Angewandte Chemie International Edition

Cover image for Vol. 54 Issue 37

Editor: Peter Gölitz, Deputy Editors: Neville Compton, Haymo Ross

Online ISSN: 1521-3773

Associated Title(s): Angewandte Chemie, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemistryOpen, ChemPlusChem, Zeitschrift für Chemie

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Here's a selection of upcoming papers. Also see the EarlyView page for the latest papers published online. Click on the VIP logos of upcoming articles to read their abstracts.

Cyclizations

Wanxiang Zhao[WWW], John Montgomery*

Functionalization of Styrenes by Copper-Catalyzed Borylation/ ortho-Cyanation and Silver-Catalyzed Annulation Processes
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201507303

Biosynthesis

Martin Baunach, Christian Hertweck*

Natural 1,3-Dipolar Cycloadditions
[Highlight]

Coming soon.

Dehydrogenation

Lei Shi, Gao-Ming Deng, Wen-Cui Li, Shu Miao, Qing-Nan Wang, Wei-Ping Zhang, An-Hui Lu*

Al2O3 Nanosheets Rich in Pentacoordinate Al3+ Ions Stabilize Pt-Sn Clusters for Propane Dehydrogenation
[Communication]
(VIP) title=

Published online on September 2, 2015.
DOI: 10.1002/anie.201507119

Anthraquinones

K. C. Nicolaou*, Min Lu, Pengxi Chen, Akshay A. Shah

Practical Synthesis of p- and o-Amino- and Methoxyphenolic Anthraquinones
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201507007

Fluorescence Probes

Pavlo Kos, Herbert Plenio*

A Fluorescent Molecular Probe for the Detection of Hydrogen Based on Oxidative Addition Reactions with Crabtree-Type Hydrogenation Catalysts
[Communication]
(VIP - Read Abstract)

Coming soon.

Leukemia Therapy

Matthew B. Minus, Wei Liu, Farrukh Vohidov, Moses M. Kasembeli, Xin Long, Michael J. Krueger, Alexandra Stevens, Mikhail I. Kolosov, David J. Tweardy*, Edward Allan R. Sison*, Michele S. Redell*, Zachary T. Ball*

Rhodium(II) Proximity-Labeling Identifies a Novel Target Site on STAT3 for Inhibitors with Potent Anti-Leukemia Activity
[Communication]
(VIP - Read Abstract)

Coming soon.

Rieske Clusters

Shenglai Yao, Florian Meier, Nils Lindenmaier, Robert Rudolph, Burgert Blom, Mario Adelhardt, Jörg Sutter, Stefan Mebs, Michael Haumann, Karsten Meyer, Martin Kaupp, Matthias Driess*

Biomimetic [2Fe-2S] Clusters with Extensively Delocalized Mixed-Valence Iron Centers
[Communication]

Coming soon.

Butterfly Complexes

Christoph Schwarzmaier, Sebastian Heinl, Gábor Balázs, Manfred Scheer*

E4 Butterfly Complexes (E=P, As) as Chelating Ligands
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201506784

Energetic Materials

David E. Chavez*, Jeffery C. Bottaro, Mark Petrie, Damon A. Parrish

Synthesis and Thermal Behavior of a Fused, Tricyclic 1,2,3,4-Tetrazine Ring System
[Communication]

Published online on September 3, 2015.
DOI: 10.1002/anie.201506744

Protein Engineering

Cornelia Ritter, Nathalie Nett, Carlos G. Acevedo-Rocha, Richard Lonsdale, Katja Kräling, Felix Dempwolff, Sabrina Hoebenreich, Peter L. Graumann, Manfred T. Reetz*, Eric Meggers*

Bioorthogonal Enzymatic Activation of Caged Compounds
[Communication]

Coming soon.

Bioinorganic Chemistry

Kenta Fujita, Yuya Tanaka, Satoshi Abe, Takafumi Ueno*

A Photoactive Carbon-Monoxide-Releasing Protein Cage for Dose-Regulated Delivery in Living Cells
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201506738

Cross-Coupling

Wei Su, Tian-Jun Gong, Xi Lu, Meng-Yu Xu, Chu-Guo Yu, Zheng-Yang Xu, Hai-Zhu Yu, Bin Xiao*, Yao Fu*

Ligand-Controlled Regiodivergent Copper-Catalyzed Alkylboration of Alkenes
[Communication]
(VIP - Read Abstract)

Coming soon.

