Angewandte Chemie International Edition

Cover image for Vol. 55 Issue 19

Editor: Peter Gölitz, Deputy Editors: Neville Compton, Haymo Ross

Online ISSN: 1521-3773

Associated Title(s): Angewandte Chemie, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemistryOpen, ChemPlusChem, Zeitschrift für Chemie

Cover Picture: Ruthenium-Catalyzed Asymmetric Propargylic Substitution Reactions of Propargylic Alcohols with Acetone (Angew. Chem. Int. Ed. 47/2005)

44_47/2005Diruthenium complexes with optically active thiolate-bridged ligands promote the catalytic propargylic substitution of propargylic alcohols with acetone as the nucleophile. The use of novel chiral ligands bearing a phenyl ring that can engage in a π–π interaction with a phenyl ring of the ruthenium–allenylidene moiety lead to high enantioselectivities in these processes. For more details, see the Communication by Y. Nishibayashi and co-workers on page 7715 ff.

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Also of Interest

Organosulfur Reagentsfor001

In their Minireview on page 7674 ff., P. Vogel and S. R. Dubbaka describe how recent developments in the area of ligands and additives allow the cross-coupling of a large variety of reactants, including inexpensive and readily available sulfonyl chlorides.

Soft Nanotechnologyfor002

Hydrogel nanoparticles are promising materials for nanotechnological and biotechnological applications. In their Review on page 7686 ff., L. A. Lyon and S. Nayak describe the advances made with these swellable materials.

Lithium Alkoxide Cubanesfor003

A dimeric, doubly bridged complex in which Li4O4 cubane units are connected by a transition-metal complex is presented by D. A. Sweigart and co-workers in their Communication on page 7710 ff.