Angewandte Chemie International Edition

Cover image for Vol. 53 Issue 52

Editor: Peter Gölitz, Deputy Editors: Neville Compton, Haymo Ross

Online ISSN: 1521-3773

Associated Title(s): Angewandte Chemie, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemistryOpen, ChemPlusChem, Zeitschrift für Chemie

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Here's a selection of upcoming papers. Also see the EarlyView page for the latest papers published online. Click on the VIP logos of upcoming articles to read their abstracts.

Borylene Complexes

Holger Braunschweig*[WWW], Melanie Forster, Thomas Kupfer, Fabian Seeler

Borylene Transfer under Thermal Conditions for the Synthesis of Rhodium and Iridium Borylene Complexes
[Communication]

Coming soon.

Flexible Electrodes

Tian Yi Ma, Jingrun Ran, Sheng Dai, Mietek Jaroniec, Shi Zhang Qiao*

Phosphorus-Doped Graphitic Carbon Nitrides Grown in Situ on Carbon-Fiber Paper: Flexible and Reversible Oxygen Electrodes
[Communication]

Published online on December 17, 2014.
DOI: 10.1002/anie.201411125

Layered Compounds

Xiaohui Liu, Janine George, Stefan Maintz, Richard Dronskowski*

β-CuN3: The Overlooked Ground-State Polymorph of Copper Azide with Heterographene-Like Layers
[Communication]

Published online on December 17, 2014.
DOI: 10.1002/anie.201410987

2D Hetero-nanostructures

Chaoliang Tan[WWW], Zhiyuan Zeng, Xiao Huang, Xianhong Rui, Xue-Jun Wu, Bing Li, Zhimin Luo, Junze Chen, Bo Chen, Qingyu Yan, Hua Zhang*

Liquid-Phase Epitaxial Growth of Two-Dimensional Semiconductor Hetero-nanostructures
[Communication]

Coming soon.

Gold Catalysis

Jacob C. Timmerman, Bradley D. Robertson, Ross A. Widenhoefer*

Gold-Catalyzed Intermolecular Anti-Markovnikov Hydroamination of Alkylidenecyclopropanes
[Communication]

Coming soon.

Polymerization

Mineto Uchiyama, Kotaro Satoh*, Masami Kamigaito*

Cationic RAFT Polymerization Using ppm Concentrations of Organic Acid
[Communication]

Published online on December 15, 2014.
DOI: 10.1002/anie.201410858

Renewable Carbon Sources

Vanessa M. Marx, Alexandra H. Sullivan, Mohand Melaimi, Scott C. Virgil*, Benjamin K. Keitz, David S. Weinberger, Guy Bertrand*, Robert H. Grubbs*

Cyclic Alkyl Amino Carbene (CAAC) Ruthenium Complexes as Remarkably Active Catalysts for Ethenolysis
[Communication]

Published online on December 17, 2014.
DOI: 10.1002/anie.201410797

Machine-Assisted Chemistry

Steven V. Ley*, Daniel E. Fitzpatrick, Richard. J. Ingham, Rebecca M. Myers

Organic Synthesis: March of the Machines
[Review]

Coming soon.

Polymer Stereocomplexes

Ye Liu, Wei-Min Ren, Meng Wang, Chuang Liu, Xiao-Bing Lu*

Crystalline Stereocomplexed Polycarbonates: Hydrogen-Bond-Driven Interlocked Orderly Assembly of the Opposite Enantiomers
[Communication]
(VIP - Read Abstract)

Coming soon.

Oxidation States

Pekka Pyykkö*, Wen-Hua Xu

The Formal Oxidation States of Iridium Now Run from −III to +IX
[Highlight]

Published online on December 16, 2014.
DOI: 10.1002/anie.201410615

Aromaticity

Miłosz Pawlicki*[WWW], Mateusz Garbicz, Ludmiła Szterenberg, Lechosław Latos-Grażyński*

Oxatriphyrins(2.1.1) Incorporating an ortho-Phenylene Motif
[Communication]

Coming soon.

Color Switching

Wenshou Wang, Yifan Ye, Ji Feng, Miaofang Chi, Jinghua Guo, Yadong Yin*

Enhanced Photoreversible Color Switching of Redox Dyes Catalyzed by Barium-Doped TiO2 Nanocrystals
[Communication]

Coming soon.

