Angewandte Chemie International Edition

Cover image for Vol. 55 Issue 20

Editor: Peter Gölitz, Deputy Editors: Neville Compton, Haymo Ross

Online ISSN: 1521-3773

Associated Title(s): Angewandte Chemie, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemistryOpen, ChemPlusChem, Zeitschrift für Chemie

50_07b/2011Back Cover: [Cu(HF2)2(pyrazine)]n: A Rectangular Antiferromagnetic Lattice with a Spin Exchange Path Made Up of Two Different FHF Bridges (Angew. Chem. Int. Ed. 7/2011)

Two types of HF2 bridges are found in the rectangular polymeric network formed from CuII, FHF, and pyrazine (pyz). The resulting linear Cu-(FHF)2-Cu chains are linked into 2D sheets by pyz units. The FHF coordination in the Cu-(FHF)2-Cu chains mimics motifs found in transition metal/azide systems. In their Communication on page 1573 ff. J. L. Manson et al. also show that stronger spin exchange occurs along the HF2 bridges than the Cu-pyz-Cu bridges.

Read Full Text  | Table of Contents