuhito Hashimoto*, Kazuhide Kamiya*

Copper-Modified Covalent Triazine Frameworks as Non-Noble-Metal Electrocatalysts for Oxygen Reduction
[Communication]

Published online on July 30, 2015.
DOI: 10.1002/anie.201503637

Cyclizations

Congjun Yu, Bin Chen, Tian Zhou, Qinshan Tian, Guozhu Zhang*

Gold(I)-Catalyzed Tandem Transformation with Diynes: Rapid Access to Linear Cyclopentenone-Fused Polycyclic Molecules
[Communication]

Published online on July 29, 2015.
DOI: 10.1002/anie.201503599

Fused-Ring Systems

Amit K. Dutta, Anthony Linden, Laura Zoppi, Kim K. Baldridge*, Jay S. Siegel*

Extended Corannulenes: Aromatic Bowl/Sheet Hybridization
[Communication]

Published online on July 27, 2015.
DOI: 10.1002/anie.201503553

Aluminum Hydroxides

Dana Reusser, William H. Casey, Alexandra Navrotsky*

Energetic Insight into the Formation of Solids from Aluminum Polyoxocations
[Communication]

Published online on July 31, 2015.
DOI: 10.1002/anie.201503544

Nucleophilic Substitution

Angie Garcia, Jillian R. Sanzone, Keith A. Woerpel*

Participation of Alkoxy Groups in Reactions of Acetals: Violation of the Reactivity/Selectivity Principle in a Curtin–Hammett Kinetic Scenario
[Communication]

Coming soon.

Magnetic Anisotropy

Octavia A. Blackburn, Nicholas F. Chilton, Katharina Keller, Claudia E. Tait, William K. Myers, Eric J. L. McInnes, Alan M. Kenwright, Paul D. Beer, Christiane R. Timmel, Stephen Faulkner*

Spectroscopic and Crystal Field Consequences of Fluoride Binding by [Yb·DTMA]3+ in Aqueous Solution
[Communication]

Published online on July 30, 2015.
DOI: 10.1002/anie.201503421

Supramolecular Systems

Euan R. Kay*[WWW], David A. Leigh*[WWW]

Rise of the Molecular Machines
[Essay]

Published online on July 28, 2015.
DOI: 10.1002/anie.201503375

Sustainable Chemistry

Tuo Wang, Jinlong Gong*

Single-Crystal Semiconductors with Narrow Band Gaps for Solar Water Splitting
[Minireview]

Published online on July 30, 2015.
DOI: 10.1002/anie.201503346

Structure Elucidation

Pedro N. Leão, Hitomi Nakamura, Margarida Costa, Alban R. Pereira, Rosário Martins, Vitor Vasconcelos*, William H. Gerwick*, Emily P. Balskus*

Biosynthesis-Assisted Structural Elucidation of the Bartolosides, Chlorinated Aromatic Glycolipids from Cyanobacteria
[Communication]

Published online on July 31, 2015.
DOI: 10.1002/anie.201503186

Organocatalytic Glycosylation

Somnath Das[WWW], Daniel Pekel, Jörg-M. Neudörfl, Albrecht Berkessel*

Organocatalytic Glycosylation by Using Electron-Deficient Pyridinium Salts
[Communication]

Published online on July 29, 2015.
DOI: 10.1002/anie.201503156

Reaction Mechanisms

Shachar Klaiman*, Lorenz S. Cederbaum

Barrierless Single-Electron-Induced cistrans Isomerization
[Communication]

Published online on July 27, 2015.
DOI: 10.1002/anie.201502963

Biosynthesis

Sheng Huang, Jioji Tabudravu, Somayah S. Elsayed, Jeanne Travert, Doe Peace, Ming Him Tong, Kwaku Kyeremeh, Sharon M. Kelly, Laurent Trembleau, Rainer Ebel, Marcel Jaspars, Yi Yu*, Hai Deng*

Discovery of a Single Monooxygenase that Catalyzes Carbamate Formation and Ring Contraction in the Biosynthesis of the Legonmycins
[Communication]

Coming soon.

