Angewandte Chemie International Edition

Cover image for Vol. 55 Issue 7

Chefredakteur: Peter Gölitz, Stellvertreter: Neville Compton, Haymo Ross

Online ISSN: 1521-3773

Associated Title(s): Angewandte Chemie, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemistryOpen, ChemPlusChem, Zeitschrift für Chemie

[]

Press Release

,
doi: 10.1002/anie.201003888

Nr. 49/2010
January 12, 2011

It Heals and Grows Together

Polymer with amazing self-healing properties

Contact: Krzysztof Matyjaszewski, Carnegie Mellon University, Pittsburgh (USA)
Registered journalists may download the original article here:
Repeatable Photoinduced Self-Healing of Covalently Cross-Linked Polymers through Reshuffling of Trithiocarbonate Units

Sooner or later, a cut to the skin or a broken bone will heal on its own; however, a scratch to a car’s paint or a tear in the wing of an airplane will not. Materials with self-healing properties could help extend the durability of products and make repairs easier. Krzysztof Matyjaszewski and his co-workers at Carnegie Mellon University (Pittsburgh, USA) and Kyushu University (Japan) have now developed a polymer that can repair itself when irradiated with UV light—over and over again. As the scientists report in the journal Angewandte Chemie, this is the first material in which capped covalent bonds repeatedly reattach, even allowing fully separated pieces to be fused back together.


© Wiley-VCH

Some previous solid self-healing materials contain tiny capsules that tear open to release a chemical agent when the material is damaged and have been able to repair themselves only one time. Other materials, including some gels, can repair themselves repeatedly but lack the covalent bonds that increase materials strength and stability.

In contrast, the new polymeric material produced by the American and Japanese team is stable and repairs itself again and again. The secret to their success is that the polymer is cross-linked through trithiocarbonate units. These are carbon atoms bonded to three sulfur atoms, two of which use their second bonding position to attach to another carbon atom. These groups have a special property: they can restructure under UV light. The light breaks one carbon–sulfur bond in the trithiocarbonate groups. This produces two radicals—molecules with a free, unpaired electron. The radicals are very reactive and attack other trithiocarbonate groups to form new carbon–sulfur bonds while breaking others to form more free radicals. The chain reaction stops when two radicals react with each other.

The researchers were able to heal cut polymer fragments with irradiation—either immersed in liquid or in bulk. They only had to firmly press the cut edges together and irradiate them. The edges grew back together by means of the radical re-organization process described above.

The self-healing effect goes much further: even shredded polymer samples could simply be pressed together and irradiated to be fused into a continuous piece. The resulting object was in the shape of the cylindrical tube in which the procedure was carried out. This self-healing process can be carried out repeatedly on the same sample. The material is thus also interesting as a new recyclable product.

(2573 characters)

SEARCH

SEARCH BY CITATION