Angewandte Chemie International Edition

Preview

Here's a selection of upcoming papers. Also see the EarlyView page for the latest papers published online. Click on the VIP logos of upcoming articles to read their abstracts.

Borylene Complexes

Holger Braunschweig*[WWW], Melanie Forster, Thomas Kupfer, Fabian Seeler

Borylene Transfer under Thermal Conditions for the Synthesis of Rhodium and Iridium Borylene Complexes
[Communication]

Coming soon.

Enantioselective Catalysis

Jennifer A. Dabrowski, Matthew T. Villaume, Amir H. Hoveyda*

Enantioselective Synthesis of Quaternary Carbon Stereogenic Centers through Copper-Catalyzed Conjugate Additions of Aryl- and Alkylaluminum Reagents to Acyclic Trisubstituted Enones
[Communication]

Coming soon.

C–H Activation

Tanguy Saget, Nicolai Cramer*[WWW]

Enantioselective C–H Arylation Strategy for Functionalized Dibenzazepinones with Quaternary Stereocenters
[Communication]

Coming soon.

Bioorganometallics

Faustine Dubar, Christian Slomianny, Jamal Khalife, Daniel Dive, Hadidjatou Kalamou, Yann Guérardel, Philippe Grellier, Christophe Biot*

The Ferroquine Antimalarial Conundrum: Redox Activation and Reinvasion Inhibition
[Communication]

Published online on June 13, 2013.
DOI: 10.1002/anie.201303690

Asymmetric Catalysis

Peng Zhang, Christian Wolf*[WWW]

Catalytic Enantioselective Difluoroalkylation of Aldehydes
[Communication]

Coming soon.

Activity-Based Protein Probes

Christoph Arkona, Jörg Rademann*

Propargyl Amides as Irreversible Inhibitors of Cysteine Proteases—A Lesson on the Biological Reactivity of Alkynes
[Highlight]

Coming soon.

Enantioselective Catalysis

Jennifer A. Dabrowski, Fredrik Haeffner, Amir H. Hoveyda*

Combining NHC–Cu and Brønsted Base Catalysis: Enantioselective Allylic Substitution/Conjugate Additions with Alkynylaluminum Reagents and Stereospecific Isomerization of the Products to Trisubstituted Allenes
[Communication]

Coming soon.

Synthetic Methods

Yuwen Wang, Weiqiang Chen, Zhenpin Lu, Zhen Hua Li*, Huadong Wang*

Metal-Free HB(C₆F₅)₂-Catalyzed Hydrogenation of Unfunctionalized Olefins and Mechanism Study of Borane-Mediated σ-Bond Metathesis
[Communication]

Coming soon.

Photoredox Catalysis

Xiao Wang*, Gregory D. Cuny*, Timothy Noël*

A Mild, One-Pot Stadler–Ziegler Synthesis of Arylsulfides Facilitated by Photoredox Catalysis in Batch and Continuous-Flow
[Communication]

Coming soon.

Bioinorganic Modeling

Guilherme M. Arantes*, Anirban Bhattacharjee, Martin J. Field

Homolytic Cleavage of Fe–S Bonds in Rubredoxin under Mechanical Stress
[Communication]

Coming soon.

Nucleophilic Boron

David A. Ruiz, Gaël Ung, Mohand Melaimi, Guy Bertrand*

Deprotonation of a Borohydride: Synthesis of a Carbene-Stabilized Boryl Anion
[Communication]

Published online on June 13, 2013.
DOI: 10.1002/anie.201303457

Asymmetric Synthesis

Graeme Barker, Madeha R. Alshawish, Melanie C. Skilbeck, Iain Coldham*

Remarkable Configurational Stability of Magnesiated Nitriles
[Communication]

Coming soon.

Synthesis Design

Kohei Sato, Akira Shigenaga, Keisuke Kitakaze, Ken Sakamoto, Daisuke Tsuji, Kohji Itoh, Akira Otaka*

Chemical Synthesis of Biologically Active Monoglycosylated GM2-Activator Protein Analogue Using N-Sulfanylethylanilide Peptide
[Communication]

Published online on June 13, 2013.
DOI: 10.1002/anie.201303390

Trifluoromethylation

Hiromichi Egami, Shintaro Kawamura, Ayako Miyazaki, Mikiko Sodeoka*

Trifluoromethylation Reactions for the Synthesis of β-Trifluoromethylamines
[Communication]

Published online on June 13, 2013.
DOI: 10.1002/anie.201303350

Radical Reactions

Jing Peng, Chao Chen*, Yong Wang, Zhenbang Lou, Ming Li, Chanjuan Xi, Hui Chen*

Direct Vicinal Disubstitution of Diaryliodonium Salts by Pyridine N-oxides and N-amidates by a 1,3-Radical Rearrangement
[Communication]

Published online on June 12, 2013.
DOI: 10.1002/anie.201303347

Optopharmacology

Laura Nevola, Andrés Martín-Quirós, Kay Eckelt, Núria Camarero, Sébastien Tosi, Artur Llobet, Ernest Giralt*, Pau Gorostiza*

Light-Regulated Stapled Peptides to Inhibit Protein–Protein Interactions Involved in Clathrin-Mediated Endocytosis
[Communication]

Coming soon.

