Angewandte Chemie International Edition

Cover image for Vol. 56 Issue 10

Chefredakteur: Peter Gölitz, Stellvertreter: Neville Compton, Haymo Ross

Online ISSN: 1521-3773

Associated Title(s): Angewandte Chemie, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemistryOpen, ChemPhotoChem, ChemPlusChem, Zeitschrift für Chemie

Articles Coming Soon

Here's a selection of upcoming papers. Also see the EarlyView page for the latest papers published online.

Natural Product Synthesis

Lingying Leng, Xiaohan Zhou, Qi Liao, Falu Wang, Hao Song*, Dan Zhang, Xiao-Yu Liu, Yong Qin*

Asymmetric Total Syntheses of Kopsia Indole Alkaloids
[Communication]

Published online on February 23, 2017.
DOI: 10.1002/anie.201700831

New Polymers: Beautiful Structures, But How Can We Bring Them to the Market?
[Editorial]

Brigitte Voit*

Published online on February 20, 2017.
DOI: 10.1002/anie.201700811

Small-Molecule Activation

Zhenbo Mo, Tibor Szilvási, Yu-Peng Zhou, Shenglai Yao, Matthias Driess*

An Intramolecular Silylene Borane Capable of Facile Activation of Small Molecules, Including Metal-Free Dehydrogenation of Water
[Communication]

Coming soon.

Expanded Porphyrins

Takanori Soya, Hirotaka Mori, Yongseok Hong, Yun Hee Koo, Dongho Kim*, Atsuhiro Osuka*

Internally 2,5-Thienylene-Bridged [46]Decaphyrin: (Annuleno)annulene Network Consisting of Möbius Aromatic Thia[28]hexaphyrins and Strong Hückel Aromaticity of its Protonated Form
[Communication]

Coming soon.

Heterogeneous Catalysis

Elena Pérez-Gallent, Marta C. Figueiredo, Federico Calle-Vallejo*, Marc T. M. Koper*

Spectroscopic Observation of a Hydrogenated CO Dimer Intermediate During CO Reduction on Cu(100) Electrodes
[Communication]

Published online on February 23, 2017.
DOI: 10.1002/anie.201700580

Solid-State NMR Spectroscopy

Jiasheng Lu, Ivan Hung, Andreas Brinkmann, Zhehong Gan, Xianqi Kong, Gang Wu*

Solid-State 17O NMR Reveals Hydrogen-Bonding Energetics: Not All Low-Barrier Hydrogen Bonds Are Strong
[Communication]

Published online on February 22, 2017.
DOI: 10.1002/anie.201700488

Nanophotonics

Yi Zhang, Qing Liao*, Xinguo Wang, Jiannian Yao, Hongbing Fu*

Lattice-Matched Epitaxial Growth of Organic Heterostructures for Integrated Optoelectronic Application
[Communication]

Coming soon.

Chemical Vapor Transport

Dake Hu, Guanchen Xu, Lei Xing, Xingxu Yan, Jingyi Wang, Jingying Zheng, Zhixing Lu, Peng Wang, Xiaoqing Pan, Liying Jiao*

Two-Dimensional Semiconductors Grown by Chemical Vapor Transport
[Communication]

Published online on February 21, 2017.
DOI: 10.1002/anie.201700439

Palladium Catalysts

Jonathan N. Jaworski, Scott D. McCann, Ilia A. Guzei, Shannon S. Stahl*

Detection of Palladium(I) in Aerobic Oxidation Catalysis
[Communication]

Published online on February 20, 2017.
DOI: 10.1002/anie.201700345

Metallacycles

Stephan M. Rummelt, Gui-Juan Cheng, Puneet Gupta, Walter Thiel, Alois Fürstner*

Hydroxy-Directed Ruthenium-Catalyzed Alkene/Alkyne Coupling: Increased Scope, Stereochemical Implications, and Mechanistic Rationale
[Communication]

Published online on February 23, 2017.
DOI: 10.1002/anie.201700342

Organocatalysis

Ping Chen, Kai Wang, Wengang Guo, Xianghui Liu, Yan Liu*, Can Li*

Enantioselective Reactions of 2-Sulfonylalkyl Phenols with Allenic Esters: Dynamic Kinetic Resolution and [4+2] Cycloaddition Involving ortho-Quinone Methide Intermediates
[Communication]

Coming soon.

