Angewandte Chemie International Edition

Cover image for Vol. 56 Issue 50

Editor: Neville Compton; Editor Emeritus: Peter Gölitz

Online ISSN: 1521-3773

Associated Title(s): Angewandte Chemie, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemistryOpen, ChemPhotoChem, ChemPlusChem, Zeitschrift für Chemie

50_36i/2011Inside Cover: Palladium-Catalyzed Borylation of Sterically Demanding Aryl Halides with a Silica-Supported Compact Phosphane Ligand (Angew. Chem. Int. Ed. 36/2011)

Immobilizing a monophosphane on a solid surface can exert a strong influence on the catalytic activities of its metal complexes. In their Communication on page 8363 ff., M. Sawamura and co-workers report that a compact monophosphane immobilized on silica gel can be utilized for the Pd-catalyzed borylation of sterically and electronically challenging aryl chlorides. This study shows that nonbulky ligands can be used for aryl chloride activation if the ligands are immobilized.

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