Organic Light-Emitting Diodes

Shipan Wang, Xianju Yan, Zong Cheng, Hongyu Zhang, Yu Liu, Yue Wang*

Highly Efficient Near-Infrared Delayed Fluorescence Organic Light Emitting Diodes Using a Phenanthrene-Based Charge-Transfer Compound
[Communication]

Coming soon.

Supramolecular Block Copolymers

Leonie Barner*, Christopher Barner-Kowollik*

The Link that Lasts: A New Frontier in Supramolecular Block Copolymer Design
[Highlight]

Coming soon.

Heterocycles

Arunachalam Sagadevan, Ayyakkannu Ragupathi, Kuo Chu Hwang*

Photoinduced Copper-Catalyzed Regioselective Synthesis of Indoles: Three-Component Coupling of Arylamines, Terminal Alkynes, and Quinones
[Communication]

Coming soon.

C–C Activation

Rongguo Ren, Huijun Zhao, Leitao Huan, Chen Zhu*

Manganese-Catalyzed Oxidative Azidation of Cyclobutanols: Regiospecific Synthesis of Alkyl Azides by C–C Bond Cleavage
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201506578

Photocatalysis

Theodore R. Canterbury, Shamindri M. Arachchige, Robert B. Moore*, Karen J. Brewer

Increased Water Reduction Efficiency of Polyelectrolyte-Bound Trimetallic [Ru,Rh,Ru] Photocatalysts in Air-Saturated Aqueous Solutions
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201506567

Metathesis

Aaron D. Lackner, Alois Fürstner*

The Triple-Bond Metathesis of Aryldiazonium Salts: A Prospect for Dinitrogen Cleavage
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201506546

Gelation vs Crystallization

Adiyala Vidyasagar[WWW], Kana M. Sureshan*

Stoichiometric Sensing to Opt between Gelation and Crystallization
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201506544

Stimuli-Responsive Materials

Hyungwoo Kim[WWW], Hemakesh Mohapatra, Scott T. Phillips*

Rapid, On-Command Debonding of Stimuli-Responsive Cross-Linked Adhesives by Continuous, Sequential Quinone Methide Elimination Reactions
[Communication]
(VIP - Read Abstract)

Coming soon.

Enzyme Catalysis

Dawei Chen, Ridao Chen, Ruishan Wang, Jianhua Li, Kebo Xie, Chuancai Bian, Lili Sun, Xiaolin Zhang, Jimei Liu, Lin Yang, Fei Ye, Xiaoming Yu, Jungui Dai*

Probing the Catalytic Promiscuity of a Regio- and Stereospecific C-Glycosyltransferase from Mangifera indica
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201506505

Metalloradicals

Douglas W. Agnew, Curtis E. Moore, Arnold L. Rheingold, Joshua S. Figueroa*

Kinetic Destabilization of Metal–Metal Single Bonds: Isolation of a Pentacoordinate Manganese(0) Monoradical
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201506498

Nanoparticles

Akihisa Yamaguchi*, Yu Mashima, Tomokazu Iyoda

Reversible Size Control of Liquid-Metal Nanoparticles under Ultrasonication
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201506469

Cross-Coupling

Yunze Huang, Rui Zhu, Kun Zhao, Zhenhua Gu*

Palladium-Catalyzed Catellani ortho-Acylation Reaction: An Efficient and Regiospecific Synthesis of Diaryl Ketones
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201506446

Chiral Polymerization

Bhawani Narayan, Karteek K. Bejagam, Sundaram Balasubramanian, Subi J. George*

Autoresolution of Segregated and Mixed p-n Stacks by Stereoselective Supramolecular Polymerization in Solution
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201506435

Cycloarylenes

Zhe Sun, Parantap Sarkar, Takuya Suenaga, Sota Sato, Hiroyuki Isobe*

Belt-Shaped Cyclonaphthylenes
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201506424

Cathode Materials

Fenghua Zheng, Chenghao Yang*, Xunhui Xiong, Jiawen Xiong, Renzong Hu, Yu Chen, Meilin Liu*

Nanoscale Surface Modification of Lithium-Rich Layered-Oxide Composite Cathodes for Suppressing Voltage Fade
[Communication]
(VIP) title=

Published online on September 3, 2015.
DOI: 10.1002/anie.201506408

C–H Activation

Zhe Dong[WWW], Jianchun Wang, Zhi Ren, Guangbin Dong*

Ortho C–H Acylation of Aryl Iodides by Palladium/Norbornene Catalysis
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201506397

