Angewandte Chemie International Edition

Preview

Here's a selection of upcoming papers. Also see the EarlyView page for the latest papers published online.

Borylene Complexes

Holger Braunschweig*[WWW], Melanie Forster, Thomas Kupfer, Fabian Seeler

Borylene Transfer under Thermal Conditions for the Synthesis of Rhodium and Iridium Borylene Complexes
[Communication]

Coming soon.

Bioenergetics

Ulrich Brandt*

Inside View of a Giant Proton Pump
[Highlight]

Published online on May 23, 2013.
DOI: 10.1002/anie.201303403

Asymmetric Catalysis

Liang Yin, Hisashi Takada, Naoya Kumagai*[WWW], Masakatsu Shibasaki*

Direct Catalytic Asymmetric Vinylogous Mannich-Type Reaction of γ-Butenolides with Ketimines
[Communication]

Coming soon.

Fuel Cells

Juan Tian, Adina Morozan, Moulay Tahar Sougrati, Michel Lefèvre, Régis Chenitz, Jean-Pol Dodelet*, Deborah Jones, Frédéric Jaouen*

Optimized Synthesis of Fe/N/C Cathode Catalysts for PEM Fuel Cells: A Matter of Iron–Ligand Coordination Strength
[Communication]

Coming soon.

Expanded Porphyrins

Sabapathi Gokulnath, Keiichi Nishimura, Motoki Toganoh, Shigeki Mori, Hiroyuki Furuta*

Palladium-Induced Pyrrolic Rearrangement of a Singly to a Doubly N-Confused [26]Hexaphyrin
[Communication]

Published online on May 23, 2013.
DOI: 10.1002/anie.201302955

Hydrogenase Mimics

Trevor R. Simmons, Vincent Artero*

Catalytic Hydrogen Oxidation: Dawn of a New Iron Age
[Highlight]

Published online on May 21, 2013.
DOI: 10.1002/anie.201302908

Stable Radicals

David Martin, Curtis E. Moore, Arnold L. Rheingold, Prof. Guy Bertrand*[WWW]

An Air-Stable Oxyallyl Radical Cation
[Communication]

Coming soon.

Boron Ligands

Philipp Bissinger, Holger Braunschweig*[WWW], Alexander Damme, Thomas Kupfer, Krzysztof Radacki

An Electron-Precise, Tetrahedral μ₃ Boride Complex
[Communication]

Coming soon.

Metalloporphyrinoids

Zhaoli Xue, Daiki Kuzuhara, Shinya Ikeda, Yuka Sakakibara, Kei Ohkubo, Naoki Aratani, Tetsuo Okujima, Hidemitsu Uno, Shunichi Fukuzumi, Hiroko Yamada*

η⁵-Cyclopentadienyliron(II)–[14]Triphyrin(2.1.1) Sandwich Compounds: Synthesis, Characterization, and Stable Redox Interconversion
[Communication]

Coming soon.

Main Group Chemistry

S. M. Ibrahim Al-Rafia, Mohammad R. Momeni, Robert McDonald, Michael J. Ferguson, Alex Brown, Eric Rivard*[WWW]

Controlled Growth of Dichlorogermanium Oligomers from Lewis Basic Hosts
[Communication]

Coming soon.

DNA Nanocapsules

Anusuya Banerjee, Dhiraj Bhatia, Anand Saminathan, Saikat Chakraborty, Shaunak Kar, Yamuna Krishnan*

Controlled Release of Encapsulated Cargo from a DNA Icosahedron using a Chemical Trigger
[Communication]

Coming soon.

Asymmetric Catalysis

James Y. Hamilton, David Sarlah, Erick M. Carreira*

Iridium-Catalyzed Enantioselective Allylic Alkynylation
[Communication]

Coming soon.

Polymersomes

Krishna Dan, Suhrit Ghosh*

One-Pot Synthesis of an Acid-Labile Amphiphilic Triblock Copolymer and its pH-Responsive Vesicular Assembly
[Communication]

Coming soon.

Homogeneous Catalysis

Sergio Gonell, Macarena Poyatos, Eduardo Peris*

Triphenylene-Based Tris(N-Heterocyclic Carbene) Ligand: Unexpected Catalytic Benefits
[Communication]

Coming soon.