Synthetic Methods

Pamela G. Alsabeh, Mark Stradiotto*

Addressing Challenges in Palladium-Catalyzed Cross-Couplings of Aryl Mesylates: Monoarylation of Ketones and Primary Alkyl Amines
[Communication]

Published online on June 12, 2013.
DOI: 10.1002/anie.201303305

Demethylases/Hydroxylases

Richard J. Hopkinson, Louise J. Walport, Martin Münzel, Nathan R. Rose, Tristan J. Smart, Akane Kawamura, Timothy D. W. Claridge, Christopher J. Schofield*

Is JmjC Oxygenase Catalysis Limited to Demethylation?
[Communication]

Coming soon.

Nano Stir Bars

Wen Han Chong, Lip Ket Chin, Rachel Lee Siew Tan, Hong Wang, Ai Qun Liu, Hongyu Chen*[WWW]

Stirring in Suspension: Nanometer-Sized Magnetic Stir Bars
[Communication]

Published online on June 13, 2013.
DOI: 10.1002/anie.201303249

Prebiotic Photochemistry

Eliot Boulanger, Anakuthil Anoop, Dana Nachtigallova, Walter Thiel, Mario Barbatti*[WWW]

Photochemical Steps in the Prebiotic Synthesis of Purine Precursors from HCN
[Communication]

Coming soon.

Natural Product Synthesis

Yu Kobayakawa, Masahisa Nakada*[WWW]

Total Syntheses of (−)-Scabronines G and A, and (−)-Episcabronine A
[Communication]

Published online on June 13, 2013.
DOI: 10.1002/anie.201303224

Continuous-Flow Microreactors

Siddharth Sharma, Ram Awatar Maurya, Kyoung-Ik Min, Guan-Young Jeong, Dong-Pyo Kim*[WWW]

Odorless Isocyanide Chemistry: An Integrated Microfluidic System for a Multistep Reaction Sequence
[Communication]

Coming soon.

Sensor Materials

Xuemei Sun, Zhitao Zhang, Xin Lu, Guozhen Guan, Houpu Li, Huisheng Peng*

Electric Current Test Paper Based on Conjugated Polymers and Aligned Carbon Nanotubes
[Communication]

Coming soon.

Asymmetric Catalysis

Mireia Sidera, Philippe M. C. Roth, Rebecca M. Maksymowicz, Stephen P. Fletcher*

Formation of Quaternary Centers by Copper-Catalyzed Asymmetric Conjugate Addition of Alkylzirconium Reagents
[Communication]

Coming soon.

Self-Assembly

Xiaoming Miao, Wei Cao, Wenting Zheng, Jingyu Wang, Xiaoli Zhang, Jie Gao, Chengbiao Yang, Deling Kong*, Huaping Xu*, Ling Wang, Zhimou Yang*[WWW]

Switchable Catalytic Activity: Selenium-Containing Peptides with Redox-Controllable Self-Assembly Properties
[Communication]

Coming soon.

Thulium Diiodide

Michal Szostak*[WWW], Malcolm Spain, David J. Procter*

Uncovering the Importance of Proton Donors in TmI₂-Promoted Electron Transfer: Facile C–N Bond Cleavage in Unactivated Amides
[Communication]

Published online on June 12, 2013.
DOI: 10.1002/anie.201303178

Self-Assembling Fibers

Mark P. Del Borgo, Adam I. Mechler*, Daouda Traore, Craig Forsyth, Prof. Jacqueline A. Wilce, Matthew C. J. Wilce, Marie-Isabel Aguilar*, Patrick Perlmutter*

Supramolecular Self-Assembly of N-Acetyl-Capped β-Peptides Leads to Nano- to Macroscale Fiber Formation
[Communication]

Coming soon.

Frustrated Lewis Pairs

Lindsay J. Hounjet, Christoph Bannwarth, Christian N. Garon, Christopher B. Caputo, Stefan Grimme*, Douglas W. Stephan*[WWW]

Combinations of Ethers and B(C₆F₅)₃ Function as Hydrogenation Catalysts
[Communication]

Published online on June 14, 2013.
DOI: 10.1002/anie.201303166

Alkaloid Synthesis

Shinji Tadano, Yuri Mukaeda, Hayato Ishikawa*[WWW]

Bio-Inspired Dimerization Reaction of Tryptophan Derivatives in Aqueous Acidic Media: Three-Step Syntheses of (+)-WIN 64821, (−)-Ditryptophenaline, and (+)-Naseseazine B
[Communication]

Coming soon.