Natural Product Synthesis

Shermin S. Goh, Guilhem Chaubet, Birgit Gockel, Marie-Caroline A. Cordonnier, Hannah Baars, Andrew W. Phillips, Edward A. Anderson*

Total Synthesis of (+)-Rubriflordilactone A
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201506366

Polyphosphorus Complexes

Martin Fleischmann, Fabian Dielmann, Laurence J. Gregoriades, Eugenia V. Peresypkina, Alexander V. Virovets, Sebastian Huber, Alexey Y. Timoshkin, Gábor Balázs, Manfred Scheer*

Redox and Coordination Behavior of the Hexaphosphabenzene Ligand in [(Cp*Mo)2(μ,η6:η6-P6)] Towards the "Naked" Cations Cu+, Ag+, and Tl+
[Communication]

Coming soon.

Rewritable Materials

Oliver Roling, Kevin De Bruycker, Benjamin Vonhören, Lucas Stricker, Martin Körsgen, Heinrich F. Arlinghaus, Bart Jan Ravoo*, Filip E. Du Prez*

Rewritable Polymer Brush Micropatterns Grafted by Triazolinedione Click Chemistry
[Communication]

Coming soon.

Structural Biology

Alexander D. Jacobs, Feng-Ming James Chang, Lindsay Morrison, Jonathan M. Dilger, Vicki H. Wysocki, David E. Clemmer, David P. Giedroc*

Resolution of Stepwise Cooperativities of Copper Binding by the Homotetrameric Copper-Sensitive Operon Repressor (CsoR): Impact on Structure and Stability
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201506349

Alkenes

Masao Morimoto, Tomoya Miura*, Masahiro Murakami*

Rhodium-Catalyzed Dehydrogenative Borylation of Aliphatic Terminal Alkenes with Pinacolborane
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201506328

C–H Activation

He Wang, Guodong Tang, Xingwei Li*

Rhodium(III)-Catalyzed Amidation of Unactivated C(sp3)–H Bonds
[Communication]

Coming soon.

Inhibitors

Edwin Kroon[WWW], Jörg O. Schulze, Evelyn Süß, Carlos J. Camacho, Ricardo M. Biondi, Alexander Dömling*

Discovery of a Potent Allosteric Kinase Modulator by Combining Computational and Synthetic Methods
[Communication]

Coming soon.

C–H Activation

Yuqi Tan, Wei Yuan, Lei Gong*, Eric Meggers*

Aerobic Asymmetric Dehydrogenative Cross-Coupling between Two C(sp3)–H Groups Catalyzed by a Chiral-at-Metal Rhodium Complex
[Communication]

Coming soon.

Natural Products

Hucheng Zhu, Chunmei Chen, Yongbo Xue, Qingyi Tong, Xiao-Nian Li, Xintao Chen, Prof. Jianping Wang, Dr. Guangmin Yao, Zengwei Luo, Dr. Yonghui Zhang*

Asperchalasine A, a Cytochalasan Dimer with an Unprecedented Decacyclic Ring System, from Aspergillus flavipes
[Communication]

Published online on September 3, 2015.
DOI: 10.1002/anie.201506264

Proline Isomerization

Gilles Berger, Miguel Vilchis-Reyes, Stephen Hanessian*

Structural Properties and Stereochemically Distinct Folding Preferences of 4,5-cis and trans-Methano-l-Proline Oligomers: The Shortest Crystalline PPII-type Helical Proline-Derived Tetramer
[Communication]

Coming soon.

Organocatalysis

Qiang-Sheng Sun, Hua Zhu, Yong-Jian Chen, Xiao-Di Yang, Xing-Wen Sun*, Guo-Qiang Lin

Squaramide-Catalyzed Synthesis of Enantioenriched Spirocyclic Oxindoles via Ketimine Intermediates with Multiple Active Sites
[Communication]

Coming soon.

Sensors

Zhongyu Cai, Daniel H. Kwak, David Punihaole, Zhenmin Hong, Sachin S. Velankar, Xinyu Liu*, Sanford A. Asher*

A Photonic Crystal Protein Hydrogel Sensor for Candida albicans
[Communication]

Coming soon.