Trifluoromethylation

Xiaowu Liu, Fei Xiong, Xuanping Huang, Liang Xu, Pengfei Li*, Xiaoxing Wu*

Copper-Catalyzed Trifluoromethylation-Initiated Radical 1,2-Aryl Migration in α,α-Diaryl Allylic Alcohols
[Communication]

Coming soon.

Host–Guest Systems

Shinya Yamamoto, Hiroki Iida, Eiji Yashima*[WWW]

Guest-Induced Unidirectional Dual Rotary and Twisting Motions of a Spiroborate-Based Double-Stranded Helicate Containing a Bisporphyrin Unit
[Communication]

Coming soon.

Silicon Chemistry

Yun Xiong, Shenglai Yao, Shigeyoshi Inoue, Jan Dirk Epping, Matthias Driess*[WWW]

A Cyclic Silylone ("Siladicarbene") with an Electron-Rich Silicon(0) Atom
[Communication]

Coming soon.

Supramolecular Chemistry

Virginia Valderrey, Eduardo C. Escudero-Adán, Pablo Ballester*[WWW]

Highly Cooperative Binding of Ion-Pair Dimers and Ion Quartets by a Bis(calix[4]pyrrole) Macrotricyclic Receptor
[Communication]

Coming soon.

Supramolecular Medicine

Kenji Watanabe, Hiroaki Kitagishi, Koji Kano*

Supramolecular Iron Porphyrin/Cyclodextrin Dimer Complex that Mimics the Functions of Hemoglobin and Methemoglobin
[Communication]

Coming soon.

Fluorescent Probes

Nam-Young Kang, Sung-Chan Lee, Sung-Jin Park, Hyung-Ho Ha, Seong-Wook Yun, Elena Kostromina, Natalia Gustavsson, Yusuf Ali, Yogeswari Chandran, Hang-Suk Chun, MyungAe Bae, Jin Hee Ahn, Weiping Han, George K. Radda, Young-Tae Chang*[WWW]

Visualization and Isolation of Langerhans Islets by a Fluorescent Probe PiY
[Communication]

Coming soon.

Photophysics

Anthony Harriman*[WWW], Mohammed A. H. Alamiry, Jerry P. Hagon, Delphine Hablot, Raymond Ziessel*[WWW]

Through-Space Electronic Energy Transfer Across Proximal Molecular Dyads
[Communication]

Coming soon.

Cell Adhesion

Wen Li, Jiasi Wang, Jinsong Ren, Xiaogang Qu*

Near-Infrared- and pH-Responsive System for Reversible Cell Adhesion using Graphene/Gold Nanorods Functionalized with i-Motif DNA
[Communication]

Published online on May 21, 2013.
DOI: 10.1002/anie.201302048

Neuritogenic Small Molecules

Pierre-Yves Dakas, Juan A. Parga, Susanne Höing, Hans R. Schöler, Jared Sterneckert, Kamal Kumar*, Herbert Waldmann*

Discovery of Neuritogenic Compound Classes Inspired by Natural Products
[Communication]

Coming soon.

Continuous Translation Reaction

Naoko Abe, Michio Hiroshima, Hideto Maruyama, Yuko Nakashima, Yukiko Nakano, Akira Matsuda, Yasushi Sako, Yoshihiro Ito*, Hiroshi Abe*

Rolling Circle Amplification in a Prokaryotic Translation System Using Small Circular RNA
[Communication]

Coming soon.

Asymmetric Catalysis

Junya Kawai, Prasanna Kumara Chikkade, Yohei Shimizu*[WWW], Motomu Kanai*

In situ Catalytic Generation of Allylcopper Species for Asymmetric Allylation: Toward 1H-Isochromene Skeletons
[Communication]

Coming soon.

Homogeneous Catalysis

Stefan Michlik, Rhett Kempe*

Regioselectively Functionalized Pyridines from Sustainable Resources
[Communication]

Coming soon.

Photochemistry

Justin E. Poelma, Brett P. Fors, Gregory F. Meyers, John W. Kramer, Craig J. Hawker*

Fabrication of Complex Three-Dimensional Polymer Brush Nanostructures through Light-Mediated Living Radical Polymerization
[Communication]

Coming soon.

