Angewandte Chemie International Edition

Cover image for Vol. 56 Issue 10

Editor: Peter Gölitz, Deputy Editors: Neville Compton, Haymo Ross

Online ISSN: 1521-3773

Associated Title(s): Angewandte Chemie, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemistryOpen, ChemPhotoChem, ChemPlusChem, Zeitschrift für Chemie

Articles Coming Soon

Here's a selection of upcoming papers. Also see the EarlyView page for the latest papers published online.

Natural Product Synthesis

Lingying Leng, Xiaohan Zhou, Qi Liao, Falu Wang, Hao Song*, Dan Zhang, Xiao-Yu Liu, Yong Qin*

Asymmetric Total Syntheses of Kopsia Indole Alkaloids
[Communication]

Coming soon.

New Polymers: Beautiful Structures, But How Can We Bring Them to the Market?
[Editorial]

Brigitte Voit*

Published online on February 20, 2017.
DOI: 10.1002/anie.201700811

Thermal Conductivity

Mattia Sist, Karl Frederik Færch Fischer, Hidetaka Kasai, Bo Brummerstedt Iversen*

Low-Temperature Anharmonicity in Cesium Chloride (CsCl)
[Communication]

Published online on February 17, 2017.
DOI: 10.1002/anie.201700638

Small-Molecule Activation

Zhenbo Mo, Tibor Szilvási, Yu-Peng Zhou, Shenglai Yao, Matthias Driess*

An Intramolecular Silylene Borane Capable of Facile Activation of Small Molecules, Including Metal-Free Dehydrogenation of Water
[Communication]

Coming soon.

Expanded Porphyrins

Takanori Soya, Hirotaka Mori, Yongseok Hong, Yun Hee Koo, Dongho Kim*, Atsuhiro Osuka*

Internally 2,5-Thienylene-Bridged [46]Decaphyrin: (Annuleno)annulene Network Consisting of Möbius Aromatic Thia[28]hexaphyrins and Strong Hückel Aromaticity of its Protonated Form
[Communication]

Coming soon.

Heterogeneous Catalysis

Elena Pérez-Gallent, Marta C. Figueiredo, Federico Calle-Vallejo*, Marc T. M. Koper*

Spectroscopic Observation of a Hydrogenated CO Dimer Intermediate During CO Reduction on Cu(100) Electrodes
[Communication]

Coming soon.

Cross-Coupling

Qi Yang[WWW], Long Zhang, Chen Ye, Sanzhong Luo*, Li-Zhu Wu*, Chen-Ho Tung

Visible-Light-Promoted Asymmetric Cross-Dehydrogenative Coupling of Tertiary Amines to Ketones by Synergistic Multiple Catalysis
[Communication]

Published online on February 17, 2017.
DOI: 10.1002/anie.201700572

Solid-State NMR Spectroscopy

Jiasheng Lu, Ivan Hung, Andreas Brinkmann, Zhehong Gan, Xianqi Kong, Gang Wu*

Solid-State 17O NMR Reveals Hydrogen-Bonding Energetics: Not All Low-Barrier Hydrogen Bonds Are Strong
[Communication]

Coming soon.

Chemical Vapor Transport

Dake Hu, Guanchen Xu, Lei Xing, Xingxu Yan, Jingyi Wang, Jingying Zheng, Zhixing Lu, Peng Wang, Xiaoqing Pan, Liying Jiao*

Two-Dimensional Semiconductors Grown by Chemical Vapor Transport
[Communication]

Published online on February 21, 2017.
DOI: 10.1002/anie.201700439

Palladium Catalysts

Jonathan N. Jaworski, Scott D. McCann, Ilia A. Guzei, Shannon S. Stahl*

Detection of Palladium(I) in Aerobic Oxidation Catalysis
[Communication]

Published online on February 20, 2017.
DOI: 10.1002/anie.201700345

Metallacycles

Stephan M. Rummelt, Gui-Juan Cheng, Puneet Gupta, Walter Thiel, Alois Fürstner*

Hydroxy-Directed Ruthenium-Catalyzed Alkene/Alkyne Coupling: Increased Scope, Stereochemical Implications, and Mechanistic Rationale
[Communication]

Coming soon.

Nanotechnology

Emily L. Kynaston, Yuan Fang, Joseph G. Manion, Nimrat K. Obhi, Jane Y. Howe, Dmitrii F. Perepichka*, Dwight S. Seferos*

Patchy Nanofibers from the Thin Film Self-Assembly of a Conjugated Diblock Copolymer
[Communication]

Published online on February 16, 2017.
DOI: 10.1002/anie.201700134

Natural Product Synthesis

Hiu C. Lam, Henry P. Pepper, Christopher J. Sumby, Jonathan H. George*

Biomimetic Total Synthesis of (±)-Verrubenzospirolactone
[Communication]

Coming soon.