Surface Chemistry

Yuanyuan Li, Xiao He*, Jun-Jie Yin, Yuhui Ma, Peng Zhang, Jingyuan Li, Yayun Ding, Jing Zhang, Yuliang Zhao, Zhifang Chai, Zhiyong Zhang*

Acquired Superoxide-Scavenging Ability of Ceria Nanoparticles
[Communication]

Published online on December 16, 2014.
DOI: 10.1002/anie.201410398

EPR-Based Trilateration

Dinar Abdullin[WWW], Nicole Florin, Gregor Hagelueken, Olav Schiemann*

EPR-Based Approach for the Localization of Paramagnetic Metal Ions in Biomolecules
[Communication]

Published online on December 17, 2014.
DOI: 10.1002/anie.201410396

Hydrodeoxygenation

Nobuhiko Ota, Masazumi Tamura, Yoshinao Nakagawa*, Kazu Okumura, Keiichi Tomishige*

Hydrodeoxygenation of Vicinal OH Groups over Heterogeneous Rhenium Catalyst Promoted by Palladium and Ceria Support
[Communication]

Published online on December 17, 2014.
DOI: 10.1002/anie.201410352

Heterocycles

Dongbing Zhao, Suhelen Vásquez-Céspedes, Frank Glorius*

Rhodium(III)-Catalyzed Cyclative Capture Approach to Diverse 1-Aminoindoline Derivatives at Room Temperature
[Communication]

Published online on December 15, 2014.
DOI: 10.1002/anie.201410342

Heterocycle Synthesis

Wu Li[WWW], Zhengli Duan, Xueye Zhang, Heng Zhang, Mengfan Wang, Ru Jiang, Hongyao Zeng, Chao Liu, Aiwen Lei*

From Anilines to Isatins: Oxidative Palladium-Catalyzed Double Carbonylation of C–H Bonds
[Communication]

Published online on December 17, 2014.
DOI: 10.1002/anie.201410321

Peptidomimetics

Elizabeth A. German[WWW], Jonathan E. Ross, Peter C. Knipe, Michaela F. Don, Sam Thompson*, Andrew D. Hamilton*

β-Strand Mimetic Foldamers Rigidified through Dipolar Repulsion
[Communication]

Coming soon.

Peptide Catalysis

Kengo Akagawa, Nobutaka Sakai, Kazuaki Kudo*

Histidine-Containing Peptide Catalysts Developed by a Facile Library Screening Method
[Communication]

Published online on December 17, 2014.
DOI: 10.1002/anie.201410268

Carbasugars

Matthew J. Moschitto, David N. Vaccarello, Chad A. Lewis*

Regiodivergent Addition of Phenols to Allylic Oxides: Control of 1,2- and 1,4-Additions for Cyclitol Synthesis
[Communication]

Coming soon.

Biosynthesis

Matthew Jenner, José Pedro Afonso, Hannah R. Bailey, Sarah Frank, Annette Kampa, Jörn Piel*, Neil J. Oldham*

Acyl-Chain Elongation Drives Ketosynthase Substrate Selectivity in trans-Acyltransferase Polyketide Synthases
[Communication]

Coming soon.

Synthetic Methods

Min Gao, Jing-jing Meng, Hui Lv*, Xumu Zhang*

Highly Regio- and Enantioselective Synthesis of γ,δ-Unsaturated Amido Esters by Catalytic Hydrogenation of Conjugated Enamides
[Communication]

Published online on December 15, 2014.
DOI: 10.1002/anie.201410213

Channelrhodopsin

Jens Kuhne, Kirstin Eisenhauer, Eglof Ritter, Peter Hegemann*, Klaus Gerwert*, Franz Bartl

Early Formation of the Ion-Conducting Pore in Channelrhodopsin-2
[Communication]

Coming soon.

Proteasome Inhibition

Philipp Beck, Theresa A. Lansdell, Nicole M. Hewlett, Jetze J. Tepe*, Michael Groll*

Indolo-Phakellins as β5-Specific Noncovalent Proteasome Inhibitors
[Communication]

Coming soon.

