Angewandte Chemie International Edition

Cover image for Vol. 54 Issue 14

Editor: Peter Gölitz, Deputy Editors: Neville Compton, Haymo Ross

Online ISSN: 1521-3773

Associated Title(s): Angewandte Chemie, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemistryOpen, ChemPlusChem, Zeitschrift für Chemie

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Here's a selection of upcoming papers. Also see the EarlyView page for the latest papers published online. Click on the VIP logos of upcoming articles to read their abstracts.

Borylene Complexes

Holger Braunschweig*[WWW], Melanie Forster, Thomas Kupfer, Fabian Seeler

Borylene Transfer under Thermal Conditions for the Synthesis of Rhodium and Iridium Borylene Complexes
[Communication]

Coming soon.

Protein Structure Determination

Timothy F. Cunningham, Miriam R. Putterman, Astha Desai, W. Seth Horne*, Sunil Saxena*

The Double-Histidine Cu2+-Binding Motif: A Highly Rigid, Site-Specific Spin Probe for Electron Spin Resonance Distance Measurements
[Communication]

Coming soon.

Asymmetric Catalysis

Karin Weidner, Zhongdong Sun, Naoya Kumagai*, Masakatsu Shibasaki*

Direct Catalytic Asymmetric Aldol Reaction of an α-Azido Amide
[Communication]

Coming soon.

Difluoromethylation

Pavel K. Mykhailiuk*[WWW]

In Situ Generation of Difluoromethyl Diazomethane for [3+2] Cycloadditions with Alkynes
[Communication]

Published online on March 20, 2015.
DOI: 10.1002/anie.201501529

Porphycenes

Koji Oohora, Ayumu Ogawa, Tamaki Fukuda, Akira Onoda, Jun-ya Hasegawa*, Takashi Hayashi*

Meso-Dibenzoporphycene has a Large Bathochromic Shift and a Porphycene Framework with an Unusual Cis Tautomeric Form
[Communication]

Coming soon.

Total Synthesis

Zhe Zhou, Marcus A. Tius*

Synthesis of Each Enantiomer of Rocaglamide by Means of a Palladium(0)-Catalyzed Nazarov-Type Cyclization
[Communication]

Coming soon.

Metallacycles

Congqing Zhu[WWW][WWW], Yuhui Yang, Ming Luo, Caixia Yang, Jingjing Wu, Lina Chen, Gang Liu, Tingbin Wen, Jun Zhu*, Haiping Xia*

Stabilizing Two Classical Antiaromatic Frameworks: Demonstration of Photoacoustic Imaging and the Photothermal Effect in Metalla-aromatics
[Communication]

Coming soon.

Synthetic Methods

Barry M. Trost*, Subham Mahapatra, Martin Hansen

Palladium-Catalyzed C–H Activation of N-Allyl Imines: Regioselective Allylic Alkylations to Deliver Substituted Aza-1,3-Dienes
[Communication]

Published online on March 24, 2015.
DOI: 10.1002/anie.201501322

Crystallization

Jamshed Anwar*, Shahzeb Khan, Lennart Lindfors

Secondary Crystal Nucleation: Nuclei Breeding Factory Uncovered
[Communication]
(VIP) title=

Published online on March 25, 2015.
DOI: 10.1002/anie.201501216

Polycycles

Zhaoyang Yao, Min Zhang, Renzhi Li, Lin Yang, Yongna Qiao, Peng Wang*

A Metal-Free N-Annulated Thienocyclopentaperylene Dye: Power Conversion Efficiency of 12 % for Dye-Sensitized Solar Cells
[Communication]

Coming soon.

NMR Spectroscopy

Giulia Mollica, Myriam Dekhil, Fabio Ziarelli, Pierre Thureau*, Stéphane Viel*

Quantitative Structural Constraints for Organic Powders at Natural Isotopic Abundance Using Dynamic Nuclear Polarization Solid-State NMR Spectroscopy
[Communication]