H₂ Production

Feng Wang, Wen-Jing Liang, Jing-Xin Jian, Cheng-Bo Li, Bin Chen, Chen-Ho Tung, Li-Zhu Wu*

Exceptional Poly(acrylic acid)-Based Artificial [FeFe]-Hydrogenases for Photocatalytic H₂ Production in Water
[Communication]

Coming soon.

Oxidative Cross-Coupling

Gaocan Li, Shengyou Qian, Chunxia Wang, Jingsong You*

Palladium(II)-Catalyzed Dehydrogenative Cross-Coupling between Two C(sp³)–H Bonds: Unexpected C=C Bond Formation
[Communication]

Coming soon.

Supramolecular Chemistry

Alina Grego, Achim Müller*[WWW], Ira A. Weinstock*[WWW]

Stepwise-Resolved Thermodynamics of Hydrophobic Self-Assembly
[Communication]

Published online on June 13, 2013.
DOI: 10.1002/anie.201303083

Polymer Receptors

Mihaiela C. Stuparu*

Rationally Designed Polymer Hosts of Fullerene
[Communication]

Published online on June 13, 2013.
DOI: 10.1002/anie.201303032

Synthetic Methods

Samir Kundlik Pawar, Chiou-Dong Wang, Sabyasachi Bhunia, Appaso Mahadev Jadhav, Rai-Shung Liu*

Gold-Catalyzed Formal Cycloaddition of 2-Ethynylbenzyl Ethers with Organic Oxides and α-Diazoesters
[Communication]

Published online on June 13, 2013.
DOI: 10.1002/anie.201303016

Sustainable Chemistry

Johannes Schranck, Anis Tlili, Matthias Beller*[WWW]

More Sustainable Formation of C–N and C–C Bonds for the Synthesis of N-Heterocycles
[Highlight]

Coming soon.

Asymmetric Catalysis

Xiao-Hui Yang, Jian-Hua Xie*[WWW], Wei-Peng Liu, Qi-Lin Zhou*

Catalytic Asymmetric Hydrogenation of δ-Ketoesters: Highly Efficient Approach to Chiral 1,5-Diols
[Communication]

Published online on June 14, 2013.
DOI: 10.1002/anie.201303011

Iron-Catalyzed Reduction

Haoquan Li, Luis C. Misal Castro, Jianxia Zheng, Thierry Roisnel, Vincent Dorcet, Jean-Baptiste Sortais*, Christophe Darcel*

Selective Reduction of Esters to Aldehydes under the Catalysis of Well-Defined NHC–Iron Complexes
[Communication]

Coming soon.

Small Molecules

Xiaoqing Zeng*, Helmut Beckers*, Helge Willner

The Iminyl Radical O₂SN
[Communication]

Coming soon.

Sulfur Tetrafluoride

James T. Goettel, Nathan Kostiuk, Michael Gerken*

The Solid-State Structure of SF₄: The Final Piece of the Puzzle
[Communication]

Coming soon.

Nanosheets

Tao Yao, Liang Liu, Chong Xiao, Xiaodong Zhang, Qinghua Liu, Shiqiang Wei*, Yi Xie*

Ultrathin Nanosheets of Half-Metallic Monoclinic Vanadium Dioxide with a Thermally Induced Phase Transition
[Communication]

Published online on June 11, 2013.
DOI: 10.1002/anie.201302891

Fluorescent Probes

Yu-De Zhuang, Po-Yi Chiang, Chia-Wen Wang, Kui-Thong Tan*

Environment-Sensitive Fluorescent Turn-On Probes Targeting Hydrophobic Ligand-Binding Domains for Selective Protein Detection
[Communication]

Coming soon.

Bioorganic Chemistry

Young-Woock Noh, Ji Hyun Hong, Sang-Mu Shim, Hye Sun Park, Hee Ho Bae, Eun Kyoung Ryu, Jung Hwan Hwang, Chul-Ho Lee, Seong Hun Cho, Moon-Hee Sung, Haryoung Poo*, Yong Taik Lim*

Polymer Nanomicelles for Efficient Mucus Delivery and Antigen-Specific High Mucosal Immunity
[Communication]

Published online on June 13, 2013.
DOI: 10.1002/anie.201302881

Nanocrystals

Ajay Singh, Shalini Singh, Sergiu Levcenko, Thomas Unold, Fathima Laffir, Kevin M. Ryan*

Compositionally Tunable Photoluminescence Emission in Cu₂ZnSn(S_1−xSe_x)₄ Nanocrystals
[Communication]

Coming soon.