Nanostructures

Yuezeng Su, Yuxin Liu, Ping Liu*, Dongqing Wu, Xiaodong Zhuang, Fan Zhang, Xinliang Feng*

Compact Coupled Graphene and Porous Polyaryltriazine-Derived Frameworks as High Performance Cathodes for Lithium-Ion Batteries
[Communication]

Published online on December 16, 2014.
DOI: 10.1002/anie.201410154

Hydrogen Splitting

Konstantin Chernichenko, Bianka Kótai, Imre Pápai*, Vladimir Zhivonitko, Martin Nieger, Markku Leskelä, Timo Repo*

Intramolecular Frustrated Lewis Pair with the Smallest Boryl Site: Reversible H2 Addition and Kinetic Analysis
[Communication]

Published online on December 17, 2014.
DOI: 10.1002/anie.201410141

Microreactor Synthesis

Heejin Kim[WWW], Hyune-Jea Lee, Dong-Pyo Kim*

Integrated One-Flow Synthesis of Heterocyclic Thioquinazolinones through Serial Microreactions with Two Organolithium Intermediates
[Communication]

Published online on December 17, 2014.
DOI: 10.1002/anie.201410062

Protein Delivery

Nicole Nischan, Henry D. Herce, Francesco Natale, Nina Bohlke, Nediljko Budisa, M. Cristina Cardoso*, Christian P. R. Hackenberger*

Covalent Attachment of Cyclic TAT Peptides to GFP Results in Protein Delivery into Live Cells with Immediate Bioavailability
[Communication]

Published online on December 17, 2014.
DOI: 10.1002/anie.201410006

Antibiotics

Sascha Baumann, Jennifer Herrmann, Ritesh Raju, Heinrich Steinmetz, Kathrin I. Mohr, Stephan Hüttel, Kirsten Harmrolfs, Marc Stadler, Rolf Müller*

Cystobactamids: Myxobacterial Topoisomerase Inhibitors Exhibiting Potent Antibacterial Activity
[Communication]
(VIP) title=

Published online on December 15, 2014.
DOI: 10.1002/anie.201409964

Molecular Structure

Oscar Martinez, Jr., Kyle N. Crabtree, Carl A. Gottlieb, John F. Stanton, Michael C. McCarthy*

An Accurate Molecular Structure of Phenyl, the Simplest Aryl Radical
[Communication]

Published online on December 17, 2014.
DOI: 10.1002/anie.201409896

Insect Pheromones

Regine Gries, Robert Britton*, Michael Holmes, Huimin Zhai, Jason Draper, Gerhard Gries*

Bed Bug Aggregation Pheromone Finally Identified
[Communication]

Coming soon.

Colloidal Crystals

Antara Pal, Vikash Malik, Le He, Ben H. Erné, Yadong Yin, Willem K. Kegel, Andrei V. Petukhov*

Tuning the Colloidal Crystal Structure of Magnetic Particles by External Field
[Communication]

Published online on December 15, 2014.
DOI: 10.1002/anie.201409878

Gold Catalysis

Janina Bucher[WWW], Tim Stößer, Matthias Rudolph, Frank Rominger, A. Stephen K. Hashmi*

CO-Extrusion in Homogeneous Gold Catalysis: Reactivity of Gold Acyl Species Generated through Water Addition to Gold Vinylidenes
[Communication]
(VIP) title=

Published online on December 15, 2014.
DOI: 10.1002/anie.201409859

Metallic States

Andrés Aguado*, Andrés Vega, Alexandre Lebon, Bernd von Issendorff

Insulating or Metallic: Coexistence of Different Electronic Phases in Zinc Clusters
[Communication]

Coming soon.

Mechanochemistry

Lisa Batzdorf, Franziska Fischer, Manuel Wilke, Klaus-Jürgen Wenzel, Franziska Emmerling*

Direct In Situ Investigation of Milling Reactions Using Combined X-ray Diffraction and Raman Spectroscopy
[Communication]

Coming soon.

Total Synthesis

Ross S. Harvey, Emily G. Mackay, Lukas Roger, Michael N. Paddon-Row*, Michael S. Sherburn*, Andrew L. Lawrence*

Total Synthesis of Ramonanins A–D
[Communication]

Published online on December 15, 2014.
DOI: 10.1002/anie.201409818

Water Reduction

Debashis Basu[WWW], Shivnath Mazumder, Xuetao Shi, Habib Baydoun, Jens Niklas, Oleg Poluektov, H. Bernhard Schlegel*, Cláudio N. Verani*

Ligand Transformations and Efficient Proton/Water Reduction with Cobalt Catalysts Based on Pentadentate Pyridine-Rich Environments
[Communication]

Coming soon.