Organocatalysis

Xiangbin Bai, Guangkuo Zeng, Tianju Shao, Zhiyong Jiang*

Catalytic Enantioselective γ-Selective Additions of 2-Allylazaarenes to Activated Ketones
[Communication]

Coming soon.

Natural Product Synthesis

Hiu C. Lam, Henry P. Pepper, Christopher J. Sumby, Jonathan H. George*

Biomimetic Total Synthesis of (±)-Verrubenzospirolactone
[Communication]

Published online on February 22, 2017.
DOI: 10.1002/anie.201700114

Asymmetric Synthesis

Erin E. Stache, Tomislav Rovis*, Abigail G. Doyle*

Dual Nickel- and Photoredox-Catalyzed Enantioselective Desymmetrization of Cyclic meso-Anhydrides
[Communication]

Published online on February 23, 2017.
DOI: 10.1002/anie.201700097

Photoredox Catalysis

Adrian Tlahuext-Aca, R. Aleyda Garza-Sanchez, Frank Glorius*

Multicomponent Oxyalkylation of Styrenes Enabled by Hydrogen-Bond-Assisted Photoinduced Electron Transfer
[Communication]

Published online on February 21, 2017.
DOI: 10.1002/anie.201700049

Electrocatalysis

Hongwen Huang, Huanhuan Jia, Zhao Liu, Pengfei Gao, Jiangtao Zhao, Zhenlin Luo, Jinlong Yang*, Jie Zeng*

Understanding of Strain Effect in Electrochemical Reduction of CO2: Using Pd Nanostructures as an Ideal Platform
[Communication]
(VIP) title=

Published online on February 20, 2017.
DOI: 10.1002/anie.201612617

Rhodium Catalysis

Soichi Yoshizaki[WWW], Yu Shibata*, Ken Tanaka*

Fulvene Synthesis by Rhodium(I)-Catalyzed [2+2+1] Cycloaddition: Synthesis and Catalytic Activity of Tunable Cyclopentadienyl Rhodium(III) Complexes with Pendant Amides
[Communication]

Published online on February 20, 2017.
DOI: 10.1002/anie.201612590

Iron Cluster Catalysis

Tim N. Gieshoff, Uttam Chakraborty, Matteo Villa, Axel Jacobi von Wangelin*

Alkene Hydrogenations by Soluble Iron Nanocluster Catalysts
[Communication]

Coming soon.

Energetic Materials

David E. Chavez*, Damon A. Parrish, Lauren Mitchell, Greg H. Imler

Azido and Tetrazolo 1,2,4,5-Tetrazine N-Oxides
[Communication]

Published online on February 23, 2017.
DOI: 10.1002/anie.201612496

Host–Guest Interactions

Keisuke Jono, Akira Suzuki, Munetaka Akita, Ken Albrecht, Kimihisa Yamamoto, Michito Yoshizawa*

A Polyaromatic Molecular Clip That Enables the Binding of Planar, Tubular, and Dendritic Compounds
[Communication]

Published online on February 22, 2017.
DOI: 10.1002/anie.201612489

Metal-Free C–C Coupling

Dilip V. Patil, Seung Woo Kim, Quynh H. Nguyen, Hanbyul Kim, Shan Wang, Tuan Hoang, Seunghoon Shin*

Brønsted Acid-Catalyzed Oxygenative Bimolecular Friedel–Crafts-type Coupling of Ynamides
[Communication]

Published online on February 23, 2017.
DOI: 10.1002/anie.201612471

Hypervalent Compounds

Muhammet Uyanik[WWW], Tatsuya Mutsuga, Kazuaki Ishihara*

4,5-Dimethyl-2-Iodoxybenzenesulfonic Acid Catalyzed Site-Selective Oxidation of 2-Substituted Phenols to 1,2-Quinols
[Communication]

Published online on February 21, 2017.
DOI: 10.1002/anie.201612463

NMR Spectroscopy

Eduardo Troche-Pesqueira, Clemens Anklin, Roberto R. Gil*, Armando Navarro-Vázquez*

Computer-Assisted 3D Structure Elucidation of Natural Products using Residual Dipolar Couplings
[Communication]

Coming soon.