Radiochemistry

Alastair A. Cant, Sue Champion, Rajiv Bhalla, Sally L. Pimlott, Andrew Sutherland*[WWW]

Nickel-Mediated Radioiodination of Aryl and Heteroaryl Bromides: Rapid Synthesis of Tracers for SPECT Imaging
[Communication]

Coming soon.

Molecular Capsules

Akira Suzuki, Kei Kondo, Munetaka Akita, Michito Yoshizawa*

Atroposelective Self-Assembly of a Molecular Capsule from Amphiphilic Anthracene Trimers
[Communication]

Coming soon.

Cumulenes

Hun Young Kim, Edward Oscar Rooney, Raymond Phillip Meury, Kyungsoo Oh*[WWW]

Ambivalent Reactivity Modes of β-Chlorovinyl Ketones: Electrophilic Lithium [3]Cumulenolates from Soft Vinyl Enolization Strategy
[Communication]

Coming soon.

Natural Products

Kyoung Hwa Jang, Sang-Jip Nam, Jeffrey B. Locke, Christopher A. Kauffman, Deanna S. Beatty, Lauren A. Paul, William Fenical*

Anthracimycin, a Potent Anthrax Antibiotic from a Marine-Derived Actinomycete
[Communication]

Coming soon.

Relativistic Effects

Florent Calvo*, Elke Pahl, Michael Wormit, Peter Schwerdtfeger*

Evidence for Low-Temperature Melting of Mercury owing to Relativity
[Communication]

Coming soon.

Arenes

Kohei Fuchibe, Yuka Mayumi, Nan Zhao, Shumpei Watanabe, Misaki Yokota, Junji Ichikawa*[WWW]

Domino Synthesis of Fluorine-Substituted Polycyclic Aromatic Hydrocarbons: 1,1-Difluoroallenes as Synthetic Platforms
[Communication]

Published online on June 14, 2013.
DOI: 10.1002/anie.201302740

Ionic Liquids

Sonja Gabl, Othmar Steinhauser, Hermann Weingärtner*

From Short-Range to Long-Range Intermolecular NOEs in Ionic Liquids: Frequency Does Matter
[Communication]

Coming soon.

Energy Harvesting

Li Zhang, Xiaodong Chen*[WWW]

Nanofluidics for Giant Power Harvesting
[Highlight]

Coming soon.

Solar Water Splitting

Min Zhou, Hao Bin Wu, Jian Bao, Lin Liang, Xiong Wen (David) Lou*[WWW], Yi Xie*

Ordered Macroporous BiVO₄ Architectures with Controllable Dual Porosity for Efficient Solar Water Splitting
[Communication]

Published online on June 14, 2013.
DOI: 10.1002/anie.201302680

Supramolecular Catalysis

Long Qin, Li Zhang*, Qingxian Jin, Jianling Zhang*, Buxing Han, Minghua Liu*

Supramolecular Assemblies of Amphiphilic l-Proline Regulated by Compressed CO₂ as a Recyclable Organocatalyst for the Asymmetric Aldol Reaction
[Communication]

Coming soon.

Homogeneous Catalysis

Sumit Chakraborty, Yogi J. Patel, Jeanette A. Krause, Hairong Guan*[WWW]

A Robust Nickel Catalyst for Cyanomethylation of Aldehydes: Activation of Acetonitrile under Base-Free Conditions
[Communication]

Published online on June 12, 2013.
DOI: 10.1002/anie.201302613

Electrochemistry

Kyle N. Knust, Dzmitry Hlushkou, Robbyn K. Anand, Ulrich Tallarek*, Richard M. Crooks*

Electrochemically Mediated Seawater Desalination
[Communication]

Coming soon.

Biomass Conversion

Linh Bui, Helen Luo, William R. Gunther, Yuriy Román-Leshkov*[WWW]

Domino Reaction Catalyzed by Zeolites with Brønsted and Lewis Acid Sites for the Production of γ-Valerolactone from Furfural
[Communication]

Published online on June 11, 2013.
DOI: 10.1002/anie.201302575

Luminescent Probes

Nalinikanth Kotagiri, Dariusz M. Niedzwiedzki, Kohtaro Ohara, Samuel Achilefu*[WWW]

Activatable Probes Based on Distance-Dependent Luminescence Associated with Cerenkov Radiation
[Communication]

Published online on June 13, 2013.
DOI: 10.1002/anie.201302564

Drug Delivery

Zilong Zhao, Hongmin Meng, Nannan Wang, Michael J. Donovan, Ting Fu, Mingxu You, Zhuo Chen, Xiaobing Zhang*, Weihong Tan*

A Controlled-Release Nanocarrier with Tumor Extracellular pH Value Driven Targeting and Translocation for Drug Delivery
[Communication]

Published online on June 11, 2013.
DOI: 10.1002/anie.201302557

Drug Design

Tony K. M. Shing*[WWW], Wai-Lung Ng, Judy Y.-W. Chan, Clara B.-S. Lau

Design, Syntheses, and SAR Studies of Carbocyclic Analogues of Sergliflozin as Potent Sodium-Dependent Glucose Cotransporter 2 Inhibitors
[Communication]

Coming soon.