Molecular-Sieve Films

Tongwen Yu, Wenling Chu, Rui Cai*, Yanchun Liu, Weishen Yang*

In Situ Electrochemical Synthesis of Oriented and Defect-Free AEL Molecular-Sieve Films Using Ionic Liquids
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201506183

Photothermal Agents

Zhengbo Sun, Hanhan Xie, Siying Tang, Xue-Feng Yu*, Zhinan Guo, Jundong Shao, Han Zhang*, Hao Huang, Huaiyu Wang, Paul K. Chu*

Ultrasmall Black Phosphorus Quantum Dots: Synthesis and Use as Photothermal Agents
[Communication]

Coming soon.

Ruthenium Carbenes

Markus Leutzsch, Larry M. Wolf, Puneet Gupta, Michael Fuchs, Walter Thiel, Christophe Farès, Alois Fürstner*

Formation of Ruthenium Carbenes by gem-Hydrogen Transfer to Internal Alkynes: Implications for Alkyne trans-Hydrogenation
[Communication]
(VIP) title=

Published online on September 2, 2015.
DOI: 10.1002/anie.201506075

Allenes

Ge Zhang, Tao Xiong, Zining Wang, Guoxing Xu, Xuedan Wang, Qian Zhang*

Highly Regioselective Radical Amination of Allenes: Direct Synthesis of Allenamides and Tetrasubstituted Alkenes
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201506066

NMR Spectroscopy

Evan W. Zhao, Haibin Zheng, Ronghui Zhou, Helena E. Hagelin-Weaver*, Clifford R. Bowers*

Shaped Ceria Nanocrystals Catalyze Efficient and Selective Para-Hydrogen-Enhanced Polarization
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201506045

18F Fluorination

Faye Buckingham, Anna K. Kirjavainen, Sarita Forsback, Anna Krzyczmonik, Thomas Keller, Ian M. Newington, Matthias Glaser, Sajinder K. Luthra, Olof Solin, Véronique Gouverneur*

Organomediated Enantioselective 18F Fluorination for PET Applications
[Communication]

Coming soon.

Radical Chemistry

George N. Khairallah, Alan T. Maccarone, Huong T. Pham, Timothy M. Benton, Tony Ly, Gabriel da Silva, Stephen J. Blanksby*, Richard A. J. O′Hair*

Radical Formation in the Gas-Phase Ozonolysis of Deprotonated Cysteine
[Communication]

Published online on September 3, 2015.
DOI: 10.1002/anie.201506019

Carbenes

Naijing Su[WWW], Juliana A. Theorell, Donald J. Wink, Tom G. Driver*

Copper-Catalyzed Formation of α-Alkoxycycloalkenones from N-Tosylhydrazones
[Communication]

Coming soon.

Cell Signaling

Jin Lu, Jinghong Li*

Label-Free Imaging of Dynamic and Transient Calcium Signaling in Single Cells
[Communication]

Coming soon.

Frustrated Lewis Pairs

Yoichi Hoshimoto*, Takuya Kinoshita, Masato Ohashi, Sensuke Ogoshi*

A Strategy to Control the Reactivation of Frustrated Lewis Pairs from Shelf-Stable Carbene Borane Complexes
[Communication]

Coming soon.

Bioelectronics

Sara Raichlin, Israel Pecht*, Mordechai Sheves*, David Cahen*

Protein Electronic Conductors: Hemin–Substrate Bonding Dictates Transport Mechanism and Efficiency across Myoglobin
[Communication]

Coming soon.

Dual Catalysis

Han Zhou[WWW], Long Zhang, Changming Xu, Sanzhong Luo*

Chiral Primary Amine/Palladium Dual Catalysis for Asymmetric Allylic Alkylation of β-Ketocarbonyl Compounds with Allylic Alcohols
[Communication]

Coming soon.

Multiple Bonds

Jingzhen Du[WWW], Linbo Wang, Meihua Xie, Liang Deng*

A Two-Coordinate Cobalt(II) Imido Complex with NHC Ligation: Synthesis, Structure, and Reactivity
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201505937

C–H Activation

Yun-Fei Zhang, Hong-Wei Zhao, Hui Wang, Jiang-Bo Wei, Zhang-Jie Shi*

Readily Removable Directing Group Assisted Chemo- and Regioselective C(sp3)–H Activation by Palladium Catalysis
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201505932

Asymmetric Catalysis

Yazhou Lou, Peng Cao, Tao Jia, Yongling Zhang, Min Wang, Jian Liao*

Copper-Catalyzed Enantioselective 1,6-Boration of para-Quinone Methides and Efficient Transformation of gem-Diarylmethine Boronates to Triarylmethanes
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201505926

Supported Catalysts

Iuliia Romanenko, David Gajan, Reine Sayah, Delphine Crozet, Erwan Jeanneau, Christine Lucas, Lénaic Leroux, Laurent Veyre, Anne Lesage, Lyndon Emsley, Emmanuel Lacôte*, Chloé Thieuleux*

Iridium(I)/N-Heterocyclic Carbene Hybrid Materials: Surface Stabilization of Low-Valent Iridium Species for High Catalytic Hydrogenation Performance
[Communication]

Coming soon.