Photovoltaics

Zhibin Yang, Hao Sun, Tao Chen, Longbin Qiu, Yongfeng Luo, Huisheng Peng*

Photovoltaic Wire Derived from Graphene Composite Fiber Achieving an 8.45 % Energy Conversion Efficiency
[Communication]

Coming soon.

Photoactivatable Lipids

André Nadler, Gregor Reither, Suihan Feng, Frank Stein, Sabine Reither, Rainer Müller, Carsten Schultz*

The Fatty Acid Composition of Diacylglycerols Determines Local Signaling Patterns
[Communication]

Coming soon.

Frustrated Lewis Pairs

Klaus Groll, Sophia M. Manolikakes, Xavier Mollat du Jourdin, Milica Jaric, Aleksei Bredihhin, Konstantin Karaghiosoff, Thomas Carell, Paul Knochel*

Regioselective Metalations of Pyrimidines and Pyrazines by Using Frustrated Lewis Pairs of BF₃·OEt₂ and Hindered Magnesium– and Zinc–Amide Bases
[Communication]

Published online on May 23, 2013.
DOI: 10.1002/anie.201301694

Autonomous Nanopropulsion

Zhiguang Wu, Yingjie Wu, Wenping He, Xiankun Lin, Jianmin Sun, Qiang He*

Self-Propelled Polymer-Based Multilayer Nanorockets for Transportation and Drug Release
[Communication]

Published online on May 23, 2013.
DOI: 10.1002/anie.201301643

Dioxygen Activation

Qingquan Lu, Jian Zhang, Fuliang Wei, Yue Qi, Huamin Wang, Zhiliang Liu, Aiwen Lei*[WWW]

Aerobic Oxysulfonylation of Alkenes Leading to Secondary and Tertiary β-Hydroxysulfones
[Communication]

Published online on May 23, 2013.
DOI: 10.1002/anie.201301634

Asymmetric Catalysis

Robert Kastl, Helma Wennemers*[WWW]

Peptide-Catalyzed Stereoselective Conjugate Addition Reactions Generating All-Carbon Quaternary Stereogenic Centers
[Communication]

Coming soon.

Natural Products

Philippe A. Peixoto, Alexandre Jean, Jacques Maddaluno, Michaël De Paolis*[WWW]

Formal Enantioselective Synthesis of Aplykurodinone-1
[Communication]

Published online on May 23, 2013.
DOI: 10.1002/anie.201301465

Catalyst Design

Stefan Zander, Edward L. Kunkes, Manfred E. Schuster, Julia Schumann, Gisela Weinberg, Detre Teschner, Nikolas Jacobsen, Robert Schlögl, Malte Behrens*

The Role of the Oxide Component in the Development of Copper Composite Catalysts for Methanol Synthesis
[Communication]

Coming soon.

Polyrotaxanes

Shuling Yu, Yajun Zhang, Xin Wang, Xu Zhen, Zhaoheng Zhang, Wei Wu*, Xiqun Jiang*

Synthesis of Paclitaxel-Conjugated β-Cyclodextrin Polyrotaxane and Its Antitumor Activity
[Communication]

Coming soon.

Detection of Glycans

Liang Lin, Xiangdong Tian, Senlian Hong, Peng Dai, Qiancheng You, Ruyi Wang, Lianshun Feng, Can Xie, Zhong-Qun Tian*, Xing Chen*

A Bioorthogonal Raman Reporter Strategy for SERS Detection of Glycans on Live Cells
[Communication]

Published online on May 23, 2013.
DOI: 10.1002/anie.201301387

Gold Catalysts

Yunyun Zhou, Neil J. Lawrence, Lu Wang, Lingmei Kong, Tai-Sing Wu, Jing Liu, Yi Gao, Joseph R. Brewer, Vivianna K. Lawrence, Renat F. Sabirianov, Yun-Liang Soo, Xiao Cheng Zeng, Peter A. Dowben, Wai Ning Mei, Chin Li Cheung*

Resonant Photoemission Observations and DFT Study of s–d Hybridization in Catalytically Active Gold Clusters on Ceria Nanorods
[Communication]

Coming soon.