Photocatalysts

Jeong Eun Yoo, Kiyoung Lee, Marco Altomare, Elena Selli, Patrik Schmuki*

Self-Organized Arrays of Single-Metal Catalyst Particles in TiO₂ Cavities: A Highly Efficient Photocatalytic System
[Communication]

Published online on June 13, 2013.
DOI: 10.1002/anie.201302525

Natural Products

Senzhi Zhao, Gopal Sirasani, Shivaiah Vaddypally, Michael J. Zdilla, Rodrigo B. Andrade*[WWW]

Total Synthesis of (−)-Melotenine A
[Communication]

Coming soon.

Supramolecular Chemistry

Changzhun Shao, Matthias Stolte, Frank Würthner*

Quadruple π Stack of Two Perylene Bisimide Tweezers: A Bimolecular Complex with Kinetic Stability
[Communication]

Published online on June 11, 2013.
DOI: 10.1002/anie.201302479

Proteomics

Ana Beloqui, Javier Calvo, Sonia Serna, Shi Yan, Iain B. H. Wilson, Manuel Martin-Lomas, Niels Christian Reichardt*

Analysis of Amino-Functionalized Glycan, Glycoprotein, and Lectin Microarrays by MALDI-TOF MS
[Communication]

Published online on June 11, 2013.
DOI: 10.1002/anie.201302455

Carborate Anions

Junichiro Kanazawa, Ryo Takita*, Aleksandra Jankowiak, Shinya Fujii, Hiroyuki Kagechika, Daisuke Hashizume, Koichi Shudo, Piotr Kaszyński, Masanobu Uchiyama*

Copper-Mediated C–C Cross-Coupling Reaction of Monocarba-closo-dodecaborate Anion for the Synthesis of Functional Molecules
[Communication]

Coming soon.

Silver Hydrides

Athanasios Zavras, George N. Khairallah*, Timothy U. Connell, Jonathan M. White, Alison J. Edwards, Paul S. Donnelly*, Richard A. J. O´Hair*

Synthesis, Structure and Gas-Phase Reactivity of a Silver Hydride Complex [Ag₃{(PPh₂)₂CH₂}₃(μ₃-H)(μ₃-Cl)]BF₄
[Communication]

Coming soon.

Gold Catalysis

Yang Yu, Weibo Yang, Frank Rominger, A. Stephen K. Hashmi*[WWW]

In Situ Generation of Nucleophilic Allenes by the Gold-Catalyzed Rearrangement of Propargylic Esters for the Highly Diastereoselective Formation of Intermolecular C(sp³)–C(sp²) Bonds
[Communication]

Published online on June 12, 2013.
DOI: 10.1002/anie.201302402

Organic Semiconductors

Henry Méndez, Georg Heimel*, Andreas Opitz, Katrein Sauer, Patrick Barkowski, Martin Oehzelt, Junshi Soeda, Toshihiro Okamoto, Jun Takeya, Jean-Baptiste Arlin, Jean-Yves Balandier, Yves Geerts, Norbert Koch, Ingo Salzmann*

Doping of Organic Semiconductors: Impact of Dopant Strength and Electronic Coupling
[Communication]

Coming soon.

Natural Products

Xavier Just-Baringo, Paolo Bruno, Lars K. Ottesen, Librada M. Cañedo, Fernando Albericio*[WWW], Mercedes Alvarez*

Total Synthesis and Stereochemical Assignment of Baringolin
[Communication]

Coming soon.

3D Metallomacrocycles

Xiaocun Lu, Xiaopeng Li, Yan Cao, Anthony Schultz, Jin-Liang Wang, Charles N. Moorefield, Chrys Wesdemiotis*[WWW], Stephen Z. D. Cheng, George R. Newkome*

Self-Assembly of a Supramolecular, Three-Dimensional, Spoked, Bicycle-like Wheel
[Communication]

Published online on June 13, 2013.
DOI: 10.1002/anie.201302362

Brucellosis Detection

Julie Guiard, Eugenia Paszkiewicz, Joanna Sadowska, David R. Bundle*[WWW]

Design and Synthesis of a Universal Antigen to Detect Brucellosis
[Communication]

Published online on June 11, 2013.
DOI: 10.1002/anie.201302303

Total Synthesis

Srinivas Banala, Paul Ensle, Roderich D. Süssmuth*

Total Synthesis of the Ribosomally Synthesized Linear Azole-Containing Peptide Plantazolicin A from Bacillus amyloliquefaciens
[Communication]

Published online on June 11, 2013.
DOI: 10.1002/anie.201302266

Asymmetric Hydrogenation

Nuria Ortega, Dan-Tam D. Tang, Slawomir Urban, Dongbing Zhao, Frank Glorius*[WWW]

Ruthenium–NHC-Catalyzed Asymmetric Hydrogenation of Indolizines: Access to Indolizidine Alkaloids
[Communication]

Coming soon.

