Angewandte Chemie International Edition

Cover image for Vol. 53 Issue 52

Editor: Peter Gölitz, Deputy Editors: Neville Compton, Haymo Ross

Online ISSN: 1521-3773

Associated Title(s): Angewandte Chemie, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemistryOpen, ChemPlusChem, Zeitschrift für Chemie

Cover Picture (Angew. Chem. Int. Ed. 3/1998)

37_03/1998The cover picture shows the surface of the Ph3PC≡C molecule, calculated with the PM3 method and color-coded according to the molecular electrostatic potential (MEP). The color scale varies from −100 kcalmol−1 (blue) to +48 kcalmol−1 (red); interactions with the solvent were not taken into account. The strongly negative region at the Cβ atom, collinear with the C-C triple bond, is remarkable. More about the synthesis of this compound, which is isoelectronic to the isocyanides and for which no Lewis structure can be formulated that can correctly describe the geometry and charge distribution, as well as reactions and spectroscopic data is reported by H. J. Bestmann et al. on pages 338–342.

Read full text | Table of Contents

SEARCH

SEARCH BY CITATION