Asymmetric Synthesis

Erin E. Stache, Tomislav Rovis*, Abigail G. Doyle*

Dual Nickel- and Photoredox-Catalyzed Enantioselective Desymmetrization of Cyclic meso-Anhydrides
[Communication]

Coming soon.

Homogeneous Catalysis

Xi-Jie Dai, Haining Wang, Chao-Jun Li*

Carbonyls as Latent Alkyl Carbanions for Conjugate Additions
[Communication]

Published online on February 17, 2017.
DOI: 10.1002/anie.201700059

Photoredox Catalysis

Adrian Tlahuext-Aca, R. Aleyda Garza-Sanchez, Frank Glorius*

Multicomponent Oxyalkylation of Styrenes Enabled by Hydrogen-Bond-Assisted Photoinduced Electron Transfer
[Communication]

Published online on February 21, 2017.
DOI: 10.1002/anie.201700049

Electrocatalysis

Hongwen Huang, Huanhuan Jia, Zhao Liu, Pengfei Gao, Jiangtao Zhao, Zhenlin Luo, Jinlong Yang*, Jie Zeng*

Understanding of Strain Effect in Electrochemical Reduction of CO2: Using Pd Nanostructures as an Ideal Platform
[Communication]
(VIP) title=

Published online on February 20, 2017.
DOI: 10.1002/anie.201612617

Rhodium Catalysis

Soichi Yoshizaki[WWW], Yu Shibata*, Ken Tanaka*

Fulvene Synthesis by Rhodium(I)-Catalyzed [2+2+1] Cycloaddition: Synthesis and Catalytic Activity of Tunable Cyclopentadienyl Rhodium(III) Complexes with Pendant Amides
[Communication]

Published online on February 20, 2017.
DOI: 10.1002/anie.201612590

Energetic Materials

David E. Chavez*, Damon A. Parrish, Lauren Mitchell, Greg H. Imler

Azido and Tetrazolo 1,2,4,5-Tetrazine N-Oxides
[Communication]

Coming soon.

Host–Guest Interactions

Keisuke Jono, Akira Suzuki, Munetaka Akita, Ken Albrecht, Kimihisa Yamamoto, Michito Yoshizawa*

A Polyaromatic Molecular Clip That Enables the Binding of Planar, Tubular, and Dendritic Compounds
[Communication]

Coming soon.

Metal-Free C–C Coupling

Dilip V. Patil, Seung Woo Kim, Quynh H. Nguyen, Hanbyul Kim, Shan Wang, Tuan Hoang, Seunghoon Shin*

Brønsted Acid-Catalyzed Oxygenative Bimolecular Friedel–Crafts-type Coupling of Ynamides
[Communication]

Coming soon.

Hypervalent Compounds

Muhammet Uyanik[WWW], Tatsuya Mutsuga, Kazuaki Ishihara*

4,5-Dimethyl-2-Iodoxybenzenesulfonic Acid Catalyzed Site-Selective Oxidation of 2-Substituted Phenols to 1,2-Quinols
[Communication]

Published online on February 21, 2017.
DOI: 10.1002/anie.201612463

Silicones

Kangsang L. Lee*

(Aminomethyl)pyridine Complexes for the Cobalt-Catalyzed Anti-Markovnikov Hydrosilylation of Alkoxy- or Siloxy(vinyl)silanes with Alkoxy- or Siloxyhydrosilanes
[Communication]

Published online on February 17, 2017.
DOI: 10.1002/anie.201612460

Superbases

Julius F. Kögel, Davor Margetić, Xiulan Xie, Lars H. Finger, Jörg Sundermeyer*

A Phosphorus Bisylide: Exploring a New Class of Superbases with Two Interacting Carbon Atoms as Basicity Centers
[Communication]

Coming soon.

Single-Molecule Electrochemistry

Weichun Zhang, Martín Caldarola, Biswajit Pradhan, Michel Orrit*

Gold Nanorod-Enhanced Fluorescence Enables Single-Molecule Electrochemistry of Methylene Blue
[Communication]

Coming soon.