Cyclic Peptides

Hong-Kui Cui, Ye Guo, Yao He, Feng-Liang Wang, Hao-Nan Chang, Yu-Jia Wang, Fang-Ming Wu, Chang-Lin Tian*, Lei Liu*

Diaminodiacid-Based Solid-Phase Synthesis of Peptide Disulfide Bond Mimics
[Communication]

Coming soon.

Ferroelectricity

Hiroki Taniguchi*, Akihide Kuwabara, Jungeun Kim, Younghun Kim, Hiroki Moriwake, Sungwng Kim, Takuya Hoshiyama, Tsukasa Koyama, Shigeo Mori, Masaki Takata, Hideo Hosono, Yoshiyuki Inaguma, Mitsuru Itoh

Ferroelectricity Driven by Twisting of Silicate Tetrahedral Chains
[Communication]

Published online on June 14, 2013.
DOI: 10.1002/anie.201302188

Synthetic Methods

Nicholas J. Green, Andrew L. Lawrence, Gomotsang Bojase, Anthony C. Willis, Michael N. Paddon-Row*, Michael S. Sherburn*

Domino Cycloaddition Organocascades of Dendralenes
[Communication]

Coming soon.

DNA-Templated Chemistry

Gang Li, Ying Liu, Yu Liu, Li Chen, Siyu Wu, Yang Liu, Xiaoyu Li*

Photoaffinity Labeling of Small-Molecule-Binding Proteins by DNA-Templated Chemistry
[Communication]

Coming soon.

Organocatalysis

Junming Mo, Liang Shen, Yonggui Robin Chi*[WWW]

Direct β-Activation of Saturated Aldehydes to Michael Acceptors through Oxidative NHC Catalysis
[Communication]

Published online on June 13, 2013.
DOI: 10.1002/anie.201302152

Host–Guest Chemistry

Jeanne L. Bolliger, Ana M. Belenguer, Jonathan R. Nitschke*[WWW]

Enantiopure Water-Soluble [Fe₄L₆] Cages: Host–Guest Chemistry and Catalytic Activity
[Communication]

Coming soon.

Photophysics

Anthony Harriman*[WWW], Mohammed A. H. Alamiry, Jerry P. Hagon, Delphine Hablot, Raymond Ziessel*[WWW]

Through-Space Electronic Energy Transfer Across Proximal Molecular Dyads
[Communication]

Published online on June 12, 2013.
DOI: 10.1002/anie.201302081

Asymmetric Fluorination

Hunter P. Shunatona, Natalja Früh, Yi-Ming Wang, Vivek Rauniyar, F. Dean Toste*

Enantioselective Fluoroamination: 1,4-Addition to Conjugated Dienes Using Anionic Phase-Transfer Catalysis
[Communication]

Published online on June 13, 2013.
DOI: 10.1002/anie.201302002

Functional Surfaces

Tsukuru Masuda, Mio Hidaka, Yoko Murase, Aya Mizutani Akimoto, Kenichi Nagase, Teruo Okano, Ryo Yoshida*

Self-Oscillating Polymer Brushes
[Communication]

Published online on June 11, 2013.
DOI: 10.1002/anie.201301988

Metal Clusters

Evgueni G. Mednikov*, Lawrence F. Dahl*

Ion Exchange of Protons by Coinage Metals to Give Gold and Silver Encapsulation within a Pseudo-D_2d Distorted Face-Capped Pd₁₄ Cubic Kernel: [(μ₁₄-M)Pd₂₂(CO)₂₀(PEt₃)₈]⁺ (M=Au, Ag)
[Communication]

Coming soon.

Femtochemistry

Fabrizio Messina, Mirabelle Prémont-Schwarz, Olivier Braem, Dequan Xiao, Victor S. Batista, Erik T. J. Nibbering*, Majed Chergui*

Ultrafast Solvent-Assisted Electronic Level Crossing in 1-Naphthol
[Communication]

Published online on June 12, 2013.
DOI: 10.1002/anie.201301931

Homogeneous Catalysis

Stefan Michlik, Rhett Kempe*

Regioselectively Functionalized Pyridines from Sustainable Resources
[Communication]

Published online on June 14, 2013.
DOI: 10.1002/anie.201301919

Synthetic Methods

Zuxiao Zhang, Fei Wang, Xin Mu, Pinhong Chen, Guosheng Liu*

Copper-Catalyzed Regioselective Fluorination of Allylic Halides
[Communication]

Published online on June 14, 2013.
DOI: 10.1002/anie.201301891

Catalyst Design

Mareike C. Holland, Shyeni Paul, W. Bernd Schweizer, Klaus Bergander, Christian Mück-Lichtenfeld, Sami Lakhdar*, Herbert Mayr, Ryan Gilmour*[WWW]

Noncovalent Interactions in Organocatalysis: Modulating Conformational Diversity and Reactivity in the MacMillan Catalyst
[Communication]

Coming soon.