Ionic Silicon(II) Compounds

Alexander C. Filippou*, Yury N. Lebedev, Oleg Chernov, Martin Straßmann, Gregor Schnakenburg

Silicon(II) Coordination Chemistry: N-Heterocyclic Carbene Complexes of Si²⁺ and SiI⁺
[Communication]

Coming soon.

Pigments

Yukikazu Takeoka*, Shinya Yoshioka*, Atsushi Takano, Shigeo Arai, Nueangnoraj Khanin, Hirotomo Nishihara, Midori Teshima, Yumiko Ohtsuka, Takahiro Seki

Production of Colored Pigments with Amorphous Arrays of Black and White Colloidal Particles
[Communication]

Coming soon.

Lithium–Sulfur Batteries

Yongzhu Fu, Yu-Sheng Su, Arumugam Manthiram*

Highly Reversible Lithium/Dissolved Polysulfide Batteries with Carbon Nanotube Electrodes
[Communication]

Coming soon.

Metallocavitands

Maxime Guitet, Pinglu Zhang, Filipa Marcelo, Coralie Tugny, Jesús Jiménez-Barbero, Olivier Buriez, Christian Amatore, Virginie Mouriès-Mansuy, Jean-Philippe Goddard, Louis Fensterbank, Yongmin Zhang, Sylvain Roland, Mickaël Ménand, Matthieu Sollogoub*[WWW]

NHC-Capped Cyclodextrins (ICyDs): Insulated Metal Complexes, Commutable Multicoordination Sphere, and Cavity-Dependent Catalysis
[Communication]

Coming soon.

Porphyrin Analogues

Zhongrui Chen, Michel Giorgi, Denis Jacquemin*, Mourad Elhabiri, Olivier Siri*

Azacalixphyrin: The Hidden Porphyrin Cousin Brought to Light
[Communication]

Coming soon.

Photomechanical Motion

Jian-Ke Sun, Wei Li, Cheng Chen, Cai-Xia Ren, Dan-Mei Pan, Jie Zhang*

Photoinduced Bending of a Large Single Crystal of a 1,2-Bis(4-pyridyl)ethylene-Based Pyridinium Salt Powered by a [2+2] Cycloaddition
[Communication]

Published online on May 21, 2013.
DOI: 10.1002/anie.201301207

Nanostructures

Shaohua Liu, Yingying Duan, Xuejiao Feng, Jun Yang, Shunai Che*[WWW]

Synthesis of Enantiopure Carbonaceous Nanotubes with Optical Activity
[Communication]

Coming soon.

Pyrrolysine Biosynthesis

Felix Quitterer, Philipp Beck, Adelbert Bacher, Michael Groll*

Structure and Reaction Mechanism of Pyrrolysine Synthase (PylD)
[Communication]

Coming soon.

Fluorogenic Probes

Jonathan C. T. Carlson, Labros G. Meimetis, Scott A. Hilderbrand, Ralph Weissleder*

BODIPY–Tetrazine Derivatives as Superbright Bioorthogonal Turn-on Probes
[Communication]

Coming soon.

Phosphorylation

Samanta Capolicchio, Divyeshsinh T. Thakor, Anthony Linden, Henning J. Jessen*

Synthesis of Unsymmetric Diphospho-Inositol Polyphosphates
[Communication]

Coming soon.

Electron Acceptors

Igor V. Kuvychko*, Cristina Dubceac, Shihu H. M. Deng, Xue-Bin Wang*, Alexander A. Granovsky, Alexey A. Popov*, Marina A. Petrukhina*, Steven H. Strauss*, Olga V. Boltalina*

C₂₀H₄(C₄F₈)₃: A Fluorine-Containing Annulated Corannulene that Is a Better Electron Acceptor Than C₆₀
[Communication]

Coming soon.

Molecular Imprinting

Guoqing Pan*, Qianping Guo, Yue Ma, Huilin Yang, Bin Li*

Thermo-Responsive Hydrogel Layers Imprinted with RGDS Peptide: A System for Harvesting Cell Sheets
[Communication]

Coming soon.