Published online on March 24, 2015.
DOI: 10.1002/anie.201501172

Bürgenstock Conference

Klaus Müller*

50 Years in the Sun of Bürgenstock—On the Success Factors of a Famous Conference
[Essay]

Published online on March 20, 2015.
DOI: 10.1002/anie.201501161

Zeolite Synthesis

Zhendong Liu, Toru Wakihara, Kazunori Oshima, Daisuke Nishioka, Yuusuke Hotta, Shanmugam P. Elangovan, Yutaka Yanaba, Takeshi Yoshikawa, Watcharop Chaikittisilp, Takeshi Matsuo, Takahiko Takewaki, Tatsuya Okubo*

Widening Synthesis Bottlenecks: Realization of Ultrafast and Continuous-Flow Synthesis of High-Silica Zeolite SSZ-13 for NOx Removal
[Communication]

Published online on March 20, 2015.
DOI: 10.1002/anie.201501160

Porphyrinoids

Norihito Fukui, Hideki Yorimitsu*, Atsuhiro Osuka*

meso,β-Oligohaloporphyrins as Useful Synthetic Intermediates of Diphenylamine-Fused Porphyrin and meso-to-meso β-to-β Doubly Butadiyne-Bridged Diporphyrin
[Communication]

Coming soon.

Asymmetric Synthesis

Francis Belanger, Charles E. Chase, Atsushi Endo, Francis G. Fang*, Jing Li, Steven R. Mathieu, Annie Z. Wilcoxen, Huiming Zhang

Stereoselective Synthesis of the Halaven C14–C26 Fragment from d-Quinic Acid: Crystallization-Induced Diastereoselective Transformation of an α-Methyl Nitrile
[Communication]

Coming soon.

Cycloaddition

Hans-Ulrich Reissig*, Reinhold Zimmer

Thrilling Strain! Donor–Acceptor-Substituted Cyclobutanes for the Synthesis of (Hetero)Cyclic Compounds
[Highlight]

Published online on March 24, 2015.
DOI: 10.1002/anie.201501135

Terpene Biosynthesis

Patrick Rabe, Khomaizon A. K. Pahirulzaman, Jeroen S. Dickschat*

Structures and Biosynthesis of Corvol Ethers—Sesquiterpenes from the Actinomycete Kitasatospora setae
[Communication]

Published online on March 24, 2015.
DOI: 10.1002/anie.201501119

Alloys

Anjan Nandula, Quang Thang Trinh, Mark Saeys*, Anastassia N. Alexandrova*

Origin of Extraordinary Stability of Square-Planar Carbon Atoms in Surface Carbides of Cobalt and Nickel
[Communication]
(VIP) title=

Published online on March 24, 2015.
DOI: 10.1002/anie.201501049

Synthetic Methods

Tuo Jiang, Teresa Bartholomeyzik, Javier Mazuela, Jochen Willersinn, Jan-E. Bäckvall*

Palladium(II)/Brønsted Acid-Catalyzed Enantioselective Oxidative Carbocyclization–Borylation of Enallenes
[Communication]

Published online on March 24, 2015.
DOI: 10.1002/anie.201501048

Heterogeneous Catalysis

Baljeet Singh, Kaustubh R. Mote, C. S. Gopinath, P. K. Madhu*, Vivek Polshettiwar*

SBA-15-Oxynitrides as a Solid-Base Catalyst: Effect of Nitridation Temperature on Catalytic Activity
[Communication]

Published online on March 20, 2015.
DOI: 10.1002/anie.201501015

B,N Azo Dyes

Holger Braunschweig*[WWW], Mehmet Ali Celik, Florian Hupp, Ivo Krummenacher, Lisa Mailänder

Formation of BN Isosteres of Azo Dyes by Ring Expansion of Boroles with Azides
[Communication]

Published online on March 25, 2015.
DOI: 10.1002/anie.201500970

Heterocycle Synthesis

Jundong Li, Huaibo Zhao, Xunjin Jiang, Xiance Wang, Haiming Hu, Lei Yu, Yandong Zhang*

The Cyano Group as a Traceless Activation Group for the Intermolecular [3+2] Cycloaddition of Azomethine Ylides: A Five-Step Synthesis of (±)-Isoretronecanol
[Communication]

Coming soon.