siRNA Delivery

Korbinian Brunner[WWW], Johannes Harder, Tobias Halbach, Julian Willibald, Fabio Spada, Felix Gnerlich, Konstantin Sparrer, Andreas Beil, Leonhard Möckl, Christoph Bräuchle, Karl-Klaus Conzelmann, Thomas Carell*

Cell-Penetrating and Neurotargeting Dendritic siRNA Nanostructures
[Communication]

Published online on December 17, 2014.
DOI: 10.1002/anie.201409803

Mixed Metal Oxides

Laifa Shen[WWW], Le Yu, Xin-Yao Yu, Xiaogang Zhang, Xiong Wen (David) Lou*

Self-Templated Formation of Uniform NiCo2O4 Hollow Spheres with Complex Interior Structures for Lithium-Ion Batteries and Supercapacitors
[Communication]

Published online on December 17, 2014.
DOI: 10.1002/anie.201409776

Dynamic Combinatorial Chemistry

Chia-Wei Hsu, Ognjen Š. Miljanić*

Adsorption-Driven Self-Sorting of Dynamic Imine Libraries
[Communication]

Coming soon.

Layered Compounds

Marco Esters[WWW], Matti B. Alemayehu, Zachary Jones, N. T. Nguyen, Michael D. Anderson, Corinna Grosse, Saskia F. Fischer, David C. Johnson*

Synthesis of Inorganic Structural Isomers By Diffusion-Constrained Self-Assembly of Designed Precursors: A Novel Type of Isomerism
[Communication]

Published online on December 17, 2014.
DOI: 10.1002/anie.201409714

Biomimetic Copper–O2 Chemistry

Nicole Kindermann[WWW], Eckhard Bill, Sebastian Dechert, Serhiy Demeshko, Edward J. Reijerse, Franc Meyer*

A Ferromagnetically Coupled (S=1) Peroxodicopper(II) Complex
[Communication]

Coming soon.

Natural Product Synthesis

Florian Glaus, Karl-Heinz Altmann*

Total Synthesis of the Tiacumicin B (Lipiarmycin A3/Fidaxomicin) Aglycone
[Communication]

Published online on December 15, 2014.
DOI: 10.1002/anie.201409510

Porous Carbon

Guang-Ping Hao, Giovanni Mondin, Zhikun Zheng, Tim Biemelt, Stefan Klosz, René Schubel, Alexander Eychmüller, Stefan Kaskel*

Unusual Ultra-Hydrophilic, Porous Carbon Cuboids for Atmospheric-Water Capture
[Communication]

Published online on December 17, 2014.
DOI: 10.1002/anie.201409439

2D Materials

Claudia Backes, Nina C. Berner, Xin Chen, Paul Lafargue, Pierre LaPlace, Mark Freeley, Georg S. Duesberg, Jonathan N. Coleman, Aidan R. McDonald*

Functionalization of Liquid-Exfoliated Two-Dimensional 2H-MoS2
[Communication]

Coming soon.

Surface Chemistry

Wei Chang, Chunyan Sun, Xibin Pang, Hua Sheng, Yue Li, Hongwei Ji, Wenjing Song, Chuncheng Chen, Wanhong Ma*, Jincai Zhao*

Inverse Kinetic Solvent Isotope Effect in TiO2 Photocatalytic Dehalogenation of Non-adsorbable Aromatic Halides: A Proton-Induced Pathway
[Communication]

Coming soon.

Organocatalysis

Hong-Yu Wang, Kai Zhang, Chang-Wu Zheng, Zhuo Chai, Dong-Dong Cao, Jia-Xing Zhang, Gang Zhao*

Asymmetric Dual-Reagent Catalysis: Mannich-type Reactions Catalyzed by Ion Pair
[Communication]

Published online on December 16, 2014.
DOI: 10.1002/anie.201409342

Transfer Hydrogenation

Indranil Chatterjee[WWW], Martin Oestreich*

B(C6F5)3-Catalyzed Transfer Hydrogenation of Imines and Related Heteroarenes Using Cyclohexa-1,4-dienes as a Dihydrogen Source
[Communication]

Coming soon.

Dual Catalysis

David C. Fabry, Meria A. Ronge, Jochen Zoller, Magnus Rueping*

C–H Functionalization of Phenols using Combined Ruthenium and Photoredox Catalysis: In Situ Generation of the Oxidant
[Communication]

Coming soon.

Amyloid β Peptides

Thomas Branch, Paul Girvan, Mauricio Barahona, Liming Ying*

Introduction of a Fluorescent Probe to Amyloid-β to Reveal Kinetic Insights into Its Interactions with Copper(II)
[Communication]

Coming soon.