Cascade Reactions

Youai Qiu, Bin Yang, Tuo Jiang, Can Zhu, Jan-E. Bäckvall*

Palladium-Catalyzed Oxidative Cascade Carbonylative Spirolactonization of Enallenols
[Communication]

Published online on February 17, 2017.
DOI: 10.1002/anie.201612384

Olefin Functionalization

Wujun Jian, Liang Ge, Yihang Jiao, Bo Qian, Hongli Bao*

Iron-Catalyzed Decarboxylative Alkyl Etherification of Vinylarenes with Aliphatic Acids as the Alkyl Source
[Communication]

Coming soon.

Hybrid Microcontainers

Ying Cong, Qiuju Li, Min Chen, Limin Wu*

Synthesis of Dual-Stimuli-Responsive Microcontainers with Two Payloads in Different Storage Spaces for Preprogrammable Release
[Communication]

Published online on February 21, 2017.
DOI: 10.1002/anie.201612291

Chemoselectivity

Ciaran P. Seath, Glenn A. Burley*, Allan J. B. Watson*

Determining the Origin of Rate-Independent Chemoselectivity in CuAAC Reactions: An Alkyne-Specific Shift in Rate-Determining Step
[Communication]

Published online on February 16, 2017.
DOI: 10.1002/anie.201612288

CO2 Reduction

Bijandra Kumar, Veerendra Atla, J. Patrick Brian, Sudesh Kumari, Tu Quang Nguyen, Mahendra Sunkara, Joshua M. Spurgeon*

Reduced SnO2 Porous Nanowires with a High Density of Grain Boundaries as Catalysts for Efficient Electrochemical CO2-into-HCOOH Conversion
[Communication]

Coming soon.

F···F Interactions

Javix Thomas, Nathan A. Seifert, Wolfgang Jäger, Yunjie Xu*

A Direct Link from the Gas to the Condensed Phase: A Rotational Spectroscopic Study of 2,2,2-Trifluoroethanol Trimers
[Communication]

Coming soon.

Organocatalysis

Youwei Xie, Benjamin List*

Catalytic Asymmetric Intramolecular [4+2] Cycloaddition of In Situ Generated ortho-Quinone Methides
[Communication]

Published online on February 17, 2017.
DOI: 10.1002/anie.201612149

Homogeneous Catalysis

Abhijit Sau, Ryan Williams, Carlos Palo-Nieto, Antonio Franconetti, Sandra Medina, M. Carmen Galan*

Palladium-Catalyzed Direct Stereoselective Synthesis of Deoxyglycosides from Glycals
[Communication]

Published online on February 17, 2017.
DOI: 10.1002/anie.201612071

Antibiotics

T. Vu Nguyen, Meghan S. Blackledge, Erick A. Lindsey, Bradley M. Minrovic, David F. Ackart, Albert B. Jeon, Andrés Obregón-Henao, Roberta J. Melander, Randall J. Basaraba*, Christian Melander*

The Discovery of 2-Aminobenzimidazoles That Sensitize Mycobacterium smegmatis and M. tuberculosis to β-Lactam Antibiotics in a Pattern Distinct from β-Lactamase Inhibitors
[Communication]

Coming soon.

Halogen Bonds

Yunteng He, Jie Zhang, Lei Lei, Wei Kong*

Self-Assembly of Iodine in Superfluid Helium Droplets: Halogen Bonds and Nanocrystals
[Communication]

Published online on February 21, 2017.
DOI: 10.1002/anie.201611922

Medicinal Chemistry

Jonathan Pettinger, Yann-Vaï Le Bihan, Marcella Widya, Rob L. M. van Montfort, Keith Jones, Matthew D. Cheeseman*

An Irreversible Inhibitor of HSP72 that Unexpectedly Targets Lysine-56
[Communication]

Coming soon.

Photochemistry

Jing Guo, Yao-Wei Xu, Kang Li, Li-Min Xiao, Sha Chen, Kai Wu, Dr. Xu-Dong Chen, Yan-Zhong Fan, Jun-Min Liu*, Cheng-Yong Su*

Regio- and Enantioselective Photodimerization within the Confined Space of a Homochiral Ruthenium/Palladium Heterometallic Coordination Cage
[Communication]

Coming soon.

Main-Group Chemistry

Ricardo Rodriguez[WWW], David Gau, Jérémy Saouli, Antoine Baceiredo*, Nathalie Saffon-Merceron, Vicenç Branchadell, Tsuyoshi Kato*

A Stable Monomeric SiO2 Complex with Donor–Acceptor Ligands
[Communication]

Coming soon.