Decarboxylative Cross-Coupling

Jie Tang[WWW], Agostino Biafora, Lukas J. Goossen*

Catalytic Decarboxylative Cross-Coupling of Aryl Chlorides and Benzoates without Activating ortho Substituents
[Communication]

Coming soon.

Pyrotechnics

Jesse J. Sabatini*, Ernst-Christian Koch*, Jay C. Poret, Jared D. Moretti, Seth M. Harbol

Chlorine-Free Red-Burning Pyrotechnics
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201505829

Photocage Compounds

Prem N. Basa, Sagar Antala, Robert E. Dempski, Shawn C. Burdette*

A Zinc(II) Photocage Based on a Decarboxylation Metal Ion Release Mechanism for Investigating Homeostasis and Biological Signaling
[Communication]

Coming soon.

Main-Group Chemistry

Christian Marquardt, Oliver Hegen, Matthias Hautmann, Gábor Balázs, Michael Bodensteiner, Alexander V. Virovets, Alexey Y. Timoshkin, Manfred Scheer*

Isolation and Characterization of Lewis Base Stabilized Monomeric Parent Stibanylboranes
[Communication]

Coming soon.

C–H Activation

Liangbin Huang, Dagmar Hackenberger, Lukas J. Gooßen*

Iridium-Catalyzed ortho-Arylation of Benzoic Acids with Arenediazonium Salts
[Communication]

Published online on September 3, 2015.
DOI: 10.1002/anie.201505769

Aromaticity

Yang Zheng, Jiao Xiong, Yangyang Sun, Xiaobo Pan*, Jincai Wu*

Stepwise Reduction of 9,10-Bis(dimesitylboryl)anthracene
[Communication]

Coming soon.

Bioinorganic Chemistry

Lydia M. Peschel, Ferdinand Belaj, Nadia C. Mösch-Zanetti*

Towards Structural-Functional Mimics of Acetylene Hydratase: Reversible Activation of Acetylene using a Biomimetic Tungsten Complex
[Communication]

Coming soon.

Metal–Metal Interactions

Andrea Cebollada, Alba Vellé, Manuel Iglesias, Lauren B. Fullmer, Sara Goberna-Ferrón, May Nyman*, Pablo J. Sanz Miguel*

Direct X-Ray Scattering Evidence for Metal–Metal Interactions in Solution at the Molecular Level
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201505736

Structural Virology

Alvaro Mallagaray, Julia Lockhauserbäumer, Grant Hansman, Charlotte Uetrecht, Thomas Peters*

Attachment of Norovirus to Histo Blood Group Antigens: A Cooperative Multistep Process
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201505672

Iron Heterocubanes

Crispin Lichtenberg*, Inés Garcia Rubio, Liliana Viciu, Mario Adelhardt, Karsten Meyer, Gunnar Jeschke, Hansjörg Grützmacher*

A Low-Valent Iron Imido Heterocubane Cluster: Reversible Electron Transfer and Catalysis of Selective C–C Couplings
[Communication]

Coming soon.

Cycloaddition

Samuel Suárez-Pantiga[WWW], Kilian Colas, Magnus J. Johansson, Abraham Mendoza*

Scalable Synthesis of Piperazines Enabled by Visible-Light Irradiation and Aluminum Organometallics
[Communication]

Coming soon.