Amyloid Self-Assembly

Yaron Bram, Ayala Lampel, Ronit Shaltiel-Karyo, Anat Ezer, Roni Scherzer-Attali, Daniel Segal, Ehud Gazit*

Monitoring and Targeting the Initial Dimerization Stage of Amyloid Self-Assembly
[Communication]

Coming soon.

Helicenes

Bastian Milde[WWW], Markus Leibeling, Martin Pawliczek, Jörg Grunenberg, Peter G. Jones, Daniel B. Werz*

π-Helicenes Truncated to a Minimum: Access Through a Domino Approach Involving Multiple Carbopalladations and a Stille Coupling
[Communication]

Coming soon.

Nitrous Oxide

Gregor Kiefer, Tina Riedel, Paul J. Dyson, Rosario Scopelliti, Kay Severin*

Synthesis of Triazenes with Nitrous Oxide
[Communication]

Coming soon.

Thermoelectric Polymers

Brendan T. McGrail, Alp Sehirlioglu, Emily Pentzer*

Polymer Composites for Thermoelectric Applications
[Minireview]

Coming soon.

Glycans

Hao Jiang, Brian P. English, Rachel B. Hazan, Peng Wu*, Ben Ovryn*

Tracking Surface Glycans on Live Cancer Cells with Single-Molecule Sensitivity
[Communication]

Published online on December 16, 2014.
DOI: 10.1002/anie.201407976

Zintl Cluster Compounds

Christian B. Benda, Markus Waibel, Thomas F. Fässler*

On the Formation of Intermetalloid Clusters: Titanocene(III)diammin as a Versatile Reactant Toward Nonastannide Zintl Clusters
[Communication]

Coming soon.

Molecular Set Screws

Jan Sanning, Pascal R. Ewen, Linda Stegemann, Judith Schmidt, Constantin G. Daniliuc, Tobias Koch, Nikos L. Doltsinis, Daniel Wegner*, Cristian A. Strassert*

Scanning-Tunneling-Spectroscopy-Directed Design of Tailored Deep-Blue Emitters
[Communication]

Published online on December 17, 2014.
DOI: 10.1002/anie.201407439

Liquid-Crystal Templates

Michael Giese, Lina K. Blusch, Mostofa K. Khan, Mark J. MacLachlan*

Functional Materials from Cellulose-Derived Liquid-Crystal Templates
[Review]

Published online on December 17, 2014.
DOI: 10.1002/anie.201407141

Metal–Organic Frameworks

Suresh B. Kalidindi, Sanjit Nayak, Michael E. Briggs, Susanna Jansat, Alexandros P. Katsoulidis, Gary J. Miller, John E. Warren, Dmytro Antypov, Furio Corà, Ben Slater, Mark R. Prestly, Carlos Martí-Gastaldo, Matthew J. Rosseinsky*

Chemical and Structural Stability of Zirconium-based Metal–Organic Frameworks with Large Three-Dimensional Pores by Linker Engineering
[Communication]

Published online on December 17, 2014.
DOI: 10.1002/anie.201406501

DNA Nanotechnology

Fuan Wang[WWW], Xiaoqing Liu, Itamar Willner*

DNA Switches: From Principles to Applications
[Review]

Published online on December 17, 2014.
DOI: 10.1002/anie.201404652

Binary Superlattices

Sung-Hwan Lim[WWW], Hyung-Sik Jang, Jae-Min Ha, Tae-Hwan Kim, Pawel Kwasniewski, Theyencheri Narayanan, Kyeong Sik Jin, Sung-Min Choi*

Highly Ordered and Highly Aligned Two-Dimensional Binary Superlattice of a SWNT/Cylindrical-Micellar System
[Communication]

Coming soon.

Biphasic Catalysis

Marc Pera-Titus*[WWW], Loïc Leclercq, Jean-Marc Clacens, Floryan De Campo, Véronique Nardello-Rataj*

Pickering Interfacial Catalysis for Biphasic Systems: From Emulsion Design to Green Reactions
[Minireview]

Coming soon.

Biofuel cells

Yang Hee Kim, Scott Banta*[WWW]

Oxidation of Methanol in an Enzymatic Biofuel Cell Using a Hydrogel Self-Assembled from Three Modified Dehydrogenases
[Communication]
(VIP - Read Abstract)

Coming soon.

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