Superbases

Julius F. Kögel, Davor Margetić, Xiulan Xie, Lars H. Finger, Jörg Sundermeyer*

A Phosphorus Bisylide: Exploring a New Class of Superbases with Two Interacting Carbon Atoms as Basicity Centers
[Communication]

Published online on February 23, 2017.
DOI: 10.1002/anie.201612446

Single-Molecule Electrochemistry

Weichun Zhang, Martín Caldarola, Biswajit Pradhan, Michel Orrit*

Gold Nanorod-Enhanced Fluorescence Enables Single-Molecule Electrochemistry of Methylene Blue
[Communication]

Published online on February 23, 2017.
DOI: 10.1002/anie.201612389

Cyanides

Angel L. Fuentes de Arriba, Elena Lenci, Mahendra Sonawane, Odilon Formery, Darren J. Dixon*

Iridium-Catalyzed Reductive Strecker Reaction for Late-Stage Amide and Lactam Cyanation
[Communication]
(VIP - Read Abstract)

Coming soon.

Olefin Functionalization

Wujun Jian, Liang Ge, Yihang Jiao, Bo Qian, Hongli Bao*

Iron-Catalyzed Decarboxylative Alkyl Etherification of Vinylarenes with Aliphatic Acids as the Alkyl Source
[Communication]

Published online on February 23, 2017.
DOI: 10.1002/anie.201612365

Synthetic Methods

Xin Yan, Heyong Cheng, Richard N. Zare*

Two-Phase Reactions in Microdroplets without the Use of Phase-Transfer Catalysts
[Communication]
(VIP) title=

Published online on February 22, 2017.
DOI: 10.1002/anie.201612308

Hybrid Microcontainers

Ying Cong, Qiuju Li, Min Chen, Limin Wu*

Synthesis of Dual-Stimuli-Responsive Microcontainers with Two Payloads in Different Storage Spaces for Preprogrammable Release
[Communication]

Published online on February 21, 2017.
DOI: 10.1002/anie.201612291

CO2 Reduction

Bijandra Kumar, Veerendra Atla, J. Patrick Brian, Sudesh Kumari, Tu Quang Nguyen, Mahendra Sunkara, Joshua M. Spurgeon*

Reduced SnO2 Porous Nanowires with a High Density of Grain Boundaries as Catalysts for Efficient Electrochemical CO2-into-HCOOH Conversion
[Communication]

Published online on February 23, 2017.
DOI: 10.1002/anie.201612194

Antibiotic Resistance

Martine I. Abboud, Philip Hinchliffe, Jürgen Brem, Robert Macsics, Inga Pfeffer, Anne Makena, Klaus-Daniel Umland, Anna M. Rydzik, Guo-Bo Li, James Spencer, Timothy D. W. Claridge*, Christopher J. Schofield*

19F-NMR Reveals the Role of Mobile Loops in Product and Inhibitor Binding by the São Paulo Metallo-β-Lactamase
[Communication]

Coming soon.

F···F Interactions

Javix Thomas, Nathan A. Seifert, Wolfgang Jäger, Yunjie Xu*

A Direct Link from the Gas to the Condensed Phase: A Rotational Spectroscopic Study of 2,2,2-Trifluoroethanol Trimers
[Communication]

Published online on February 23, 2017.
DOI: 10.1002/anie.201612161

Antibiotics

T. Vu Nguyen, Meghan S. Blackledge, Erick A. Lindsey, Bradley M. Minrovic, David F. Ackart, Albert B. Jeon, Andrés Obregón-Henao, Roberta J. Melander, Randall J. Basaraba*, Christian Melander*

The Discovery of 2-Aminobenzimidazoles That Sensitize Mycobacterium smegmatis and M. tuberculosis to β-Lactam Antibiotics in a Pattern Distinct from β-Lactamase Inhibitors
[Communication]

Coming soon.