Phosphorus Radicals

Kai Schwedtmann, Stephen Schulz, Felix Hennersdorf, Thomas Strassner, Evgenia Dmitrieva, Jan J. Weigand*

Synthesis and EPR/UV/Vis-NIR Spectroelectrochemical Investigation of a Persistent Phosphanyl Radical Dication
[Communication]

Published online on July 31, 2015.
DOI: 10.1002/anie.201502737

Persistent Luminescence

Mikael Palner[WWW], Kanyi Pu, Shirley Shao, Jianghong Rao*

Semiconducting Polymer Nanoparticles with Persistent Near-infrared Luminescence for In Vivo Optical Imaging
[Communication]

Published online on July 29, 2015.
DOI: 10.1002/anie.201502736

NMR Techniques

Josep Saurí, Wolfgang Bermel, Alexei V. Buevich, Edward C. Sherer, Leo A. Joyce, Maged H. M. Sharaf, Paul L. Schiff, Jr., Teodor Parella, R. Thomas Williamson*, Gary E. Martin*

Homodecoupled 1,1- and 1,n-ADEQUATE: Pivotal NMR Experiments for the Structure Revision of Cryptospirolepine
[Communication]

Published online on July 27, 2015.
DOI: 10.1002/anie.201502540

CO2 Reduction

Ana Sofia Varela, Nastaran Ranjbar Sahraie, Julian Steinberg, Wen Ju, Hyung-Suk Oh, Peter Strasser*

Metal-Doped Nitrogenated Carbon as Efficient Catalyst for Direct CO2 Electroreduction to CO and Hydrocarbons
[Communication]

Published online on July 31, 2015.
DOI: 10.1002/anie.201502099

Photobiology

Ana P. Gamiz-Hernandez, Iva Neycheva Angelova, Robert Send, Dr. Dage Sundholm, Ville R. I. Kaila*

Protein-Induced Color Shift of Carotenoids in β-Crustacyanin
[Communication]

Published online on July 28, 2015.
DOI: 10.1002/anie.201501609

Supported Graphene

Alejandro Criado*, Michele Melchionna, Silvia Marchesan, Maurizio Prato*

The Covalent Functionalization of Graphene on Substrates
[Review]

Coming soon.

Flexible Electronics

Jizhong Song, Haibo Zeng*

Transparent Electrodes Printed with Nanocrystal Inks for Flexible Smart Devices
[Minireview]

Published online on July 29, 2015.
DOI: 10.1002/anie.201501233

Self-Healing Materials

Charles E. Diesendruck, Nancy R. Sottos, Jeffrey S. Moore, Scott R. White*

Biomimetic Self-Healing
[Review]

Published online on July 27, 2015.
DOI: 10.1002/anie.201500484

Volatolomics

Yoav Y. Broza, Pawel Mochalski, Vera Ruzsanyi, Anton Amann, Hossam Haick*

Hybrid Volatolomics and Disease Detection
[Review]

Published online on July 31, 2015.
DOI: 10.1002/anie.201500153

Zintl Cluster Compounds

Christian B. Benda, Markus Waibel, Thomas F. Fässler*

On the Formation of Intermetalloid Clusters: Titanocene(III)diammin as a Versatile Reactant Toward Nonastannide Zintl Clusters
[Communication]

Coming soon.

Binary Superlattices

Sung-Hwan Lim[WWW], Hyung-Sik Jang, Jae-Min Ha, Tae-Hwan Kim, Pawel Kwasniewski, Theyencheri Narayanan, Kyeong Sik Jin, Sung-Min Choi*

Highly Ordered and Highly Aligned Two-Dimensional Binary Superlattice of a SWNT/Cylindrical-Micellar System
[Communication]

Coming soon.

Biofuel cells

Yang Hee Kim, Scott Banta*[WWW]

Oxidation of Methanol in an Enzymatic Biofuel Cell Using a Hydrogel Self-Assembled from Three Modified Dehydrogenases
[Communication]
(VIP - Read Abstract)

Coming soon.

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