Angewandte Chemie International Edition

Cover image for Vol. 55 Issue 44

Editor: Peter Gölitz, Deputy Editors: Neville Compton, Haymo Ross

Online ISSN: 1521-3773

Associated Title(s): Angewandte Chemie, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemistryOpen, ChemPlusChem, Zeitschrift für Chemie

Cover Picture (Angew. Chem. Int. Ed. Engl. 1/1985)

24_01/1985The cover page shows the highly symmetrical cluster [[C5Me5]3Re3O6]2⊕, which forms surprisingly readily from the trioxo half-sandwich complex [[C5Me5]Re3O3] and PPh3 in aerated tetrahydrofuran. M3O6 structural groups of this kind were hitherto unknown. ReO4 is formed as the counterion. The salt—blue-green crystals—is stable towards oxygen. Further details are reported by W. A. Hermann et al. on p. 50.

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