Silylamide Complexes

Michelle Faust, Aimee M. Bryan, Akseli Mansikkamäki, Petra Vasko, Marilyn M. Olmstead, Heikki M. Tuononen*, Fernande Grandjean, Gary J. Long, Philip P. Power*

The Instability of Ni{N(SiMe3)2}2: A Fifty Year Old Transition Metal Silylamide Mystery
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201505518

Thermoelectrics

Ran Ang*, Atta Ullah Khan, Naohito Tsujii, Ken Takai, Ryuhei Nakamura*, Takao Mori*

Thermoelectricity Generation and Electron–Magnon Scattering in a Natural Chalcopyrite Mineral from a Deep-Sea Hydrothermal Vent
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201505517

Membrane Proteins

Shakeel A. Shahid, Madhu Nagaraj, Nandini Chauhan, Trent W. Franks, Benjamin Bardiaux, Michael Habeck, Marcella Orwick-Rydmark, Dirk Linke*, Barth-J. van Rossum*

Solid-state NMR Study of the YadA Membrane-Anchor Domain in the Bacterial Outer Membrane
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201505506

Tuberculosis

Peter Leidinger, Jens Treptow, Kristine Hagens, Jacqueline Eich, Nicole Zehethofer, Dominik Schwudke, Wulf Oehlmann, Heinrich Lünsdorf, Oliver Goldmann, Ulrich E. Schaible*, Kurt E. J. Dittmar*, Claus Feldmann*

Isoniazid@Fe2O3 Nanocontainers and Their Antibacterial Effect on Tuberculosis Mycobacteria
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201505493

Synthetic Methods

Chun-Hua Yang, Yu-Shi Zhang, Wen-Wen Fan, Gong-Qing Liu, Yue-Ming Li*

Intramolecular Aminoboration of Unfunctionalized Olefins
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201505489

Boron Monolayers

Zhuhua Zhang, Yang Yang, Guoying Gao, Boris I. Yakobson*

Two-Dimensional Boron Monolayers Mediated by Metal Substrates
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201505425

Protein Synthesis

Chunmao He, Sameer S. Kulkarni, Frédéric Thuaud[WWW], Jeffrey W. Bode*

Chemical Synthesis of the 20 kDa Heme Protein Nitrophorin 4 by α-Ketoacid-Hydroxylamine (KAHA) Ligation
[Communication]

Coming soon.

Chiral Discrimination

Ahmad Masarwa, Dennis Gerbig, Liron Oskar, Aharon Loewenstein, Hans Peter Reisenauer, Philippe Lesot*, Peter R. Schreiner*, Ilan Marek*

Synthesis and Stereochemical Assignment of Crypto-Optically Active 2H6-Neopentane
[Communication]
(VIP - Read Abstract)

Coming soon.

Heterocycles

Xiaoxun Li, Hui Li, Wangze Song, Po-Sen Tseng, Lingyan Liu*, Ilia A. Guzei, Weiping Tang*

Divergent Reactivity of Rhodium(I) Carbenes Derived from Indole Annulations
[Communication]

Coming soon.

Electrochemistry

Renata Balgley, Sreejith Shankar, Michal Lahav*, Milko E. van der Boom*

Rerouting Electron Transfer in Molecular Assemblies by Redox-Pair Matching
[Communication]

Coming soon.

Hollow Nanoparticles

Longyu Li, Conghui Yuan, Dongming Zhou, Alexander E. Ribbe, Kevin R. Kittilstved, S. Thayumanavan*

Utilizing Reversible Interactions in Polymeric Nanoparticles to Generate Hollow Metal–Organic Nanoparticles
[Communication]

Coming soon.

Mesoporous Metals

Yunqi Li[WWW], Bishnu Prasad Bastakoti*, Victor Malgras, Cuiling Li, Jing Tang, Jung Ho Kim, Yusuke Yamauchi*

Polymeric Micelle Assembly for the Smart Synthesis of Mesoporous Platinum Nanospheres with Tunable Pore Sizes
[Communication]

Coming soon.

Peptide Coupling

Jing Li[WWW], Martin J. Lear, Yuya Kawamoto, Shigenobu Umemiya, Alice R. Wong, Eunsang Kwon, Itaru Sato, Yujiro Hayashi*

Oxidative Amidation of Nitroalkanes with Amine Nucleophiles using Molecular Oxygen and Iodine
[Communication]

Coming soon.

Biosensors

Simona Ranallo, Marianna Rossetti, Kevin W. Plaxco, Alexis Vallée-Bélisle*, Francesco Ricci*

A Modular, DNA-Based Beacon for Single-Step Fluorescence Detection of Antibodies and Other Proteins
[Communication]

Coming soon.

Self-Propelled Devices

Murat Uygun, Virendra V. Singh, Kevin Kaufmann, Deniz A. Uygun, Severina D. S. de Oliveira, Joseph Wang*

Micromotor-Based Biomimetic Carbon Dioxide Sequestration: Towards Mobile Microscrubbers
[Communication]

Coming soon.