Borenium Cations

Marc Devillard[WWW], Rémy Brousses, Karinne Miqueu*, Ghenwa Bouhadir*, Didier Bourissou*

A Stable but Highly Reactive Phosphine-Coordinated Borenium: Metal-free Dihydrogen Activation and Alkyne 1,2-Carboboration
[Communication]

Published online on March 20, 2015.
DOI: 10.1002/anie.201500959

Fluorescent Probes

Yao Sun, Xiaowei Ma, Kai Cheng, Biying Wu, Jianli Duan, Hao Chen, Lihong Bu, Ruiping Zhang, Xianming Hu, Zixin Deng, Lei Xing, Xuechuan Hong*, Zhen Cheng*

Strained Cyclooctyne as a Molecular Platform for Construction of Multimodal Imaging Probes
[Communication]

Published online on March 20, 2015.
DOI: 10.1002/anie.201500941

Asymmetric Catalysis

Chen Xie, Lingmin Wu, Jianlin Han*, Vadim A. Soloshonok, Yi Pan

Assembly of Fluorinated Quaternary Stereogenic Centers through Catalytic Enantioselective Detrifluoroacetylative Aldol Reactions
[Communication]

Published online on March 24, 2015.
DOI: 10.1002/anie.201500908

Ether Synthesis

Xiao Shen[WWW], Constanze N. Neumann, Claudia Kleinlein, Nathaniel W. Goldberg, Tobias Ritter*

Alkyl Aryl Ether Bond Formation with PhenoFluor
[Communication]

Published online on March 20, 2015.
DOI: 10.1002/anie.201500902

Asymmetric Synthesis

Kei Kitamura, Naoyuki Shimada, Craig Stewart, Abdurrahman C. Atesin, Tülay A. Ateşin*, Marcus A. Tius*

Enantioselective Palladium(0)-Catalyzed Nazarov-Type Cyclization
[Communication]

Coming soon.

Heterogeneous Catalysis

Jose R. Cabrero-Antonino, Antonio Leyva-Pérez*, Avelino Corma*

Beyond Acid Strength in Zeolites: Soft Framework Counteranions for Stabilization of Carbocations on Zeolites and Its Implication in Organic Synthesis
[Communication]

Published online on March 20, 2015.
DOI: 10.1002/anie.201500864

NMR Spectroscopy

Axelle Cotte, Damien Jeannerat*

1D NMR Homodecoupled 1H Spectra with Scalar Coupling Constants from 2D NemoZS-DIAG Experiments
[Communication]

Published online on March 25, 2015.
DOI: 10.1002/anie.201500831

C–H Activation

Manfred Manßen, Nicolai Lauterbach, Jaika Dörfler, Marc Schmidtmann, Wolfgang Saak, Sven Doye*, Rüdiger Beckhaus*

Efficient Access to Titanaaziridines by C–H Activation of N-Methylanilines at Ambient Temperature
[Communication]

Published online on March 24, 2015.
DOI: 10.1002/anie.201500796

DNA Nanocages

Yulin Li, Cheng Tian, Zhiyu Liu, Wen Jiang, Chengde Mao*

Structural Transformation: Assembly of an Otherwise Inaccessible DNA Nanocage
[Communication]
(VIP) title=

Published online on March 25, 2015.
DOI: 10.1002/anie.201500755

Reaction Mechanisms

Thomas Fallon*[WWW], Martin Oestreich*

A Constellation of Deuterium-Labeled Silanes as a Simple Mechanistic Probe not Requiring Absolute Configuration Determination
[Communication]
(VIP) title=

Published online on March 20, 2015.
DOI: 10.1002/anie.201500750

Synthetic Methods

Xigong Liu, Zhilin Meng, Chengkun Li, Hongxiang Lou, Lei Liu*

Organocatalytic Enantioselective Oxidative C–H Alkenylation and Arylation of N-Carbamoyl Tetrahydropyridines and Tetrahydro-β-carbolines
[Communication]

Published online on March 25, 2015.
DOI: 10.1002/anie.201500703

Cluster Compounds

Xian-Kai Wan, Shang-Fu Yuan, Qing Tang, De-en Jiang*, Quan-Ming Wang*

Alkynyl-Protected Au23 Nanocluster: A 12-Electron System
[Communication]

Published online on March 25, 2015.
DOI: 10.1002/anie.201500590

Structure Elucidation

Maria Baias, Anne Lesage, Sonia Aguado, Jerome Canivet, Virginie Moizan-Basle, Nathalie Audebrand, David Farrusseng*, Lyndon Emsley*

