Angewandte Chemie International Edition

Cover image for Vol. 53 Issue 35

Editor: Peter Gölitz, Deputy Editors: Neville Compton, Haymo Ross

Online ISSN: 1521-3773

Associated Title(s): Angewandte Chemie, Chemistry - A European Journal, Chemistry – An Asian Journal, Zeitschrift für Chemie

51_21i/2012Inside Cover: Photoswitchable Dynamic Magnetic Relaxation in a Well-Isolated {Fe2Co} Double-Zigzag Chain (Angew. Chem. Int. Ed. 21/2012)

A cooperative, reversible charge-transfer-induced spin transition that occurs upon cooling and heating of the well-isolated cyanide-bridged FeIII2CoII double-zigzag chain {[Fe(pzTp)(CN)3]2Co(4-styrylpyridine)2}·2H2O·2CH3OH (pzTp=tetrakis(pyrazolyl)borate) is described in the Communication by T. Liu, O. Sato, C.-Y. Duan et al. on page 5119 ff. Irradiation of the chain with 532 nm light at 5 K results in a single-chain magnetic behavior with no antiferromagnetic ordering after the irradiation.

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