Halogenation

Sylvie Dérien*, Hubert Klein, Christian Bruneau

Selective Ruthenium-Catalyzed Hydrochlorination of Alkynes: One-Step Synthesis of Vinylchlorides
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201505144

Single-Molecule Microscopy

Martin Lehmann*, Benjamin Gottschalk, Dmytro Puchkov, Peter Schmieder, Sergej Schwagerus, Christian P. R. Hackenberger, Volker Haucke, Jan Schmoranzer*

Multicolor Caged dSTORM Resolves the Ultrastructure of Synaptic Vesicles in the Brain
[Communication]

Coming soon.

Amyloid Inhibitors

Erika Andreetto, Eleni Malideli, Li-Mei Yan, Michael Kracklauer, Karine Farbiarz, Marianna Tatarek-Nossol, Gerhard Rammes, Elke Prade, Tatjana Neumüller, Andrea Caporale, Anna Spanopoulou, Maria Bakou, Bernd Reif, Aphrodite Kapurniotu*

A Hot-Segment-Based Approach for the Design of Cross-Amyloid Interaction Surface Mimics as Inhibitors of Amyloid Self-Assembly
[Communication]

Coming soon.

Surface Functionalization

Guillaume Delaittre*, Anja S. Goldmann, Jan O. Mueller, Christopher Barner-Kowollik*

Efficient Photochemical Approaches for Spatially Resolved Surface Functionalization
[Review]

Published online on September 2, 2015.
DOI: 10.1002/anie.201504920

Nuclear Forensics

Klaus Mayer, Maria Wallenius*, Klaus Lützenkirchen, Joan Horta, Adrian Nicholl, Gert Rasmussen, Pieter van Belle, Zsolt Varga, Razvan Buda, Nicole Erdmann, Jens-Volker Kratz, Norbert Trautmann, L. Keith Fifield, Stephen G. Tims, Michaela B. Fröhlich, Peter Steier

Uranium from German Nuclear Power Projects of the 1940s— A Nuclear Forensic Investigation
[Communication]

Coming soon.

Phosphorous Compounds

Jonathan Wong, Yongxin Li, Yanwei Hao, Rongqiang Tian*, François Mathey*

Isomerization of Secondary Phosphirane into Terminal Phosphinidene Complexes: An Analogy between Monovalent Phosphorus and Transition Metals
[Communication]

Coming soon.

Polymerization

Andrew W. Baggett, Fang Guo, Bo Li, Shih-Yuan Liu*, Frieder Jäkle*

Regioregular Synthesis of Azaborine Oligomers and a Polymer with a syn Conformation Stabilized by N–H···π Interactions
[Communication]

Coming soon.

Unconventional Retrosynthesis

Yoshihiro Ueda, Takumi Furuta, Takeo Kawabata*

Final-Stage Site-Selective Acylation for the Total Syntheses of Multifidosides A–C
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201504729

Surface Reactions

Qibo Deng*, Varun Gopal, Dr. Jörg Weissmüller

Less Noble or More Noble: How Strain Affects the Binding of Oxygen on Gold
[Communication]

Coming soon.

Cobalt Catalysts

Jongwoo Han, Young Jin Sa, Yeonjun Shim, Min Choi, Noejung Park, Sang Hoon Joo*, Sungjin Park*

Coordination Chemistry of [Co(acac)2] with N-Doped Graphene: Implications for Oxygen Reduction Reaction Reactivity of Organometallic Co-O4-N Species
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201504707

Core/Shell Nanoparticles

Di Yang, Xinchang Pang, Yanjie He, Yiquan Wang, Genxiang Chen, Wenzhong Wang, Zhiqun Lin*

Precisely Size-Tunable Magnetic/Plasmonic Core/Shell Nanoparticles with Controlled Optical Properties
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201504676

Protein Ligation

Lara R. Malins[WWW], Nicholas J. Mitchell, Sheena McGowan, Richard J. Payne*

Oxidative Deselenization of Selenocysteine: Applications for Programmed Ligation at Serine
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201504639

Photophysics

Kyu Hyung Park, Pyosang Kim, Woojae Kim, Hideyuki Shimizu, Minwoo Han, Eunji Sim*, Masahiko Iyoda*, Dongho Kim*

Excited-State Dynamic Planarization of Cyclic Oligothiophenes in the Vicinity of a Ring-to-Linear Excitonic Behavioral Turning Point
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201504588

NMR Spectroscopy

Nilamoni Nath, Edward J. d´Auvergne, Christian Griesinger*

Long-Range Residual Dipolar Couplings: A Tool for Determining the Configuration of Small Molecules
[Communication]

Coming soon.

