Angewandte Chemie International Edition

Cover image for Vol. 55 Issue 23

Editor: Peter Gölitz, Deputy Editors: Neville Compton, Haymo Ross

Online ISSN: 1521-3773

Associated Title(s): Angewandte Chemie, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemistryOpen, ChemPlusChem, Zeitschrift für Chemie

51_41/2012Cover Picture: Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal–Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts (Angew. Chem. Int. Ed. 41/2012)

Acid-resistant, water-stable MOFs with ultra-large 1D channels exhibiting biomimetic catalytic activity have been developed. In their Communication on page 10307 ff., H.-C. Zhou and co-workers report the synthesis, characterization, and catalytic studies of an isostructural series of MOFs designated as PCN-222. The combination of a zirconium cluster and an iron–porphyrin derivative gave rise to PCN-222(Fe), which is highly effective in catalyzing the oxidation of a number of peroxidase substrates.

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Also of Interest

Photobiophysicsfor001

In their Communication on page 10256 ff., J. A. Wyer and S. Brøndsted Nielsen describe the gas-phase spectroscopy of isolated ferric heme nitrosyl ions and complexes with different amino acids.


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H. Shinokubo et al. report the selective formation of diazaacenes and azahelicenes through the oxidation of aminoanthracene derivatives in their Communication on page 10333 ff.


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In their Communication on page 10386 ff., A. Vertes et al. outline the compartmentalization of metabolites within subcellular domains by using cell microdissection and laser ablation electrospray ionization mass spectrometry.


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