Superstructure of a Substituted Zeolitic Imidazolate Metal–Organic Framework Determined by Combining Proton Solid-State NMR Spectroscopy and DFT Calculations
[Communication]

Published online on March 25, 2015.
DOI: 10.1002/anie.201500518

B,N Heterocycles

Deng-Tao Yang, Soren K. Mellerup, Xiang Wang, Jia-Sheng Lu, Suning Wang*

Reversible 1,1-Hydroboration: Boryl Insertion into a C–N Bond and Competitive Elimination of HBR2 or R–H
[Communication]

Published online on March 20, 2015.
DOI: 10.1002/anie.201500487

Metal–Organic Frameworks

Hao Wang, Jian Xu, Da-Shuai Zhang, Qiang Chen, Rong-Mei Wen, Ze Chang, Xian-He Bu*

Crystalline Capsules: Metal–Organic Frameworks Locked by Size-Matching Ligand Bolts
[Communication]

Published online on March 20, 2015.
DOI: 10.1002/anie.201500468

Peptidomimetics

Rock J. Mancini, Lalisa Stutts, Troy Moore, Aaron P. Esser-Kahn*

Controlling the Origins of Inflammation with a Photoactive Lipopeptide Immunopotentiator
[Communication]

Published online on March 20, 2015.
DOI: 10.1002/anie.201500416

Cell Adhesion

Shihui Li, Erin R. Gaddes, Niancao Chen, Yong Wang*

Molecular Encryption and Reconfiguration for Remodeling of Dynamic Hydrogels
[Communication]

Published online on March 25, 2015.
DOI: 10.1002/anie.201500397

Proteomics

Malgorzata Broncel, Remigiusz A. Serwa*, Paulina Ciepla, Eberhard Krause, Margaret J. Dallman, Anthony I. Magee, Edward W. Tate*

Multifunctional Reagents for Quantitative Proteome-Wide Analysis of Protein Modification in Human Cells and Dynamic Profiling of Protein Lipidation During Vertebrate Development
[Communication]

Published online on March 25, 2015.
DOI: 10.1002/anie.201500342

Self-Assembly

Jatish Kumar, Hiroyuki Tsumatori, Junpei Yuasa, Tsuyoshi Kawai*, Takuya Nakashima*

Self-Discriminating Termination of Chiral Supramolecular Polymerization: Tuning the Length of Nanofibers
[Communication]

Published online on March 20, 2015.
DOI: 10.1002/anie.201500292

Nanoparticles

Ophélie Vaillant, Khaled El Cheikh, David Warther, David Brevet, Marie Maynadier, Elise Bouffard, Frédéric Salgues, Audrey Jeanjean, Pierre Puche, Catherine Mazerolles, Philippe Maillard, Olivier Mongin, Mireille Blanchard-Desce, Laurence Raehm, Xavier Rébillard, Jean-Olivier Durand*, Magali Gary-Bobo*, Alain Morère*, Marcel Garcia

Mannose-6-Phosphate Receptor: A Target for Theranostics of Prostate Cancer
[Communication]

Published online on March 20, 2015.
DOI: 10.1002/anie.201500286

DNA Nanostructures

Jennifer E. Padilla*, Ruojie Sha, Martin Kristiansen, Junghuei Chen, Natasha Jonoska, Nadrian C. Seeman*

A Signal-Passing DNA-Strand-Exchange Mechanism for Active Self-Assembly of DNA Nanostructures
[Communication]

Published online on March 24, 2015.
DOI: 10.1002/anie.201500252

Hydrides

Xingbang Hu*, Michèle Soleilhavoup, Mohand Melaimi, Jiaxiang Chu, Guy Bertrand*

Air-Stable (CAAC)CuCl and (CAAC)CuCuBH4 Complexes as Catalysts for the Hydrolytic Dehydrogenation of BH3NH3
[Communication]

Published online on March 20, 2015.
DOI: 10.1002/anie.201500224

Mechanochemistry

Keiichi Imato, Atsushi Irie, Takahiro Kosuge, Tomoyuki Ohishi, Masamichi Nishihara, Atsushi Takahara*, Hideyuki Otsuka*

Mechanophores with a Reversible Radical System and Freezing-Induced Mechanochemistry in Polymer Solutions and Gels
[Communication]

Coming soon.

