Angewandte Chemie International Edition

Cover image for Vol. 54 Issue 21

Editor: Peter Gölitz, Deputy Editors: Neville Compton, Haymo Ross

Online ISSN: 1521-3773

Associated Title(s): Angewandte Chemie, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemistryOpen, ChemPlusChem, Zeitschrift für Chemie

Cover Picture (Angew. Chem. Int. Ed. Engl. 18/1995)

35_18/1996The cover picture shows the palladium-catalyzed cyclization cascade of an iodotriene in the presence of CO in which “living” organopalladium species are formed as intermediates. Remarkably, this reaction succeeds with terminal alkenes that usually undergo β-dehydropalladation in the Heck reaction. E. Negishi et al. report more about this first cascade-type acylpalladation yielding polycycles with an angular mode of fusion on p. 2125 ff. In the reaction shown seven C-C bonds are formed in one step.

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