Cross-Coupling

Alastair J. J. Lennox, Guy C. Lloyd-Jones*[WWW]

Transmetalation in the Suzuki–Miyaura Coupling: The Fork in the Trail
[Minireview]

Coming soon.

Photoactivatable Lipids

André Nadler, Gregor Reither, Suihan Feng, Frank Stein, Sabine Reither, Rainer Müller, Carsten Schultz*

The Fatty Acid Composition of Diacylglycerols Determines Local Signaling Patterns
[Communication]

Published online on June 14, 2013.
DOI: 10.1002/anie.201301716

Thioglycoside Synthesis

Kedar N. Baryal, Danyang Zhu, Xiaohua Li, Jianglong Zhu*

Umpolung Reactivity in the Stereoselective Synthesis of S-Linked 2-Deoxyglycosides
[Communication]

Coming soon.

Total Synthesis

Rebecca M. Wilson, Suwei Dong, Ping Wang, Samuel J. Danishefsky*

The Winding Pathway to Erythropoietin Along the Chemistry–Biology Frontier: A Success At Last
[Minireview]

Coming soon.

Synthetic Methods

Manuel Jäger, Marcel Hartmann, Johannes G. de Vries*[WWW], Adriaan J. Minnaard*

Catalytic Regioselective Oxidation of Glycosides
[Communication]

Coming soon.

Complex Ceramic Structures

Esther Garcia-Tunon*, Suelen Barg, Robert Bell, Jonathan V. M. Weaver, Claudia Walter, Lidia Goyos, Eduardo Saiz

Designing Smart Particles for the Assembly of Complex Macroscopic Structures
[Communication]

Coming soon.

DNA Repair

Junpei Yamamoto*, Ryan Martin, Shigenori Iwai, Pascal Plaza*, Klaus Brettel*

Repair of the (6–4) Photoproduct by DNA Photolyase Requires Two Photons
[Communication]

Published online on June 12, 2013.
DOI: 10.1002/anie.201301567

PEGylated Prodrugs

Friederike Inga Nollmann, Tina Goldbach, Nicole Berthold, Ralf Hoffmann*

Controlled Systemic Release of Therapeutic Peptides from PEGylated Prodrugs by Serum Proteases
[Communication]

Published online on June 13, 2013.
DOI: 10.1002/anie.201301533

Molecular Switches

Gebhard Haberhauer*, Christine Kallweit, Christoph Wölper, Dieter Bläser

An Azobenzene Unit Embedded in a Cyclopeptide as a Type-Specific and Spatially Directed Switch
[Communication]

Coming soon.

Semiconductor Plasmonics

Li-Wei Chou, Michael A. Filler*[WWW]

Engineering Multimodal Localized Surface Plasmon Resonances in Silicon Nanowires
[Communication]

Published online on June 13, 2013.
DOI: 10.1002/anie.201301468

Biosensors

Maria Tintoré, Isaac Gállego, Brendan Manning, Ramon Eritja, Carme Fàbrega*

DNA Origami as a DNA Repair Nanosensor at the Single-Molecule Level
[Communication]

Published online on June 13, 2013.
DOI: 10.1002/anie.201301293

Quadruplex Formation

Jun Zhou, Samir Amrane, Dursun Nizam Korkut, Anne Bourdoncle, Hong-Zhang He, Dik-Lung Ma, Jean-Louis Mergny*

Combination of i-Motif and G-Quadruplex Structures within the Same Strand: Formation and Application
[Communication]

Published online on June 14, 2013.
DOI: 10.1002/anie.201301278

Asymmetric Catalysis

Andreas Schumacher, Maurizio Bernasconi, Andreas Pfaltz*

Chiral N-Heterocyclic Carbene/Pyridine Ligands for the Iridium-Catalyzed Asymmetric Hydrogenation of Olefins
[Communication]

Published online on June 13, 2013.
DOI: 10.1002/anie.201301251

Porphyrin Analogues

Zhongrui Chen, Michel Giorgi, Denis Jacquemin*, Mourad Elhabiri, Olivier Siri*

Azacalixphyrin: The Hidden Porphyrin Cousin Brought to Light
[Communication]

Published online on June 14, 2013.
DOI: 10.1002/anie.201301217

Imaging Agents

Xiaonan Huang, Gang Huang, Shanrong Zhang, Koji Sagiyama, Osamu Togao, Xinpeng Ma, Yiguang Wang, Yang Li, Todd C. Soesbe, Baran D. Sumer, Masaya Takahashi, A. Dean Sherry, Jinming Gao*

Multi-Chromatic pH-Activatable ¹⁹F-MRI Nanoprobes with Binary ON/OFF pH Transitions and Chemical-Shift Barcodes
[Communication]

Coming soon.