Gold Photocatalysis

Jin Xie[WWW], Shuai Shi, Tuo Zhang, Nina Mehrkens, Matthias Rudolph, A. Stephen K. Hashmi*

A Highly Efficient Gold-Catalyzed Photoredox α-C(sp3)–H Alkynylation of Tertiary Aliphatic Amines with Sunlight
[Communication]

Coming soon.

Bacterial Detection

Houyu Wang, Yanfeng Zhou, Xiangxu Jiang, Bin Sun, Ying Zhu, Hui Wang, Yuanyuan Su, Yao He*

Simultaneous Capture, Detection, and Inactivation of Bacteria as Enabled by a Surface-Enhanced Raman Scattering Multifunctional Chip
[Communication]

Coming soon.

Boron-Doped Graphite

Timothy C. King, Peter D. Matthews, Hugh Glass, Jonathan A. Cormack, Juan Pedro Holgado, Michal Leskes, John M. Griffin, Oren A. Scherman, Paul D. Barker, Clare P. Grey, Siân E. Dutton, Richard M. Lambert, Gary Tustin, Ali Alavi*, Dominic S. Wright*

Theory and Practice: Bulk Synthesis of C3B and its H2- and Li-Storage Capacity
[Communication]

Published online on March 25, 2015.
DOI: 10.1002/anie.201412200

Biosensors

Xiaohu Zhang, Abasaheb N. Dhawane, Joyce Sweeney, Yun He, Mugdha Vasireddi, Suri S. Iyer*

Electrochemical Assay to Detect Influenza Viruses and Measure Drug Susceptibility
[Communication]

Coming soon.

Biosynthetic Pathways

Xin Fang, Ying Tong Di, Yu Zhang, Zhi Ping Xu, Yang Lu, Qian Qian Chen, Qi Tai Zheng, Xiao Jiang Hao*

Unprecedented Quassinoids with Promising Biological Activity from Harrisonia perforata
[Communication]

Published online on March 25, 2015.
DOI: 10.1002/anie.201412126

Photocatalysis

Hua Sheng, Hongna Zhang, Wenjing Song, Hongwei Ji, Wanhong Ma, Chuncheng Chen*, Jincai Zhao

Activation of Water in Titanium Dioxide Photocatalysis by Formation of Surface Hydrogen Bonds: An In Situ IR Spectroscopy Study
[Communication]

Published online on March 25, 2015.
DOI: 10.1002/anie.201412035

Monofluoromethylation

Yi-Ming Su, Guang-Shou Feng, Zhen-Yu Wang, Quan Lan, Xi-Sheng Wang*

Nickel-Catalyzed Monofluoromethylation of Aryl Boronic Acids
[Communication]

Published online on March 24, 2015.
DOI: 10.1002/anie.201412026

Radical Cascades

Yinjun Xie, Shengmei Guo, Longmin Wu, Chungu Xia, Hanmin Huang*

Metal Bridging for Directing and Accelerating Electron Transfer as Exemplified by Harnessing the Reactivity of AIBN
[Communication]

Published online on March 25, 2015.
DOI: 10.1002/anie.201411974

Polycyclic π Systems

Bernd Kohl, Frank Rominger, Michael Mastalerz*

A Pyrene-Fused N-Heteroacene with Eleven Rectilinearly Annulated Aromatic Rings
[Communication]

Coming soon.

Photodynamic Therapy

Safacan Kolemen, Murat Işık, Gyoung Mi Kim, Dabin Kim, Hao Geng, Muhammed Buyuktemiz, Tugce Karatas, Xian-Fu Zhang, Yavuz Dede, Juyoung Yoon*, Engin U. Akkaya*

Intracellular Modulation of Excited-State Dynamics in a Chromophore Dyad: Differential Enhancement of Photocytotoxicity Targeting Cancer Cells
[Communication]

Published online on March 24, 2015.
DOI: 10.1002/anie.201411962

Porous capsules

Somenath Garai[WWW], Mirta Rubčić, Hartmut Bögge, Erhard T. K. Haupt, Pierre Gouzerh, Achim Müller*

A Unique Fluoride Nanocontainer: Porous Molecular Capsules Can Accommodate an Unusually High Number of "Rather Labile" Fluoride Anions
[Communication]
(VIP) title=

Published online on March 24, 2015.
DOI: 10.1002/anie.201411814

Organic Electronics

David J. Dibble, Young S. Park, Amir Mazaheripour, Mehran J. Umerani, Joseph W. Ziller, Alon A. Gorodetsky*

Synthesis of Polybenzoquinolines as Precursors for Nitrogen-Doped Graphene Nanoribbons
[Communication]

Coming soon.

