Angewandte Chemie International Edition

Cover image for Vol. 53 Issue 28

Editor: Peter Gölitz, Deputy Editors: Neville Compton, Haymo Ross

Online ISSN: 1521-3773

Associated Title(s): Angewandte Chemie, Chemistry - A European Journal, Chemistry – An Asian Journal, Zeitschrift für Chemie

46_08b/2007Inside Cover Picture: Structural and Compositional Control in {M12} Cobalt and Nickel Coordination Clusters Detected Magnetochemically and with Cryospray Mass Spectrometry (Angew. Chem. Int. Ed. 8/2007)

Coordination clusters comprising three linked M4 O4 cubanes are prepared. The resulting isostructural {Ni12 } (see picture) and {Co12} cations, as well as mixed-metal structures, are characterized by ferro-and antiferromagnetic coupling. The composition of the cluster complexes was confirmed by low-temperature electrospray mass spectrometry. For more information on these species, see the Communication by P. Kögerler, L. Cronin, and co-workers on page 1340ff.

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