Halogen Bonds

Yunteng He, Jie Zhang, Lei Lei, Wei Kong*

Self-Assembly of Iodine in Superfluid Helium Droplets: Halogen Bonds and Nanocrystals
[Communication]

Published online on February 21, 2017.
DOI: 10.1002/anie.201611922

Medicinal Chemistry

Jonathan Pettinger, Yann-Vaï Le Bihan, Marcella Widya, Rob L. M. van Montfort, Keith Jones, Matthew D. Cheeseman*

An Irreversible Inhibitor of HSP72 that Unexpectedly Targets Lysine-56
[Communication]

Published online on February 22, 2017.
DOI: 10.1002/anie.201611907

Photochemistry

Jing Guo, Yao-Wei Xu, Kang Li, Li-Min Xiao, Sha Chen, Kai Wu, Dr. Xu-Dong Chen, Yan-Zhong Fan, Jun-Min Liu*, Cheng-Yong Su*

Regio- and Enantioselective Photodimerization within the Confined Space of a Homochiral Ruthenium/Palladium Heterometallic Coordination Cage
[Communication]

Coming soon.

Main-Group Chemistry

Ricardo Rodriguez[WWW], David Gau, Jérémy Saouli, Antoine Baceiredo*, Nathalie Saffon-Merceron, Vicenç Branchadell, Tsuyoshi Kato*

A Stable Monomeric SiO2 Complex with Donor–Acceptor Ligands
[Communication]

Coming soon.

Graphene Nanoribbons

Maxime Daigle, Dandan Miao, Andrea Lucotti, Matteo Tommasini, Jean-François Morin*

Helically Coiled Graphene Nanoribbons
[Communication]
(VIP - Read Abstract)

Coming soon.

Methane Activation

Fanglin Che, Su Ha*, Jean-Sabin McEwen*

Catalytic Reaction Rates Controlled by Metal Oxidation State: C–H Bond Cleavage in Methane over Nickel-Based Catalysts
[Communication]

Coming soon.

Water-Based NMR Spectroscopy

Ricardo P. Martinho, Mihajlo Novakovic, Gregory L. Olsen, Lucio Frydman*

Heteronuclear 1D and 2D NMR Resonances Detected by Chemical Exchange Saturation Transfer to Water
[Communication]

Coming soon.

Proton-Coupled Electron Transfer

Tarali Devi, Yong-Min Lee, Jieun Jung, Muniyandi Sankaralingam, Wonwoo Nam*, Shunichi Fukuzumi*

A Chromium(III)-Superoxo Complex as a Three-Electron Oxidant with a Large Tunneling Effect in Multi-Electron Oxidation of NADH Analogues
[Communication]

Coming soon.

Electrophilic C–H Borylation

Qin Yin[WWW], Hendrik F. T. Klare*, Martin Oestreich*

Catalytic Friedel–Crafts C–H Borylation of Electron-Rich Arenes: Dramatic Rate Acceleration by Added Alkenes
[Communication]

Coming soon.

Gas-Phase Reactions

Li-Xue Jiang, Chongyang Zhao, Xiao-Na Li*, Hui Chen*, Sheng-Gui He*

Formation of Gas-Phase Formate in Thermal Reactions of Carbon Dioxide with Diatomic Iron Hydride Anions
[Communication]
(VIP - Read Abstract)

Coming soon.

Homogeneous Catalysis

Nurbey Gulia, Olafs Daugulis*

Palladium-Catalyzed Pyrazole-Directed sp3 C–H Bond Arylation for the Synthesis of β-Phenethylamines
[Communication]

Coming soon.

NMR Spectroscopy

Maria Vinaixa*, Miguel A. Rodríguez, Suvi Aivio, Jordi Capellades, Josep Gómez, Nicolau Canyellas, Travis H. Stracker, Oscar Yanes*

Positional Enrichment by Proton Analysis (PEPA): A One-Dimensional 1H-NMR Approach for 13C Stable Isotope Tracer Studies in Metabolomics
[Communication]

Published online on February 21, 2017.
DOI: 10.1002/anie.201611347

Photoanodes

Chengcheng Li, Ang Li, Zhibin Luo, Jijie Zhang, Xiaoxia Chang, Zhiqi Huang, Tuo Wang*, Jinlong Gong*

Surviving High-Temperature Calcination: ZrO2-Induced Hematite Nanotubes for Photoelectrochemical Water Oxidation
[Communication]

Published online on February 21, 2017.
DOI: 10.1002/anie.201611330

Peptide Cyclization

Weidong Liu, Yiwu Zheng, Xudong Kong, Christian Heinis, Yibing Zhao, Chuanliu Wu*

Precisely Regulated and Efficient Locking of Linear Peptides into Stable Multicyclic Topologies through a One-Pot Reaction
[Communication]

Coming soon.

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