Olefin Cross Metathesis

Myles B. Herbert, Robert H. Grubbs*

Z-Selective Cross Metathesis with Ruthenium Catalysts: Synthetic Applications and Mechanistic Implications
[Minireview]

Published online on March 20, 2015.
DOI: 10.1002/anie.201411588

Mononuclear Lanthanide SMMs

Andrew J. Brown[WWW], Dawid Pinkowicz, Mohamed R. Saber, Kim R. Dunbar*

A Trigonal-Pyramidal Erbium(III) Single-Molecule Magnet
[Communication]

Published online on March 24, 2015.
DOI: 10.1002/anie.201411190

Asymmetric Synthesis

Barry M. Trost*, Meera Rao

Development of Chiral Sulfoxide Ligands for Asymmetric Catalysis
[Review]

Published online on March 20, 2015.
DOI: 10.1002/anie.201411073

Surface Architectures

José I. Urgel, David Ecija*, Willi Auwärter*, Daphné Stassen, Davide Bonifazi*, Johannes V. Barth

Orthogonal Insertion of Lanthanide and Transition-Metal Atoms in Metal-Organic Networks on Surfaces
[Communication]

Coming soon.

Lignin Valorization

Thorsten vom Stein[WWW], Tim den Hartog, Julien Buendia, Spas Stoychev, Jakob Mottweiler, Carsten Bolm, Jürgen Klankermayer*, Walter Leitner

Ruthenium-Catalyzed C–C Bond Cleavage in Lignin Model Substrates
[Communication]

Published online on March 25, 2015.
DOI: 10.1002/anie.201410620

Amino Acid Labeling

Sean E. Pidgeon, Jonathan M. Fura, William Leon, Morgan Birabaharan, Dmitri Vezenov, Marcos M. Pires*

Metabolic Profiling of Bacteria by Unnatural C-terminated d-Amino Acids
[Communication]

Coming soon.

Electrode Materials

Wen Liu[WWW], Pilgun Oh, Xien Liu, Min-Joon Lee, Woongrae Cho, Sujong Chae, Youngsik Kim, Jaephil Cho*

Nickel-Rich Layered Lithium Transitional-Metal Oxide for High-Energy Lithium-Ion Batteries
[Review]

Published online on March 20, 2015.
DOI: 10.1002/anie.201409262

Magnetotactic Bacteria

Damien Faivre*[WWW], Tina Ukmar Godec

From Bacteria to Mollusks: The Principles Underlying the Biomineralization of Iron Oxide Materials
[Review]

Coming soon.

Zintl Cluster Compounds

Christian B. Benda, Markus Waibel, Thomas F. Fässler*

On the Formation of Intermetalloid Clusters: Titanocene(III)diammin as a Versatile Reactant Toward Nonastannide Zintl Clusters
[Communication]

Coming soon.

Bioactive Glasses

Delia S. Brauer*[WWW]

Bioactive Glasses—Structure and Properties
[Review]

Published online on March 24, 2015.
DOI: 10.1002/anie.201405310

Binary Superlattices

Sung-Hwan Lim[WWW], Hyung-Sik Jang, Jae-Min Ha, Tae-Hwan Kim, Pawel Kwasniewski, Theyencheri Narayanan, Kyeong Sik Jin, Sung-Min Choi*

Highly Ordered and Highly Aligned Two-Dimensional Binary Superlattice of a SWNT/Cylindrical-Micellar System
[Communication]

Coming soon.

Biofuel cells

Yang Hee Kim, Scott Banta*[WWW]

Oxidation of Methanol in an Enzymatic Biofuel Cell Using a Hydrogel Self-Assembled from Three Modified Dehydrogenases
[Communication]
(VIP - Read Abstract)

Coming soon.

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