Antibiotics

Luke A. Clifton, Stephen A. Holt, Arwel V. Hughes, Emma L. Daulton, Wanatchaporn Arunmanee, Frank Heinrich, Syma Khalid, Damien Jefferies, Timothy R. Charlton, John R. P. Webster, Christian J. Kinane, Jeremy H. Lakey*

An Accurate In Vitro Model of the E. coli Envelope
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201504287

Metal–Organic Frameworks

Jian Yang, Fengjun Zhang, Haiyuan Lu, Xun Hong, Hailong Jiang, Yuen Wu*, Yadong Li*

Hollow Zn/Co ZIF Particles Derived from Core–Shell ZIF-67@ZIF-8 as Selective Catalyst for the Semi-Hydrogenation of Acetylene
[Communication]

Published online on September 2, 2015.
DOI: 10.1002/anie.201504242

Molecular Switches

Benedikt Rösner[WWW], Magdalena Milek, Alexander Witt, Benoît Gobaut, Piero Torelli, Rainer H. Fink*, Marat M. Khusniyarov*

Reversible Photoswitching of a Spin-Crossover Molecular Complex in the Solid State at Room Temperature
[Communication]

Coming soon.

Systems Chemistry

Rakesh Mukherjee, Rivka Cohen-Luria, Nathaniel Wagner, Gonen Ashkenasy*

A Bistable Switch in Dynamic Thiodepsipeptide Folding and Template-Directed Ligation
[Communication]

Coming soon.

Homogeneous Catalysis

Julia R. Khusnutdinova, David Milstein*

Metal–Ligand Cooperation
[Review]

Coming soon.

Zeolites

Stijn Van de Vyver[WWW], Yuriy Román-Leshkov*

Metalloenzyme-Like Zeolites as Lewis Acid Catalysts for C–C Bond Formation
[Minireview]

Published online on September 3, 2015.
DOI: 10.1002/anie.201503701

Biosynthesis

Sheng Huang, Jioji Tabudravu, Somayah S. Elsayed, Jeanne Travert, Doe Peace, Ming Him Tong, Kwaku Kyeremeh, Sharon M. Kelly, Laurent Trembleau, Rainer Ebel, Marcel Jaspars, Yi Yu*, Hai Deng*

Discovery of a Single Monooxygenase that Catalyzes Carbamate Formation and Ring Contraction in the Biosynthesis of the Legonmycins
[Communication]

Coming soon.

Small-Ring Systems

Yao Xu, Michael L. Conner, M. Kevin Brown*

Cyclobutane and Cyclobutene Synthesis: Catalytic Enantioselective [2+2] Cycloadditions
[Minireview]

Published online on September 2, 2015.
DOI: 10.1002/anie.201502815

Reaction Intermediates

Yasuaki Yamanaka, Yuki Kato, Koichi Hashimoto, Keisuke Iida, Kazuo Nagasawa, Hiroshi Nakayama, Naoshi Dohmae, Keiichi Noguchi, Takumi Noguchi, Masafumi Yohda, Masafumi Odaka*

Time-Resolved Crystallography of the Reaction Intermediate of Nitrile Hydratase: Revealing a Role for the Cysteinesulfenic Acid Ligand as a Catalytic Nucleophile
[Communication]
(VIP) title=

Published online on September 2, 2015.
DOI: 10.1002/anie.201502731

Solar Energy Conversion

Vincenzo Balzani*, Giacomo Bergamini, Paola Ceroni

Light: A Very Peculiar Reactant and Product
[Essay]

Published online on September 2, 2015.
DOI: 10.1002/anie.201502325

Zintl Cluster Compounds

Christian B. Benda, Markus Waibel, Thomas F. Fässler*

On the Formation of Intermetalloid Clusters: Titanocene(III)diammin as a Versatile Reactant Toward Nonastannide Zintl Clusters
[Communication]

Coming soon.

Binary Superlattices

Sung-Hwan Lim[WWW], Hyung-Sik Jang, Jae-Min Ha, Tae-Hwan Kim, Pawel Kwasniewski, Theyencheri Narayanan, Kyeong Sik Jin, Sung-Min Choi*

Highly Ordered and Highly Aligned Two-Dimensional Binary Superlattice of a SWNT/Cylindrical-Micellar System
[Communication]

Coming soon.

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