Liquid Crystals

Takahiro Ueda, Shiori Masuko, Fumito Araoka, Ken Ishikawa, Hideo Takezoe*

A General Method for the Enantioselective Formation of Helical Nanofilaments
[Communication]

Coming soon.

Asymmetric Synthesis

Andrey E. Sheshenev, Ekaterina V. Boltukhina, Andrew J. P. White, King Kuok (Mimi) Hii*[WWW]

Methylene-Bridged Bis(imidazoline)-Derived 2-Oxopyrimidinium Salts as Catalysts for Asymmetric Michael Reactions
[Communication]

Coming soon.

Conducting Materials

Yusuke Kawanaka, Akihiro Shimizu, Tetsuro Shinada, Rika Tanaka, Yoshio Teki*

Using Stable Radicals To Protect Pentacene Derivatives from Photodegradation
[Communication]

Published online on May 21, 2013.
DOI: 10.1002/anie.201300595

POMcycles

Hong-Ying Zang, Haralampos N. Miras, De-Liang Long, Benjamin Rausch, Leroy Cronin*[WWW]

Template-Directed Assembly of Polyoxothiometalate Scaffolds into Nanomolecular Architectures
[Communication]

Coming soon.

Sensor Particles

Wei Wan, Mustafa Biyikal, Ricarda Wagner, Börje Sellergren*, Knut Rurack*

Fluorescent Sensory Microparticles that "Light-up" Consisting of a Silica Core and a Molecularly Imprinted Polymer (MIP) Shell
[Communication]

Coming soon.

Synthetic Methods

Jiajing Tan, Matsujiro Akakura, Hisashi Yamamoto*

The Supersilyl Group as a Carboxylic Acid Protecting Group: Application to Highly Stereoselective Aldol and Mannich Reactions
[Communication]

Coming soon.

Macrocyclic Hosts

Xiao-Jie Cheng, Li-Li Liang, Kai Chen, Ning-Ning Ji, Xin Xiao, Jian-Xin Zhang, Yun-Qian Zhang, Sai-Feng Xue, Qian-Jiang Zhu, Xin-Long Ni*, Zhu Tao*

Twisted Cucurbit[14]uril
[Communication]

Coming soon.

C–C Bond Formation

Tetsu Tsubogo, Takanori Ishiwata, Shū Kobayashi*

Asymmetric Carbon–Carbon Bond Formation under Continuous-Flow Conditions with Chiral Heterogeneous Catalysts
[Review]

Coming soon.

Oxidative Radical Coupling

Zhiliang Huang, Liqun Jin, Ye Feng, Pan Peng, Hong Yi, Aiwen Lei*

Iron-Catalyzed Oxidative Radical Cross-Coupling/Cyclization between Phenols and Olefins
[Communication]

Coming soon.

Targeted Delivery

Min Suk Shim, Younan Xia*

A Reactive Oxygen Species (ROS)-Responsive Polymer for Safe, Efficient, and Targeted Gene Delivery in Cancer Cells
[Communication]

Coming soon.

Synthetic Methods

Jing Zhang, Angel Ugrinov, Pinjing Zhao*[WWW]

Ruthenium(II)/N-Heterocyclic Carbene Catalyzed [3+2] Carbocyclization with Aromatic N–H Ketimines and Internal Alkynes
[Communication]

Published online on May 21, 2013.
DOI: 10.1002/anie.201209031

Non-natural Translation

Katarzyna Gorska, Nicolas Winssinger*

Reactions Templated by Nucleic Acids: More Ways to Translate Oligonucleotide-Based Instructions into Emerging Function
[Review]

Coming soon.

Biosynthesis

Christopher T. Walsh, Robert V. O´Brien, Chaitan Khosla*

Nonproteinogenic Amino Acid Building Blocks for Nonribosomal Peptide and Hybrid Polyketide Scaffolds
[Review]

Coming soon.

Biofuel cells

Yang Hee Kim, Scott Banta*[WWW]

Oxidation of Methanol in an Enzymatic Biofuel Cell Using a Hydrogel Self-Assembled from Three Modified Dehydrogenases
[Communication]

Coming soon.

Graphene

Andre K. Geim*

Random Walk to Graphene (Nobel Lecture)
[Review]

Coming soon.