C–H Activation

Yang Wang[WWW], Vladimir Gevorgyan*

Synthesis of Active Hexafluoroisopropyl Benzoates through Hydrogen-Bond-Enabled Palladium(II)-Catalyzed C–H Alkoxycarbonylation Reaction
[Communication]

Published online on February 17, 2017.
DOI: 10.1002/anie.201611757

Supramolecular Chemistry

Prithankar Pramanik, Debes Ray, Vinod K. Aswal, Suhrit Ghosh*

Supramolecularly Engineered Amphiphilic Macromolecules: Molecular Interaction Overrules Packing Parameters
[Communication]

Published online on February 17, 2017.
DOI: 10.1002/anie.201611715

Proton-Coupled Electron Transfer

Tarali Devi, Yong-Min Lee, Jieun Jung, Muniyandi Sankaralingam, Wonwoo Nam*, Shunichi Fukuzumi*

A Chromium(III)-Superoxo Complex as a Three-Electron Oxidant with a Large Tunneling Effect in Multi-Electron Oxidation of NADH Analogues
[Communication]

Coming soon.

C–C Activation

Martin Jakoobi, Nathan Halcovitch, George F. S. Whitehead, Alexey G. Sergeev*

Selective Arene Cleavage through Direct Insertion of Iridium into the Aromatic Ring
[Communication]

Published online on February 17, 2017.
DOI: 10.1002/anie.201611409

Arenes

Sukdev Bag, Ramasamy Jayarajan, Rahul Mondal, Debabrata Maiti*

Template-Assisted meta-C–H Alkylation and Alkenylation of Arenes
[Communication]

Published online on February 16, 2017.
DOI: 10.1002/anie.201611360

NMR Spectroscopy

Maria Vinaixa*, Miguel A. Rodríguez, Suvi Aivio, Jordi Capellades, Josep Gómez, Nicolau Canyellas, Travis H. Stracker, Oscar Yanes*

Positional Enrichment by Proton Analysis (PEPA): A One-Dimensional 1H-NMR Approach for 13C Stable Isotope Tracer Studies in Metabolomics
[Communication]

Published online on February 21, 2017.
DOI: 10.1002/anie.201611347

Interfacial Reaction Dynamics

Jiamei Quan, Takahiro Kondo, Guichang Wang, Junji Nakamura*

Energy Transfer Dynamics of Formate Decomposition on Cu(110)
[Communication]

Published online on February 17, 2017.
DOI: 10.1002/anie.201611342

Photoanodes

Chengcheng Li, Ang Li, Zhibin Luo, Jijie Zhang, Xiaoxia Chang, Zhiqi Huang, Tuo Wang*, Jinlong Gong*

Surviving High-Temperature Calcination: ZrO2-Induced Hematite Nanotubes for Photoelectrochemical Water Oxidation
[Communication]

Published online on February 21, 2017.
DOI: 10.1002/anie.201611330

Bioconjugation

Hong Geun Lee, Guillaume Lautrette, Bradley L. Pentelute*, Stephen L. Buchwald*

Palladium-Mediated Arylation of Lysine in Unprotected Peptides
[Communication]
(VIP) title=

Published online on February 16, 2017.
DOI: 10.1002/anie.201611202

Electron Donors

Benjamin Eberle, Elisabeth Kaifer, Hans-Jörg Himmel*

A Stable Hexakis(guanidino)benzene: Realization of the Strongest Neutral Organic Four-Electron Donor
[Communication]

Published online on February 17, 2017.
DOI: 10.1002/anie.201611189

Natural Product Synthesis

Markus Neumeyer[WWW], Reinhard Brückner*

First Stereoselective Total Synthesis of a Dimeric Naphthoquinonopyrano-γ-lactone: (+)-γ-Actinorhodin
[Communication]

Published online on February 17, 2017.
DOI: 10.1002/anie.201611183

History of Chemistry

Dudley R. Herschbach*

Michael Polanyi: Patriarch of Chemical Dynamics and Tacit Knowing
[Essay]

Published online on February 17, 2017.
DOI: 10.1002/anie.201610968

Peptide Cyclization

Weidong Liu, Yiwu Zheng, Xudong Kong, Christian Heinis, Yibing Zhao, Chuanliu Wu*

Precisely Regulated and Efficient Locking of Linear Peptides into Stable Multicyclic Topologies through a One-Pot Reaction
[Communication]

Coming soon.

Macrocycles

Ludger A. Wessjohann*, Oliver Kreye, Daniel G. Rivera*

One-Pot Assembly of Amino Acid Bridged Hybrid Macromulticyclic Cages through Multiple Multicomponent Macrocyclizations
[Communication]

Published online on February 17, 2017.
DOI: 10.1002/anie.201610801

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