Quantum Dots

Yongqiang Dong, Hongchang Pang, Hong Bin Yang, Chunxian Guo, Jingwei Shao, Yuwu Chi, Chang Ming Li*, Ting Yu*

Carbon-Based Dots Co-doped with Nitrogen and Sulfur for High Quantum Yield and Excitation-Independent Emission
[Communication]

Published online on June 11, 2013.
DOI: 10.1002/anie.201301114

Homogeneous Catalysis

Youliang Wang, Akop Yepremyan, Subir Ghorai, Robert Todd, Donald H. Aue*[WWW], Liming Zhang*

Gold-Catalyzed Cyclizations of cis-Enediynes: Insights into the Nature of Gold–Aryne Interactions
[Communication]

Coming soon.

Self-Assembled Nanostructures

Fabian J. Eber, Sabine Eiben, Holger Jeske, Christina Wege*[WWW]

Bottom-Up-Assembled Nanostar Colloids of Gold Cores and Tubes Derived From Tobacco Mosaic Virus
[Communication]

Published online on June 12, 2013.
DOI: 10.1002/anie.201300834

Supported Catalysts

N. Acerbi*, S. C. Edman Tsang*, G. Jones, S. Golunski, P. Collier

Rationalization of Interactions in Precious Metal/Ceria Catalysts Using the d-Band Center Model
[Communication]

Coming soon.

Bioinorganic Chemistry

Seraphine V. Wegner, Joachim P. Spatz*

Cobalt(III) as a Stable and Inert Mediator Ion between NTA and His6-Tagged Proteins
[Communication]

Published online on June 14, 2013.
DOI: 10.1002/anie.201210317

Nanomaterials

Goutam Manna, Riya Bose, Narayan Pradhan*

Semiconducting and Plasmonic Copper Phosphide Platelets
[Communication]

Published online on June 12, 2013.
DOI: 10.1002/anie.201210277

Hierarchical Assembly

Chunhua Cai, Yongliang Li, Jiaping Lin*, Liquan Wang, Shaoliang Lin, Xiao-Song Wang*, Tao Jiang

Simulation-Assisted Self-Assembly of Multicomponent Polymers into Hierarchical Assemblies with Varied Morphologies
[Communication]

Coming soon.

Non-natural Translation

Katarzyna Gorska, Nicolas Winssinger*

Reactions Templated by Nucleic Acids: More Ways to Translate Oligonucleotide-Based Instructions into Emerging Function
[Review]

Published online on June 12, 2013.
DOI: 10.1002/anie.201208460

Bioorganometallic Chemistry

Dik-Lung Ma*, Hong-Zhang He, Ka-Ho Leung, Daniel Shiu-Hin Chan, Chung-Hang Leung

Bioactive Luminescent Transition-Metal Complexes for Biomedical Applications
[Review]

Published online on June 13, 2013.
DOI: 10.1002/anie.201208414

Molecular Imprinting

Li Li, Yue Lu, Zijun Bie, Hong-Yuan Chen, Zhen Liu*

Photolithographic Boronate Affinity Molecular Imprinting: A General and Facile Approach for Glycoprotein Imprinting
[Communication]

Published online on June 13, 2013.
DOI: 10.1002/anie.201207950

CO₂ Photoreduction

Severin N. Habisreutinger, Lukas Schmidt-Mende*, Jacek K. Stolarczyk*

Photocatalytic Reduction of CO₂ on TiO₂ and Other Semiconductors
[Review]

Published online on June 13, 2013.
DOI: 10.1002/anie.201207199

Oxygen Reduction Reaction

Shaojun Guo, Sen Zhang, Shouheng Sun*

Tuning Nanoparticle Catalysis for the Oxygen Reduction Reaction
[Review]

Published online on June 14, 2013.
DOI: 10.1002/anie.201207186

Biofuel cells

Yang Hee Kim, Scott Banta*[WWW]

Oxidation of Methanol in an Enzymatic Biofuel Cell Using a Hydrogel Self-Assembled from Three Modified Dehydrogenases
[Communication]

Coming soon.

Graphene

Andre K. Geim*

Random Walk to Graphene (Nobel Lecture)
[Review]

Coming soon.